Research Article
AZO - HYDRAZO TAUTOMERISM: FURTHER EVIDENCE BASED ON POLAROGRAPHIC REDUCTION AND ACIDITY FUNCTION OF SOME HETEROCYCLIC COMPOUNDS CONTAINING OXIMINO - GROUP
Abstract
Potentiometric pKa and polarographic behaviour of 1, 3-indandione-monoxime and four of its substituted derivatives were investigated in buffer solution of pH ~ 2-12. The results showed that the compounds are in the azo-form, where its reduction wave precedes that of the oxime. A mechanism for the electrodic processes was proposed. Half-wave potentials showed fair cor- relation with Hammett’s er constants while pKa is practically independent.
Keywords
References
- Azo-hydrazo tautomerism: Further evidence based on polarographic reduction and acidity function of some heterocyclic compounds containing oximino-group
Year 1994,
Volume: 40 , 1 - 2, 01.01.1994
Abstract
References
- Azo-hydrazo tautomerism: Further evidence based on polarographic reduction and acidity function of some heterocyclic compounds containing oximino-group
There are 1 citations in total.
Details
| Primary Language | English |
|---|---|
| Subjects | Chemical Engineering |
| Journal Section | Research Article |
| Authors | |
| Publication Date | January 1, 1994 |
| Published in Issue | Year 1994 Volume: 40 |
Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
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