The carbanions of ethyl cyanoacetate, cyanoacetanilide, malononitrile and cyanoacetami- de react with aryl carbamoyl aryl hydrazidoyl chlorides (1 a-f) in ethanol at room temperature to give the corresponding substituted pyrazoles (3 a-f, 6 a-c, 7 a-e and 8 a). The structural as- signments have been made on the basis of elemental analysis, spectral data and the Chemical evidence for the resulting pyrazoles. On the other hand, aminoacetonitriie was reacted with (1 b) and 9 to give the corresponding substituted triazines (13 b) and quinolino 1, 2-f triazine derivative (12). The mechanism of the different reactions were discussed.
Primary Language | English |
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Subjects | Chemical Engineering |
Journal Section | Research Article |
Authors | |
Publication Date | January 1, 1990 |
Published in Issue | Year 1990 Volume: 36 |
Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
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