THE REACTİONS OF İNDANDİONES WITH ACTIVE METHYLENE COMPOUNDS

Yıl 1988, Cilt: 34 Sayı: 01.02, 136 - 140, 01.01.1899

Tahsin Uyar

https://doi.org/10.1501/Commub_0000000495

Öz

We have studied the reactions of 1,3-indandione (I), 2-methyI-l,3-indandione (II) and 2,2-dimethy!-l,3-indandione (III) with maloncnitrile and metliyi cyanoacetate. Both, I and II, reacted with malononitrile to give several compounds. The reaction of methyi cyano¬acetate with I gave a dark, resinous material under similar conditions, while II gave mono imine of the indandione in poor yield. The reaction of III with malononitrile and methyi cyanoaceta¬te did not take place. The structure of the compounds were confirmed on the hasis of IR, UV, lHNMR and mass spectral studies

Anahtar Kelimeler

The reaction, material, lHNMR and mass

Kaynakça

• Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering