THE PREDICTION OF İSOBARİC BİNARY VAPOUR - LIQUID EQUILIBRIA FROM TWO ISOTHERMAL HEAT OF MIXING DATA

Year 1987, Volume: 33 , 54 - 70, 01.01.1987

Ülkü Özalp

https://doi.org/10.1501/Commub_0000000480

Abstract

The new modified forms of the Wilsou and the NRTL equations of heat of mixiug data were developed, whose application can be extended to isobaric binary VLE predictions. That was obtained assuming that the two Wilson and NRTL parameters are linear functions of teınpe- rature. Both equations give sufficicnt predictions for systems with max heats of mixing less then 130 cal/ g. mol. Howevcr, the Wilson equation is incapable to describe the heat of mixing data for the system with large heats of mixing, the NRTL equation can overcome this problem, but the quality of the VLE predictions is stili poor.

Keywords

The new modified forms, That was obtained, Wilson equation is incapable

References

• Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering