Effect of Solvent on the Reaction Rat e. Part. III Role of Macrocyclic Ethers on the Sjy2 Reactions in Water-Dioxane Solutions

Yıl 1981, Cilt: 27 , 0 - 0, 01.01.1981

H. Yetişli

https://doi.org/10.1501/Commub_0000000133

Öz

Effect of some macrocyclic ethers have been investigated in the reaction of di or tri nitro phenoxides with some alkil halides in water-dioxane mixtures. Ithas been found that in most cases heptaoxa oligomer has more influence although the fact that the such compounds are more pronounced on the S]yl type of reaetions with respect to Sjy2 reaetions so that the ehters seem to capable to bind the carbonium intermediates even in water-dioxane mixtures.

Anahtar Kelimeler

Reaction Rat, Macrocyclic Ethers, Sjy2 Reactions

Kaynakça

• Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering