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Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives

Year 1983, Volume: 29 , 0 - 0, 01.01.1983
https://doi.org/10.1501/Commub_0000000517

Abstract

Diethyl (2-bromo-l- phenyl, vinyl) phosphonite and diethyl (1-chloro-l-phenyl, vinyl) phosphonate react with diazomethane, diphenyldiazomethane, and phenylbenzoyldiazomet- hane. The reaction with diazomethane goes by 3 ' 2 “ 5 scheme of dipolar cycloaddition. The reaction of the phosphonite with diphenyldiazomethane goes by the 3-3-6 scheme, while in the case of phosphonate cleavage of C-P bond took place. However, the reaction of phospho-nate with pheriylbenzoyldiazomethane goes by 3 -- 2 — 5 scheme of 1, 3-dipolar cycloaddition with. the cleavage of C-P bond. .

References

  • Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
Year 1983, Volume: 29 , 0 - 0, 01.01.1983
https://doi.org/10.1501/Commub_0000000517

Abstract

References

  • Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
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Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Article
Authors

William I. Awad This is me

Publication Date January 1, 1983
Published in Issue Year 1983 Volume: 29

Cite

Vancouver Awad WI. Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives. Commun. Fac. Sci. Univ. Ank. Ser. B. 1983;29.

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

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