Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance

Merve Vurucuel; Ali Duran; Abdullah İnci; Erkan Yılmaz

doi:10.17776/csj.1138433

EN

Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance

Abstract

Access the quality and sufficient amount of water is started to being problem with population increasing. One of the way to behalf the solution of this problem is usage waste water treatment in industry and agriculture. Wastewater treatment methods have disadvantages of being costly and producing secondary pollutants, photocatalysis, which is one of the advanced oxidation methods that is more advantageous and effective in removing pollutants, is promising. The newest member of nanomaterial, C-quantum dots (CQDs) has been increasingly get attention on lots of field including photocatalyst. Semiconductors are commonly used in photocatalysis however, they have electron pair recombination problem that results decreasing of efficiency. Doping semiconductors with different nanomaterials is one of the easiest ways to get over the problem. Recently CQDs has been started to used as dopping agent. Solvothermal method is among the easiest and environmentally friendly methods in nanomaterial synthesis. In this study, the effect of dimethylformamide, dimethylsulfoxide, ethylene glycol and water as solvothermal solvent on the photocatalytic efficiency of C-modified ZnO nanoparticles (CQDs@ZnO NPs) was investigated for the first time in the literature. Photocatalytic performance of CQDs@ZnO NPs was investigated on the photocatalytic degradation of methylene blue (MB). Angora mohair has been used as a CQDs source for the first time in the literature. Photocatalytic degradation performances of CQDs@ZnO NPs for MB at 300 min were 82.4%, 87.6% and 99% for ethylene glycol-water mixture, DMSO and DMF, respectively. The results proved that solvent type for solvothermal synthesis procedure has important role for photocatalytic performance of CQDs@ZnO NPs.

Keywords

Photocatalytic degradation, solvothermal synthesis, C-quantum dots, Angora mohair, ZnO NPs.

Supporting Institution

The Research Fund of the Erciyes University

Project Number

FYL-2021-11148

Thanks

This work was supported by the Research Fund of the Erciyes University (Project Number FYL-2021-11148). Authors acknowledges the Republic of Turkey Ministry of Agriculture and Forestry Çankırı Directorate of Provincial Agriculture and Forestry.

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Details

Primary Language

English

Subjects

Environmental Sciences

Journal Section

Research Article

Authors

Merve Vurucuel
0000-0001-8054-1306
Türkiye

Ali Duran
0000-0002-6260-2424
Türkiye

Abdullah İnci
0000-0003-1614-0756
Türkiye

Erkan Yılmaz ^*
0000-0001-8962-3199
Türkiye

Publication Date

December 27, 2022

Submission Date

June 30, 2022

Acceptance Date

November 9, 2022

Published in Issue

Year 2022 Volume: 43 Number: 4

DOI

https://doi.org/10.17776/csj.1138433

IZ

https://izlik.org/JA94AC72ZU

APA

Vurucuel, M., Duran, A., İnci, A., & Yılmaz, E. (2022). Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance. Cumhuriyet Science Journal, 43(4), 606-612. https://doi.org/10.17776/csj.1138433

AMA

1.Vurucuel M, Duran A, İnci A, Yılmaz E. Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance. CSJ. 2022;43(4):606-612. doi:10.17776/csj.1138433

Chicago

Vurucuel, Merve, Ali Duran, Abdullah İnci, and Erkan Yılmaz. 2022. “Green Synthesis of C-Quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-Quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance”. Cumhuriyet Science Journal 43 (4): 606-12. https://doi.org/10.17776/csj.1138433.

EndNote

Vurucuel M, Duran A, İnci A, Yılmaz E (December 1, 2022) Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance. Cumhuriyet Science Journal 43 4 606–612.

IEEE

[1]M. Vurucuel, A. Duran, A. İnci, and E. Yılmaz, “Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance”, CSJ, vol. 43, no. 4, pp. 606–612, Dec. 2022, doi: 10.17776/csj.1138433.

ISNAD

Vurucuel, Merve - Duran, Ali - İnci, Abdullah - Yılmaz, Erkan. “Green Synthesis of C-Quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-Quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance”. Cumhuriyet Science Journal 43/4 (December 1, 2022): 606-612. https://doi.org/10.17776/csj.1138433.

JAMA

1.Vurucuel M, Duran A, İnci A, Yılmaz E. Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance. CSJ. 2022;43:606–612.

MLA

Vurucuel, Merve, et al. “Green Synthesis of C-Quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-Quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance”. Cumhuriyet Science Journal, vol. 43, no. 4, Dec. 2022, pp. 606-12, doi:10.17776/csj.1138433.

Vancouver

1.Merve Vurucuel, Ali Duran, Abdullah İnci, Erkan Yılmaz. Green Synthesis of C-quantum Dots Modified ZnO Nanophotocatalyst: The Effect of Different Solvents Used in Production of C-quantum Dots Modified ZnO Nanophotocatalyst on Photocatalytic Performance. CSJ. 2022 Dec. 1;43(4):606-12. doi:10.17776/csj.1138433

Cited By

ZnO quantum dots for wastewater Remediation: Phytotoxicity, photocatalytic performance, and economic assessment

Optical Materials

https://doi.org/10.1016/j.optmat.2025.117391

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