Polymeric Microspheres for Efficient Adsorption of Reactive Black 5 Dye: Adsorption Isotherms, Kinetics and Thermodynamic Evaluations
Abstract
In parallel with the increasing human population, industry is growing rapidly, which also causes an increase in the amount of wastewater. Dyes, which represent the largest group of pollutants in wastewater, are utilized in various industries, mainly in the textile sector. In addition to the annual production of tons of dyes, significant quantities of dye-contaminated wastewater are released into the environment. In this study, poly(ethylene glycol dimethacrylate-N-methacryloyl-L-tryptophan methyl ester) (PEDMATP) microspheres were employed to adsorption one of the synthetic dyes, reactive black 5 (RB5), from the aqueous medium. The impacts of parameters such as pH, initial concentration, temperature, and contact time on adsorption were examined. The maximum RB5 adsorbed amount onto PEDMATP was determined as 20.06 mg/g at 277 K and pH=7. The data obtained are compatible with the Langmuir isotherm and pseudo-second-order kinetic models. The polymeric microspheres could be reused up to 5 times with negligible losses (approximetly 15%) of adsorption capacity.
Keywords
Adsorption, Dyes, Polymeric microspheres, Reactive black 5
Supporting Institution
References
- [1] Bulgariu, L., Escudero, L. B., Bello, O. S., Iqbal, M., Nisar, J., Adegoke, K. A., ... & Anastopoulos, I. (2019). The utilization of leaf-based adsorbents for dyes removal: A review. Journal of Molecular Liquids, 276, 728–747. https://doi.org/10.1016/j.molliq.2018.12.001
- [2] Gupta, V. K. (2009). Application of low-cost adsorbents for dye removal–A review. Journal of Environmental Management, 90(8), 2313–2342. https://doi.org/10.1016/j.jenvman.2008.11.017
- [3] Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science, 209, 172–184. https://doi.org/10.1016/j.cis.2014.04.002
- [4] Zhou, Y., Lu, J., Zhou, Y., & Liu, Y. (2019). Recent advances for dyes removal using novel adsorbents: A review. Environmental Pollution, 252, 352–365. https://doi.org/10.1016/j.envpol.2019.05.072
- [5] Zhuang, Z., Cheng, X., Cao, L., He, G., Zhou, J., & Wei, Y. (2023). Secondary bond interface assembly of polyethyleneimine on zein microparticles for rapid adsorption of Reactive Black 5. Colloids and Surfaces B: Biointerfaces, 225, 113247. https://doi.org/10.1016/j.colsurfb.2023.113247
- [6] Tlaiaa, Y. S., Naser, Z. A. R., & Ali, A. H. (2020). Comparison between coagulation and electrocoagulation processes for the removal of reactive black dye RB-5 and COD reduction. Desalination and Water Treatment, 195, 154–161. https://doi.org/10.5004/dwt.2020.25866
- [7] He, Z., Song, S., Zhou, H., Ying, H., & Chen, J. (2007). C.I. Reactive Black 5 decolorization by combined sonolysis and ozonation. Ultrasonics Sonochemistry, 14(3), 298–304. https://doi.org/10.1016/j.ultsonch.2006.06.002
- [8] Meriç, S., Kaptan, D., & Ölmez, T. (2004). Color and COD removal from wastewater containing Reactive Black 5 using Fenton’s oxidation process. Chemosphere, 54(3), 435–441. https://doi.org/10.1016/j.chemosphere.2003.08.010
- [9] Semiz, L. (2020). Removal of reactive black 5 from wastewater by membrane filtration. Polymer Bulletin, 77(6), 3047–3059. https://doi.org/10.1007/s00289-019-02905-w
- [10] Çelebi, H., Bahadir, T., Tulun, Ş., Şimşek, İ., & Bilican, I. (2025). Utilization of peanut shell: Investigating the adsorption mechanism and optimization of red 195 and reactive black-5. International Journal of Environmental Science and Technology, 22(1), 219–236. https://doi.org/10.1007/s13762-024-05847-x