Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Asuman Uçar; Mükerrem Fındık; Nuriye Koçak; Alper Çolak; Onur Şahin

doi:10.17776/csj.812164

EN

Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Abstract

Herein a novel inorganic-organic hybrid Keggin-type heteropolymolybdate [Ni2Na(C12H8N2)4(BMo12O40)(H2O)2] (1) has been synthesized under hydrothermal conditions in aqueous solution. The cyrstal structure was fully characterized by powder X-ray diffraction (XRD), elemental analysis, Fourier-tranform infrared spectrum (FT-IR), Thermogravimetric analysis (TGA) and Scanning Electron Microscopy (SEM) analysis. Single crystal X-ray structural analysis demonstrates that the complex consists of a Keggin anion [BMo12O40]5− polyanion, four 1,10-phenanthroline (C12H8N2) ligands, two Ni(II) ions, two Na(I) ions and two aqua ligands. The experimental powder X-ray diffraction (XRD) result of the crystal is consistent with the calculated data. The SEM image shows that the compound crystals have a cubic structure.

Keywords

Polyoxometalates, Coordination complexes, Oxoclusters, Hydrothermal synthesis, Keggin

Supporting Institution

Necmettin Erbakan University Research Foundation

Project Number

151210002

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Asuman Uçar ^*
0000-0003-2674-3120
Türkiye

Mükerrem Fındık
0000-0002-9441-0814
Türkiye

Nuriye Koçak
0000-0002-0531-3538
Türkiye

Alper Çolak
0000-0003-4478-7792
Türkiye

Onur Şahin
0000-0003-3765-3235
Türkiye

Publication Date

March 29, 2021

Submission Date

October 18, 2020

Acceptance Date

January 21, 2021

Published in Issue

Year 2021 Volume: 42 Number: 1

DOI

https://doi.org/10.17776/csj.812164

IZ

https://izlik.org/JA82AC99GM

APA

Uçar, A., Fındık, M., Koçak, N., Çolak, A., & Şahin, O. (2021). Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline. Cumhuriyet Science Journal, 42(1), 22-29. https://doi.org/10.17776/csj.812164

AMA

1.Uçar A, Fındık M, Koçak N, Çolak A, Şahin O. Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline. CSJ. 2021;42(1):22-29. doi:10.17776/csj.812164

Chicago

Uçar, Asuman, Mükerrem Fındık, Nuriye Koçak, Alper Çolak, and Onur Şahin. 2021. “Hydrothermal Synthesis and Crystal Structures of a Novel Keggin-Type Polyoxometalate Based on 1,10-Phenanthroline”. Cumhuriyet Science Journal 42 (1): 22-29. https://doi.org/10.17776/csj.812164.

EndNote

Uçar A, Fındık M, Koçak N, Çolak A, Şahin O (March 1, 2021) Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline. Cumhuriyet Science Journal 42 1 22–29.

IEEE

[1]A. Uçar, M. Fındık, N. Koçak, A. Çolak, and O. Şahin, “Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline”, CSJ, vol. 42, no. 1, pp. 22–29, Mar. 2021, doi: 10.17776/csj.812164.

ISNAD

Uçar, Asuman - Fındık, Mükerrem - Koçak, Nuriye - Çolak, Alper - Şahin, Onur. “Hydrothermal Synthesis and Crystal Structures of a Novel Keggin-Type Polyoxometalate Based on 1,10-Phenanthroline”. Cumhuriyet Science Journal 42/1 (March 1, 2021): 22-29. https://doi.org/10.17776/csj.812164.

JAMA

1.Uçar A, Fındık M, Koçak N, Çolak A, Şahin O. Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline. CSJ. 2021;42:22–29.

MLA

Uçar, Asuman, et al. “Hydrothermal Synthesis and Crystal Structures of a Novel Keggin-Type Polyoxometalate Based on 1,10-Phenanthroline”. Cumhuriyet Science Journal, vol. 42, no. 1, Mar. 2021, pp. 22-29, doi:10.17776/csj.812164.

Vancouver

1.Asuman Uçar, Mükerrem Fındık, Nuriye Koçak, Alper Çolak, Onur Şahin. Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline. CSJ. 2021 Mar. 1;42(1):22-9. doi:10.17776/csj.812164

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