Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities

Ayşegül Şenocak; Hüseyin Akbaş

doi:10.17776/csj.824566

EN

Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities

Abstract

The reaction of o-aminophenol with para hydroxy and methoxy substituted benzaldehydes yielded two Schiff bases. These Schiff bases functioning precursors were turned into palladium complexes by treating palladium acetate. The structural formulas based on spectral methods (elemental analysis, FT-IR spectroscopy, NMR spectroscopy and QTOF-LC/MS spectroscopy) were suggested for obtained both complexes. According to the structural characterization methods, one of the complexes had also an acetate co-ligand along with the hydroxy substituted Schiff base ligand. In the other complex, the palladium central ion was proposed to be coordinated with two methoxy substituted Schiff bases. Besides, DPPH scavenging activities of the all synthesized compounds were determined and compared to well-known antioxidant standards. According to the results, antioxidant activities of the palladium complexes was mild but lower than parent Schiff bases.

Keywords

Schiff base, o-aminophenol, DPPH scavenging activity, palladium complex, spectroscopic methods

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Ayşegül Şenocak ^*
0000-0001-9210-4621
Türkiye

Hüseyin Akbaş
0000-0002-3013-9033
Türkiye

Publication Date

March 29, 2021

Submission Date

November 11, 2020

Acceptance Date

March 17, 2021

Published in Issue

Year 2021 Volume: 42 Number: 1

DOI

https://doi.org/10.17776/csj.824566

IZ

https://izlik.org/JA73PL75TY

APA

Şenocak, A., & Akbaş, H. (2021). Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities. Cumhuriyet Science Journal, 42(1), 68-74. https://doi.org/10.17776/csj.824566

AMA

1.Şenocak A, Akbaş H. Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities. CSJ. 2021;42(1):68-74. doi:10.17776/csj.824566

Chicago

Şenocak, Ayşegül, and Hüseyin Akbaş. 2021. “Palladium Complexes of NO Type Schiff Bases: Synthesis, Characterization and Antioxidant Activities”. Cumhuriyet Science Journal 42 (1): 68-74. https://doi.org/10.17776/csj.824566.

EndNote

Şenocak A, Akbaş H (March 1, 2021) Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities. Cumhuriyet Science Journal 42 1 68–74.

IEEE

[1]A. Şenocak and H. Akbaş, “Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities”, CSJ, vol. 42, no. 1, pp. 68–74, Mar. 2021, doi: 10.17776/csj.824566.

ISNAD

Şenocak, Ayşegül - Akbaş, Hüseyin. “Palladium Complexes of NO Type Schiff Bases: Synthesis, Characterization and Antioxidant Activities”. Cumhuriyet Science Journal 42/1 (March 1, 2021): 68-74. https://doi.org/10.17776/csj.824566.

JAMA

1.Şenocak A, Akbaş H. Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities. CSJ. 2021;42:68–74.

MLA

Şenocak, Ayşegül, and Hüseyin Akbaş. “Palladium Complexes of NO Type Schiff Bases: Synthesis, Characterization and Antioxidant Activities”. Cumhuriyet Science Journal, vol. 42, no. 1, Mar. 2021, pp. 68-74, doi:10.17776/csj.824566.

Vancouver

1.Ayşegül Şenocak, Hüseyin Akbaş. Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities. CSJ. 2021 Mar. 1;42(1):68-74. doi:10.17776/csj.824566

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https://doi.org/10.1016/j.ica.2023.121505

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