Application of a new inhibitor for the corrosion of iron in acidic solution: Electrochemical effect of a scorpion venom

Yıl 2023, Cilt: 6 Sayı: 2, 88 - 93, 30.12.2023

Demet Özkır , Osman Seyyar

https://doi.org/10.46239/ejbcs.1373150

Öz

In this study, the venom of the species Leiurus abdullahbayrami, known as the yellow scorpion from the Buthidae family, was applied for the first time as a natural corrosion inhibitor for iron in hydrochloric acid solution. The effectiveness of scorpion venom as an eco-friendly and natural inhibitor was determined by electrochemical methods such as electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (Tafel extrapolation method) and linear polarization resistance (LPR) after an hour of immersion. Four different concentrations were determined for the green and natural inhibitor scorpion venom in 1.0 M HCl, and it was observed that the corrosion of iron in these solutions was significantly inhibited. In general, the inhibition efficiency was above 80%. According to the potentiodynamic polarization data, it has been determined that the Leiurus abdullahbayrami venom acts as a cathodic-type inhibitor on the Fe surface. Finally, the surface images of the iron electrodes in 1.0 M HCl solutions without and with Leiurus abdullahbayrami venom after 1 h immersion were examined by field emission scanning electron microscope (FE-SEM), it was concluded that the surface containing scorpion venom had a flatter compared to the uninhibited surface.

Anahtar Kelimeler

Scorpion venom, Leiurus abdullahbayrami, Acidic corrosion, Green inhibitor, Adsorption, EIS

Kaynakça

• Akkoç S, Özkır D, Başaran E, Kaya S, Berisha A. 2023. A combined experimental and theoretical approach effect of a benzimidazolium salt as a new corrosion inhibitor on mild steel in HCl solution. Ionics, 29:3813–3827.
• Doğru Mert B. 2017. Yumuşak Çeliğin Korozyon Davranışı. Çukurova Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 32(2):145-152.
• Erbil M. 2012. Korozyon İlkeler – Yöntemler, Korozyon Derneği Yayını, Poyraz Ofset, Ankara.
• Fang Y, Suganthan B, Ramasamy RP. 2019. Electrochemical characterization of aromatic corrosion inhibitors from plant extracts. J Electroanal Chem. 840:74-83.
• Gomes A, Gomes A. 2015. Scorpion Venoms. In: Gopalakrishnakone P. et al (eds.) Scorpion Venom Research Around the World: Heterometrus Species, Springer Dordrecht Heidelberg New York.
• Nazlıgül H, Güllü E, Mert ME, Doğru Mert B. 2022. Investigation of Inhibition Performance of Epdantoin for Mild Steel Protection in HCl Solution: Electrochemical and Quantum Theoretical Approaches. Tr J Nature Sci. 11(4):70-78.
• Numanoğlu Çevik Y, Kanat MA. 2022. Comparative analysis of peptides and proteins in two congeneric (Leiurus abdullahbayrami; Buthidae) scorpion venoms by MALDI-TOF MS. Biological Diversity and Conservation, 15(2):186-194.
• Özkır D. 2019a. A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques. Journal of Electrochemical Science and Technology, 10(1):37–54.
• Özkır D. 2019b. The Electrochemical Variation of a Kind of Protein Staining and Food Dye as a New Corrosion Inhibitor on Mild Steel in Acidic Medium. Int J Electrochem. (Article ID 5743952), 2019:1–11.
• Özkır D, Kayakırılmaz K. 2020. The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl) diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel. J Electrochem Sci Technol. 11(3):257-272.
• Özkır D. 2021a. The role of Lavandula sp. extract for effective inhibiting the mild steel corrosion in the hydrochloric acid solution. Int J Chem Technol. 5(2):125-132.
• Özkır D. 2021b. An Overview of Plagiochila porelloides (Marchantiophyta) as a New Environmentally Sustainable Green Corrosion Inhibitor for Mild Steel in Acidic Solution. Anatolian Bryol. 7(2):119-130.
• Policarpi EdB, Spinelli A. 2020. Application of Hymenaea stigonocarpa fruit shell extract as eco-friendly corrosion inhibitor for steel in sulfuric acid. J Taiwan Inst Chem Eng. 116:215-222.
• Singh DK, Ebenso EE, Singh MK, Behera D, Udayabhanu G, John RP. 2018. Non-toxic Schiff bases as efficient corrosion inhibitors for mild steel in 1 M HCl: Electrochemical, AFM, FE-SEM and theoretical studies. J Mol Liq. 250:88-99.
• Srivastava M, Tiwari P, Srivastava SK, Prakash R, Ji G. 2017. Electrochemical investigation of Irbesartan drug molecules as an inhibitor of mild steel corrosion in 1 M HCl and 0.5 M H 2 SO 4 solutions. J Mol Liq. 236:184-197.
• Tobassum S, Tahir HM, Arshad M, Zahid MT, Ali S, Ahsan MM. 2020. Nature and applications of scorpion venom: An overview. Toxin Rev. 39(3):214-225.
• Wen J, Zhang X, Liu Y, Shang B, He J, Li L. 2023. Exploration of imidazol-4-methylimine thiourea as effective corrosion inhibitor for mild steel in hydrochloric medium: Experimental and theoretical studies. Colloids Surf A: Physicochem Eng Asp. 674:131895.