Yıl 2019, Cilt 7 , Sayı , Sayfalar 155 - 163 2019-11-24

Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases

Moza M. AL-JIBOURY [1] , Khansaa Sh. AL-NAMA [2]


Unsymmetrically brighted tetradentate Schiff bases H2L1= [1-(E)-((3-((E)-2hydroxybenzlidene) amino) phenyl)imino) methyl), naphthalene-2-ol], H2l2= [2-((E)-1-((3(((E) 2hydroxybenzlidene) amino)phenyl) imino) phenyl) imino)ethyl)phenol], H2L3= [2-((E)-1-((3(((E) 2hydroxybenzlidene) amino)phenyl)methyl)-5methoxyphenol] Which derived from m-phenylenediamine with salicyaldehyde and 2-hydroxynaphthaldehyde or 2-hydroxyacetophenone or 2-hydroxy-4methoxybenzophenone and their complexes of the type [ Cu2Ln2], where n=1,2,3 have been synthesized. Adduct complexes of the type [Cu2Ln2 (py)4] were also prepared in (1:4) (complex : py) molar ratio. The complexes and adducts were characterized by elemental analysis (C.H.N), metal content, (IR, UV-Vis, 1H-NMR) spectroscopy, conductivity and magnetic measurements. The resulted data suggested that the Schiff bases containing ONNO donor atoms acts as dibasic tetradendetate ligands through coordinated with Cu(II). Conductivity data in DMSO solution showed that all complexes are non-electrolyte. Magnetic moment and electronic spectra data indicat that the complexes have either tetrahedral or octahedral geometry. The ligands and their complexes were screened for antibacterial activity against Bacillus and Morganella Morgani. The ligands and their complexes showed some biological activities.
Antibacterial activity, M-phenylenediamine, Schiff base, Unsymmetrical tetradentate
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Birincil Dil en
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Yazar: Moza M. AL-JIBOURY
Kurum: Mosul University
Ülke: Iraq


Yazar: Khansaa Sh. AL-NAMA
Kurum: Mosul University
Ülke: Iraq


Tarihler

Yayımlanma Tarihi : 24 Kasım 2019

Bibtex @araştırma makalesi { epstem655372, journal = {The Eurasia Proceedings of Science Technology Engineering and Mathematics}, issn = {}, eissn = {2602-3199}, address = {isresoffice@gmail.com}, publisher = {ISRES Organizasyon Turizm Eğitim Danışmanlık Ltd. Şti.}, year = {2019}, volume = {7}, pages = {155 - 163}, doi = {}, title = {Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases}, key = {cite}, author = {AL-JIBOURY, Moza M. and AL-NAMA, Khansaa Sh.} }
APA AL-JIBOURY, M , AL-NAMA, K . (2019). Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases. The Eurasia Proceedings of Science Technology Engineering and Mathematics , 7 () , 155-163 . Retrieved from https://dergipark.org.tr/tr/pub/epstem/issue/50288/655372
MLA AL-JIBOURY, M , AL-NAMA, K . "Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases". The Eurasia Proceedings of Science Technology Engineering and Mathematics 7 (2019 ): 155-163 <https://dergipark.org.tr/tr/pub/epstem/issue/50288/655372>
Chicago AL-JIBOURY, M , AL-NAMA, K . "Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases". The Eurasia Proceedings of Science Technology Engineering and Mathematics 7 (2019 ): 155-163
RIS TY - JOUR T1 - Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases AU - Moza M. AL-JIBOURY , Khansaa Sh. AL-NAMA Y1 - 2019 PY - 2019 N1 - DO - T2 - The Eurasia Proceedings of Science Technology Engineering and Mathematics JF - Journal JO - JOR SP - 155 EP - 163 VL - 7 IS - SN - -2602-3199 M3 - UR - Y2 - 2020 ER -
EndNote %0 The Eurasia Proceedings of Science Technology Engineering and Mathematics Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases %A Moza M. AL-JIBOURY , Khansaa Sh. AL-NAMA %T Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases %D 2019 %J The Eurasia Proceedings of Science Technology Engineering and Mathematics %P -2602-3199 %V 7 %N %R %U
ISNAD AL-JIBOURY, Moza M. , AL-NAMA, Khansaa Sh. . "Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases". The Eurasia Proceedings of Science Technology Engineering and Mathematics 7 / (Kasım 2019): 155-163 .
AMA AL-JIBOURY M , AL-NAMA K . Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases. EPSTEM. 2019; 7: 155-163.
Vancouver AL-JIBOURY M , AL-NAMA K . Synthesis, Characterization and Biological Activity of Binuclear Cu(II) Complexes with Unsymmetrical Brighted Tetradentate Schiff Bases. The Eurasia Proceedings of Science Technology Engineering and Mathematics. 2019; 7: 163-155.