Yıl 2019, Cilt 7 , Sayı , Sayfalar 220 - 227 2019-11-24

Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide

Afyaa M. YOUNUS [1] , İhsan A. MUSTAFA [2]


The work presented in research describes the preparation and characterization of new complexes resulted from the reaction of diaminothiuramdisulfide(tds)with metals (or metals chlorides)of group(VIII)[Na2pdcl4,Pt(0) and K2ptcl4]in addition to group(IB)metals[Ag(0) ,AgCl and Au(o)]. The thiuramdisulfide compound (tds) reduced to the corresponding aminodithiocarbamate anion (H2NNHCS2)-in some complexes(Oxidative addition reaction ) However, in the remaining complexes the (tds)were simply added to the metal chloride ( addition reaction) without cleavage of the –S-S-bond.the resulting complexes can be classified as follows. I-The oxidative addition reactions offered complexes of the type: 1-[M(L)2]((Where L=H2NNHCS2-(aminodithiocarbamate anion) and M=Pd(II),Pt(II) , Ag(II ))and [Ag2(L)4NiCl2]. 2-[M(L)3][M=Au(III)]in addition to the complexes [Au(L)3(1,10 –Phen)] . II-The addition reactions resulted in the formation of the complexes [M(tds)Cl2] whene Pt(II).The prepared complexes were characterized using molar conductivity, UV-Vis and IR spectra in addition to magnetic measurements and metal analysis by atomic absorption .The results suggest a tetra-or hexa-coordinated complexes and also displayed the importance of using different solvents upon the type of reaction and prodect.
Diaminothiuramdisulfide, Metals, Coordinated complexes
  • Angeli, E., Wagner, J., Lawrick, E., Moore, K., Anderson, M., Soderland, L., & Brizee, A. (2010, May 5). General format. Retrieved from http://owl.english.purdue.edu/owl/resource/560/01/ Calfee, R. C., & Valencia, R. R. (1991). APA guide to preparing manuscripts for journal publication. Washington, DC: American Psychological Association. Duncan, G. J., & Brooks-Gunn, J. (Eds.). (1997). Consequences of growing up poor. New York, NY: Russell Sage Foundation. Harlow, H. F. (1983). Fundamentals for preparing psychology journal articles. Journal of Comparative and Physiological Psychology, 55, 893-896. Helfer, M. E., Kempe, R. S., & Krugman, R. D. (1997). The battered child (5th ed.). Chicago, IL: University of Chicago Press. Henry, W. A., III. (1990, April 9). Making the grade in today's schools. Time, 135, 28-31. Lastname, F. N. (Year). Title of dissertation. (Doctoral dissertation). Retrieved from Name of database. (Accession or Order Number) Lastname, F. N. (Year). Title of dissertation. (Unpublished doctoral dissertation). Name of Institution, Location. O'Neil, J. M., & Egan, J. (1992). Men's and women's gender role journeys: A metaphor for healing, transition, and transformation. In B. R. Wainrib (Ed.), Gender issues across the life cycle (pp. 107-123). New York, NY: Springer. Plath, S. (2000). The unabridged journals. K. V. Kukil (Ed.). New York, NY: Anchor. Schnase, J. L., & Cunnius, E. L. (Eds.). (1995). Proceedings from CSCL '95: The First International Conference on Computer Support for Collaborative Learning. Mahwah, NJ: Erlbaum. Schultz, S. (2005, December 28). Calls made to strengthen state energy policies. The Country Today, pp. 1A, 2A. Scruton, R. (1996). The eclipse of listening. The New Criterion, 15(30), 5-13.
Birincil Dil en
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Yazar: Afyaa M. YOUNUS
Kurum: University of Mosul
Ülke: Iraq


Yazar: İhsan A. MUSTAFA
Kurum: University of Mosul
Ülke: Iraq


Tarihler

Yayımlanma Tarihi : 24 Kasım 2019

Bibtex @araştırma makalesi { epstem656365, journal = {The Eurasia Proceedings of Science Technology Engineering and Mathematics}, issn = {}, eissn = {2602-3199}, address = {isresoffice@gmail.com}, publisher = {ISRES Organizasyon Turizm Eğitim Danışmanlık Ltd. Şti.}, year = {2019}, volume = {7}, pages = {220 - 227}, doi = {}, title = {Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide}, key = {cite}, author = {YOUNUS, Afyaa M. and MUSTAFA, İhsan A.} }
APA YOUNUS, A , MUSTAFA, İ . (2019). Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide. The Eurasia Proceedings of Science Technology Engineering and Mathematics , 7 () , 220-227 . Retrieved from https://dergipark.org.tr/tr/pub/epstem/issue/50288/656365
MLA YOUNUS, A , MUSTAFA, İ . "Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide". The Eurasia Proceedings of Science Technology Engineering and Mathematics 7 (2019 ): 220-227 <https://dergipark.org.tr/tr/pub/epstem/issue/50288/656365>
Chicago YOUNUS, A , MUSTAFA, İ . "Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide". The Eurasia Proceedings of Science Technology Engineering and Mathematics 7 (2019 ): 220-227
RIS TY - JOUR T1 - Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide AU - Afyaa M. YOUNUS , İhsan A. MUSTAFA Y1 - 2019 PY - 2019 N1 - DO - T2 - The Eurasia Proceedings of Science Technology Engineering and Mathematics JF - Journal JO - JOR SP - 220 EP - 227 VL - 7 IS - SN - -2602-3199 M3 - UR - Y2 - 2020 ER -
EndNote %0 The Eurasia Proceedings of Science Technology Engineering and Mathematics Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide %A Afyaa M. YOUNUS , İhsan A. MUSTAFA %T Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide %D 2019 %J The Eurasia Proceedings of Science Technology Engineering and Mathematics %P -2602-3199 %V 7 %N %R %U
ISNAD YOUNUS, Afyaa M. , MUSTAFA, İhsan A. . "Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide". The Eurasia Proceedings of Science Technology Engineering and Mathematics 7 / (Kasım 2019): 220-227 .
AMA YOUNUS A , MUSTAFA İ . Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide. EPSTEM. 2019; 7: 220-227.
Vancouver YOUNUS A , MUSTAFA İ . Characterization and Comparison of the Reaction Product of (Pd, Pt, Ag and Au) in Different Solvent with Diaminothiuramdisulfide. The Eurasia Proceedings of Science Technology Engineering and Mathematics. 2019; 7: 227-220.