Erzincan University Journal of Science and Technology

2149-4584

Erzincan Binali Yıldırım Üniversitesi

10.18185/erzifbed.1384410

Separation Science

Separasyon Bilimi

Use of Activated and Modified Pumice Stone for Removal of Mercury (II) and Arsenic (III) Ions From Aqueous Solution

https://orcid.org/0000-0002-2490-2741

Tirtom

Vedia Nüket

MANİSA CELÂL BAYAR ÜNİVERSİTESİ

08 31 2024

17 2 308 326 11 01 2023 05 28 2024

2008

Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi

Removal of Hg (II) and As (III) ions from aqueous solutions using activated and modified pumice stone were investigated. The pH, temperature, initial metal ion concentration which are very important for removal studies, were investigated by batch method. The experiments demonstrated that the equilibrium adsorption data ﬁt the Freundlich isotherm model well for Hg (II) and As (III) ions. The negative value of ΔH° = -199.92 kJ mol-1 and -78,15 kJ mol-1 for mercury (II) and arsenic (III) ions indicates that the adsorption process is exothermic. ΔS° were calculated as -267.85 J K-1 mol-1 for As (III) ions and the positive value of ΔS° = 0.69 kJ K-1 mol-1 for Hg (II) ions. The negative value of ΔG°=-405.14 kJ mol-1 for Hg (II) ions and -1.67 kJ mol-1 for As (III) ions indicates that adsorption is voluntary. EDTA has been found to be a good desorbent in desorption studies to recover arsenic and Hg ions. The experiments show that pumice stone can be used for Hg (II) and As (III) removal in aqueous solution.

Adsorption Arsenic Mercury Pumice stone Wastewater

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