SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES

Elvan Sayın; Güneş Süheyla Kürkçüoğlu

doi:10.18038/estubtda.1229463

TR EN

SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES

Abstract

In this investigation, we present synthesis and characterized of three new heteropolynuclear cyanide complexes with 2-(Hydroxymethyl)pyridine (hmpH) of [M(H2O)(hmpH)Ni(CN)4]2·nH2O, (M(II) = Fe, Co and Ni); n = 12 for Fe, 2 for Co and Ni). The obtained complexes have been studied by elemental, thermal analysis, FT-IR, and Raman spectroscopic measurement techniques. Considering the alterations in characteristic peaks of cyanide, aqua, and hmpH ligands, general knowledge about the structural features of the complexes was detected from the vibrational spectra. The Ni(II) ion is coordinated by four cyanide-carbon atoms forming a square planar geometry. In addition, thermal analyses and electrical features of the complexes were investigated.

Keywords

Cyanide complex, Tetracyanonickelate(II) complex, 2-(Hydroxymethyl)pyridine complex, FT-IR and Raman spectra, Thermal analyses

Supporting Institution

The Research Fund of Eskişehir Osmangazi University.

Project Number

201319D14

Thanks

This paper is dedicated to Prof. Dr. Ziya KANTARCI, who died on January, 2012.

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Details

Primary Language

English

Subjects

Atomic and Molecular Physics

Journal Section

Research Article

Authors

Elvan Sayın ^*
0000-0001-7379-1817
Palestine

Güneş Süheyla Kürkçüoğlu
0000-0003-3945-3085
Türkiye

Publication Date

December 27, 2023

Submission Date

January 5, 2023

Acceptance Date

December 19, 2023

Published in Issue

Year 2023 Volume: 24 Number: 4

DOI

https://doi.org/10.18038/estubtda.1229463

IZ

https://izlik.org/JA52LM52SK

APA

Sayın, E., & Kürkçüoğlu, G. S. (2023). SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering, 24(4), 216-229. https://doi.org/10.18038/estubtda.1229463

AMA

1.Sayın E, Kürkçüoğlu GS. SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES. Estuscience - Se. 2023;24(4):216-229. doi:10.18038/estubtda.1229463

Chicago

Sayın, Elvan, and Güneş Süheyla Kürkçüoğlu. 2023. “SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES”. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering 24 (4): 216-29. https://doi.org/10.18038/estubtda.1229463.

EndNote

Sayın E, Kürkçüoğlu GS (December 1, 2023) SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering 24 4 216–229.

IEEE

[1]E. Sayın and G. S. Kürkçüoğlu, “SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES”, Estuscience - Se, vol. 24, no. 4, pp. 216–229, Dec. 2023, doi: 10.18038/estubtda.1229463.

ISNAD

Sayın, Elvan - Kürkçüoğlu, Güneş Süheyla. “SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES”. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering 24/4 (December 1, 2023): 216-229. https://doi.org/10.18038/estubtda.1229463.

JAMA

1.Sayın E, Kürkçüoğlu GS. SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES. Estuscience - Se. 2023;24:216–229.

MLA

Sayın, Elvan, and Güneş Süheyla Kürkçüoğlu. “SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES”. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 24, no. 4, Dec. 2023, pp. 216-29, doi:10.18038/estubtda.1229463.

Vancouver

1.Elvan Sayın, Güneş Süheyla Kürkçüoğlu. SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES. Estuscience - Se. 2023 Dec. 1;24(4):216-29. doi:10.18038/estubtda.1229463

SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES

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SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES

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