SYNTHESIS OF ALUMINA FROM KAOLIN FOUND IN AJEBO, OGUN STATE, NIGERIA

This study proposes the utilization of kaolin as an alternate resource for alumina production due to the decreasing availability of bauxite ores in Nigeria. This project covers the procedures and operations required to produce a high surface area γ-alumina using kaolin, a refractory material. The kaolin used in this study was sourced from Ajebo in Ogun State, Nigeria. The mineral processing of kaolin was the initial step involving removing inherent impurities from the clay. Subsequently, calcination was performed to eliminate crystallised water and impurities and activate the kaolin's limited alumina content. This activation process facilitated the subsequent acid-leaching reactions. At 90oC, 5M HCl acid was used to leach meta-kaolin, which was then filtered. The filtrate was mixed with 5M NaOH at 900oC and was transformed into sodium aluminate. This reaction also facilitated the removal of magnesium and iron hydroxides. Subsequently, HCl was introduced to adjust the pH of the solution. The resulting aluminium hydroxide was then calcinated at temperatures of 700oC and 900oC for 2 hours each to produce γ-alumina. Ultimately, the calcined material was cooled to ambient temperature inside the furnace. The produced γ-alumina was further characterised using X-ray Fluorescence (XRF), Fourier Transform Infrared spectrometer (FTIR), and Scanning Electron Microscopy (SEM).

This study proposes the utilization of kaolin as an alternate resource for alumina production due to the decreasing availability of bauxite ores in Nigeria. This project covers the procedures and operations required to produce a high surface area γ-alumina using kaolin, a refractory material. The kaolin used in this study was sourced from Ajebo in Ogun State, Nigeria. The mineral processing of kaolin was the initial step involving removing inherent impurities from the clay. Subsequently, calcination was performed to eliminate crystallised water and impurities and activate the kaolin's limited alumina content. This activation process facilitated the subsequent acid-leaching reactions. At 90oC, 5M HCl acid was used to leach meta-kaolin, which was then filtered. The filtrate was mixed with 5M NaOH at 900oC and was transformed into sodium aluminate. This reaction also facilitated the removal of magnesium and iron hydroxides. Subsequently, HCl was introduced to adjust the pH of the solution. The resulting aluminium hydroxide was then calcinated at temperatures of 700oC and 900oC for 2 hours each to produce γ-alumina. Ultimately, the calcined material was cooled to ambient temperature inside the furnace. The produced γ-alumina was further characterised using X-ray Fluorescence (XRF), Fourier Transform Infrared spectrometer (FTIR), and Scanning Electron Microscopy (SEM).