VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE

Dursun Karaağaç

doi:10.18038/estubtda.624414

EN

VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE

Abstract

New cyano-bridged polymeric complexes formulated as [Co(H₂O)(ampy)Ni(CN)₄]∙H₂O and [Ni(ampy)₂Ni(CN)₄]∙H₂O (ampy = 3-aminomethylpyridine: abbreviated henceforth as Co-Ni-ampy and Ni-Ni-ampy) have been obtained in powder form and characterized by vibrational (infrared and Raman) spectroscopy, thermal and elemental analyses. In previous study, structure of complex [Cd(NH₃)(ampy)Ni(CN)₄]_n (Cd-Ni-ampy) was determined by single crystal X-ray diffraction methods. In this complex, the coordination environment of the Cd(II) ions are distorted octahedral geometry, whereas around the Ni(II) center is pyramidal. The spectral features suggest that Cd-Ni-ampy with Co-Ni-ampy are similar to each other and the ampy ligand is coordinated to metal ions as bidentate ligand. In addition, complex Ni-Ni-ampy is similar in structure to the Hofmann type complexes and its structure consists of polymeric layers of │Ni–Ni(CN)₄│_∞ with the ampy ligand bounded to the nickel(II) atom. Thermal stabilities and decomposition products of the complexes were investigated using TG, DTG and DTA curves in the temperature range of 30 – 700 °C in the static air atmosphere.

Keywords

Vibrational spectra,Tetracyanonickelate(II),3-aminomethylpyridine,Cyano-bridged complexes,Pyramidal

Supporting Institution

This work was supported by the Research Fund of Eskişehir Osmangazi University

Project Number

Project number: 201219024

Thanks

I would like to thank Prof. Dr. Güneş Süheyla Kürkçüoğlu for his support in writing of this article.

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Dursun Karaağaç ^*
0000-0003-3504-6765

Publication Date

September 26, 2019

Submission Date

August 8, 2018

Acceptance Date

August 28, 2019

Published in Issue

Year 2019 Volume: 20 Number: 3

DOI

https://doi.org/10.18038/estubtda.624414

IZ

https://izlik.org/JA38KN25PD

APA

Karaağaç, D. (2019). VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering, 20(3), 216-226. https://doi.org/10.18038/estubtda.624414

AMA

1.Karaağaç D. VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE. Estuscience - Se. 2019;20(3):216-226. doi:10.18038/estubtda.624414

Chicago

Karaağaç, Dursun. 2019. “VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE”. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering 20 (3): 216-26. https://doi.org/10.18038/estubtda.624414.

EndNote

Karaağaç D (September 1, 2019) VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering 20 3 216–226.

IEEE

[1]D. Karaağaç, “VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE”, Estuscience - Se, vol. 20, no. 3, pp. 216–226, Sept. 2019, doi: 10.18038/estubtda.624414.

ISNAD

Karaağaç, Dursun. “VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE”. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering 20/3 (September 1, 2019): 216-226. https://doi.org/10.18038/estubtda.624414.

JAMA

1.Karaağaç D. VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE. Estuscience - Se. 2019;20:216–226.

MLA

Karaağaç, Dursun. “VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE”. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 20, no. 3, Sept. 2019, pp. 216-2, doi:10.18038/estubtda.624414.

Vancouver

1.Dursun Karaağaç. VIBRATIONAL SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF THE CYANO-BRIDGED POLYMERIC COMPLEXES WITH 3-AMINOMETHYLPYRIDINE. Estuscience - Se. 2019 Sep. 1;20(3):216-2. doi:10.18038/estubtda.624414

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