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Lanthanide doped bismuth tungstates: an investigation for LED and photocatalysis applications

Year 2018, Volume: 19 Issue: 4, 1001 - 1012, 31.12.2018
https://doi.org/10.18038/aubtda.412443

Abstract

In this work, we studied optical, photocatalytic and photoelectrochemical properties of a series of lanthanide-doped double layered Aurivillius type bismuthoxides. The visible-light harvesting photocatalysts doped with Eu, Pr, Nd, Tm, Ho and Ceions were synthesized by solid-state synthesis method using lanthanide precursors ranging from 0.2 to 10 mol % and were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Furthermore, luminescence of Pr and Euion doped catalysts are evaluated. Photoelectrochemical behaviour of the powders was also investigated. Best photoelectrochemical response is achieved with Tm ion doped sample.

References

  • [1 ] Kubacka A, Fernández-García M, Colón G. Advanced nanoarchitectures for solar photocatalytic applications. Chem Rev 2012; 112: 1555–1614.
  • [2 ] Zhang G, Lü F, Li M, Yang J, Zhang X, Huang B. Synthesis of nanometer Bi2WO6 synthesized by sol-gel method and its visible-light photocatalytic activity for degradation of 4BS. J Phys Chem Solids 2010; 71: 579–582.
  • [3 ] Amano F, Nogami K, Ohtani B. Enhanced photocatalytic activity of bismuth-tungsten mixed oxides for oxidative decomposition of acetaldehyde under visible light irradiation. Catal Commun 2012; 20: 12–16.
  • [4 ] Zhuo Y, Huang J, Cao L, Ouyang H, Wu J. Photocatalytic activity of snow-like Bi2WO6 microcrystalline for decomposition of Rhodamine B under natural sunlight irradiation. Mater Lett 2013; 90: 107–110.
  • [5 ] Dumrongrojthanath P, Thongtem T, Phuruangrat A, Thongtem S. Synthesis and characterization of hierarchical multilayered flower-like assemblies of Ag doped Bi2WO6 and their photocatalytic activities. Superlattices Microstruct 2013; 64: 196–203.
  • [6 ] Zhang L, Baumanis C, Robben L, Kandiel T, Bahnemann D. Bi 2WO 6 inverse opals: Facile fabrication and efficient visible-light-driven photocatalytic and photoelectrochemical water-splitting activity. Small 2011; 7: 2714–2720.
  • [7 ] Zhang Z, Wang W, Yin W, Shang M, Wang L, Sun S. Inducing photocatalysis by visible light beyond the absorption edge: Effect of upconversion agent on the photocatalytic activity of Bi2WO6. Appl Catal B Environ 2010; 101: 68–73.
  • [8 ] Tian Y, Zhang L, Zhang J. A superior visible light-driven photocatalyst: Europium-doped bismuth tungstate hierarchical microspheres. J Alloys Compd 2012; 537: 24–28.
  • [9 ] Qamar M, Khan A. Mesoporous hierarchical bismuth tungstate as a highly efficient visible-light-driven photocatalyst. RSC Adv 2014; 4: 9542–9542.
  • [10 ] Liu C, Liu J, Zhang G, Zhang J, Wu Q, Xu Y, Sun Y. Facile room-temperature precipitation strategy for Ag2O/Bi2WO6 heterojunction with high simulated sunlight photocatalytic performance via bi-directed electron migration mechanism. RSC Adv 2015; 5: 32333–32342.
  • [11 ] Zhang Z, Wang W, Zhou Y. Hydrothermal synthesis of a novel BiErWO6 photocatalyst with wide spectral responsive property. Appl Surf Sci 2014; 319: 250–255.
  • [12 ] Huang H, Liu K, Chen K, Zhang Y, Zhang Y, Wang S. Ce and F Comodification on the Crystal Structure and Enhanced Photocatalytic Activity of Bi 2 WO 6 Photocatalyst under Visible Light Irradiation. J Phys Chem C 2014; : 140624153631000.
  • [13 ] Kudo A, Hijii S. H2 or O2 Evolution from Aqueous Solutions on Layered Oxide Photocatalysts Consisting of Bi3+ with 6s2 Configuration and d0 Transition Metal Ions. Chem Lett 1999; 28: 1103–1104.
  • [14 ] Cruz AM, Alfaro SO, Torres-Martínez LM, Ramírez IJ. Synthesis of Bi 2 W 2 O 9 from an amorphous complex precursor : characterization and evaluation of its photocatalytical properties. J Ceram Process Res 2008; 9: 490–494.
  • [15 ] Alfaro SO, Martínez-De La Cruz A. Synthesis, characterization and visible-light photocatalytic properties of Bi2WO6 and Bi2W2O9 obtained by co-precipitation method. Appl Catal A Gen 2010; 383: 128–133.
  • [16 ] Hassan MS, Amna T, Yang OB, Kim HC, Khil MS. TiO 2 nanofibers doped with rare earth elements and their photocatalytic activity. Ceram Int 2012; 38: 5925–5930.
  • [17 ] Sin JC, Lam SM, Lee KT, Mohamed AR. Preparation of rare earth-doped ZnO hierarchical micro/nanospheres and their enhanced photocatalytic activity under visible light irradiation. Ceram Int 2014; 40: 5431–5440.
  • [18 ] Stengll V, Bakardjieva S, Murafa N. Preparation and photocatalytic activity of rare earth doped TiO2 nanoparticles. Mater Chem Phys 2009; 114: 217–226.
  • [19 ] Xu X, Ge Y, Li B, Fan F, Wang F. Shape evolution of Eu-doped Bi2WO6 and their photocatalytic properties. Mater Res Bull 2014; 59: 329–336.
  • [20 ] Feldmann C, Jüstel T, Ronda CR, Schmidt PJ. Inorganic luminescent materials: 100 Years of research and application. Adv Funct Mater 2003; 13: 511–516.
  • [21 ] Guan M, Sun J, Tao F, Xu Z. A host crystal for the rare-earth ion dopants: Synthesis of pure and ln-doped urchinlike BiPO4 structure and its photoluminescence. Cryst Growth Des 2008; 8: 2694–2697.
  • [22 ] Zhang ZJ, Chen XY. Sb2MoO6, Bi2MoO6, Sb2WO6, and Bi2WO6 flake-like crystals: Generalized hydrothermal synthesis and the applications of Bi2WO6 and Bi2MoO6 as red phosphors doped with Eu3+ ions. Mater Sci Eng B 2016; : 1–7.
  • [23 ] Guan M, He X, Shang T, Sun J, Zhou Q. Hydrothermal synthesis of ultrathin Bi 2MO 6 (M=W, Mo) nanoplates as new host substances for red-emitting europium ion. Prog Nat Sci Mater Int 2012; 22: 334–340.
  • [24 ] Kumar BV, Veldurthi NK, Reddy JR, Vithal M. Solvothermal synthesis, characterisation, luminescence and photocatalytic activity of Bi2WO6:Eu nanocrystals. Micro Nano Lett 2012; 7: 544.
  • [25 ] Li Y-Y, Cheng W-D, Zhang H, Lin C-S, Zhang W-L, Geng L, Chai G-L, Luo Z-Z, He Z-Z. A series of novel rare-earth bismuth tungstate compounds LnBiW2O9 (Ln=Ce, Sm, Eu, Er): synthesis, crystal structure, optical and electronic properties. Dalton Trans 2011; 40: 7357–7364.
  • [26 ] Tian N, Zhang Y, Huang H, He Y, Guo Y. Influences of Gd substitution on the crystal structure and visible-light-driven photocatalytic performance of Bi2WO6. J Phys Chem C 2014; 118: 15640–15648.
  • [27 ] Feteira A, Sinclair DC. Microwave Dielectric Properties of Low Firing Temperature Bi 2 W 2 O 9 Ceramics. J Am Ceram Soc 2008; 91: 1338–1341.
  • [28 ] Tortosa M, Mollar M, Mari B. Synthesis of ZnCdO thin films by electrodeposition. J Cryst Growth 2007; 304: 97–102.
  • [29 ] Xu A-W, Gao Y, Liu H-Q. The Preparation, Characterization, and their Photocatalytic Activities of Rare-Earth-Doped TiO2 Nanoparticles. J Catal 2002; 207: 151–157.
  • [30 ] Tkachuk AM, Ivanova SE, Mirzaeva AA, Joubert M-F, Guyot Y. Spectroscopic characteristics of praseodymium-doped cubic double sodium-yttrium fluoride crystals Na0.4Y0.6F2.2:Pr3+. Intensities of optical transitions and luminescence kinetics. Opt Spectrosc 2014; 116: 392–407.
  • [31 ] Brown E, Hanley CB, Hömmerich U, Bluiett a. G, Trivedi SB. Spectroscopic study of neodymium doped potassium lead bromide for mid-infrared solid state lasers. J Lumin 2013; 133: 244–248.
  • [32 ] Yıldırım C, Birer Ö. Ultraviolet upconversion spectra of sonochemically synthesized doped NaYF4 crystals. Chem Phys 2014; 445: 46–52.
  • [33 ] Venkateswarlu M, Mahamuda S, Swapna K, Prasad MVVKS, Srinivasa Rao A, Shakya S, Mohan Babu A, Vijaya Prakash G. Holmium doped Lead Tungsten Tellurite glasses for green luminescent applications. J Lumin 2015; 163: 64–71.
  • [34 ] Reszczyńska J, Grzyb T, Sobczak JW, Lisowski W, Gazda M, Ohtani B, Zaleska A. Visible light activity of rare earth metal doped (Er3+, Yb3+ or Er3+/Yb3+) titania photocatalysts. Appl Catal B Environ 2015; 163: 40–49.
  • [35 ] Goodall JBM, Illsley D, Lines R, Makwana NM, Darr JA. Structure-property-composition relationships in doped zinc oxides: Enhanced photocatalytic activity with rare earth dopants. ACS Comb Sci 2015; 17: 100–112.
  • [36 ] Podhorodecki A, Nyk M, Misiewicz J, Strek W. Optical investigation of the emission lines for Eu3+ and Tb3+ ions in the GaN powder host. J Lumin 2007; 126: 219–224.
  • [37 ] Jayaramaiah JR, Lakshminarasappa BN, Nagabhushana BM. Luminescence studies of europium doped yttrium oxide nano phosphor. Sensors Actuators, B Chem 2012; 173: 234–238.
  • [38 ] Jha K, Jayasimhadri M. Structural and emission properties of Eu3+-doped alkaline earth zinc-phosphate glasses for white LED applications. J Am Ceram Soc 2017; 100: 1402–1411.
  • [39 ] Gupta SK, Ghosh PS, Pathak N, Kadam RM. Why host to dopant energy transfer is absent in the MgAl 2 O 4 :Eu 3+ spinel? And exploring Eu 3+ site distribution and local symmetry through its photoluminescence: interplay of experiment and theory. RSC Adv 2016; 6: 42923–42932.
  • [40 ] Gupta SK, Ghosh PS, Sahu M, Bhattacharyya K, Tewari R, Natarajan V. Intense red emitting monoclinic LaPO4:Eu3+ nanoparticles: host–dopant energy transfer dynamics and photoluminescence properties. RSC Adv 2015; 5: 58832–58842.
  • [41 ] Ma̧czka M, Macalika L, Hanuza J. Raman and IR spectra of the cation-deficient Aurivillius layered crystal Bi2W2O9. J Raman Spectrosc 2009; 40: 2099–2103.
  • [42 ] Boronat C, Rivera T, Garcia-Guinea J, Correcher V. Cathodoluminescence emission of REE (Dy, Pr and Eu) doped LaAlO3phosphors. Radiat Phys Chem 2017; 130: 236–242.
  • [43 ] Isasi-Marín J, Pérez-Estébanez M, Díaz-Guerra C, Castillo JF, Correcher V, Cuervo-Rodríguez MR. Structural, magnetic and luminescent characteristics of Pr 3+-doped ZrO2 powders synthesized by a sol-gel method. J Phys D Appl Phys 2009; 42.
  • [44 ] Shaban YA, Khan SUM. Photoresponse of visible light active CM-n-TiO 2, HM-n-TiO 2, CM-n-Fe 2O 3, and CM-p-WO 3 towards water splitting reaction. Int J Photoenergy 2012; 2012.
Year 2018, Volume: 19 Issue: 4, 1001 - 1012, 31.12.2018
https://doi.org/10.18038/aubtda.412443

Abstract

References

  • [1 ] Kubacka A, Fernández-García M, Colón G. Advanced nanoarchitectures for solar photocatalytic applications. Chem Rev 2012; 112: 1555–1614.
  • [2 ] Zhang G, Lü F, Li M, Yang J, Zhang X, Huang B. Synthesis of nanometer Bi2WO6 synthesized by sol-gel method and its visible-light photocatalytic activity for degradation of 4BS. J Phys Chem Solids 2010; 71: 579–582.
  • [3 ] Amano F, Nogami K, Ohtani B. Enhanced photocatalytic activity of bismuth-tungsten mixed oxides for oxidative decomposition of acetaldehyde under visible light irradiation. Catal Commun 2012; 20: 12–16.
  • [4 ] Zhuo Y, Huang J, Cao L, Ouyang H, Wu J. Photocatalytic activity of snow-like Bi2WO6 microcrystalline for decomposition of Rhodamine B under natural sunlight irradiation. Mater Lett 2013; 90: 107–110.
  • [5 ] Dumrongrojthanath P, Thongtem T, Phuruangrat A, Thongtem S. Synthesis and characterization of hierarchical multilayered flower-like assemblies of Ag doped Bi2WO6 and their photocatalytic activities. Superlattices Microstruct 2013; 64: 196–203.
  • [6 ] Zhang L, Baumanis C, Robben L, Kandiel T, Bahnemann D. Bi 2WO 6 inverse opals: Facile fabrication and efficient visible-light-driven photocatalytic and photoelectrochemical water-splitting activity. Small 2011; 7: 2714–2720.
  • [7 ] Zhang Z, Wang W, Yin W, Shang M, Wang L, Sun S. Inducing photocatalysis by visible light beyond the absorption edge: Effect of upconversion agent on the photocatalytic activity of Bi2WO6. Appl Catal B Environ 2010; 101: 68–73.
  • [8 ] Tian Y, Zhang L, Zhang J. A superior visible light-driven photocatalyst: Europium-doped bismuth tungstate hierarchical microspheres. J Alloys Compd 2012; 537: 24–28.
  • [9 ] Qamar M, Khan A. Mesoporous hierarchical bismuth tungstate as a highly efficient visible-light-driven photocatalyst. RSC Adv 2014; 4: 9542–9542.
  • [10 ] Liu C, Liu J, Zhang G, Zhang J, Wu Q, Xu Y, Sun Y. Facile room-temperature precipitation strategy for Ag2O/Bi2WO6 heterojunction with high simulated sunlight photocatalytic performance via bi-directed electron migration mechanism. RSC Adv 2015; 5: 32333–32342.
  • [11 ] Zhang Z, Wang W, Zhou Y. Hydrothermal synthesis of a novel BiErWO6 photocatalyst with wide spectral responsive property. Appl Surf Sci 2014; 319: 250–255.
  • [12 ] Huang H, Liu K, Chen K, Zhang Y, Zhang Y, Wang S. Ce and F Comodification on the Crystal Structure and Enhanced Photocatalytic Activity of Bi 2 WO 6 Photocatalyst under Visible Light Irradiation. J Phys Chem C 2014; : 140624153631000.
  • [13 ] Kudo A, Hijii S. H2 or O2 Evolution from Aqueous Solutions on Layered Oxide Photocatalysts Consisting of Bi3+ with 6s2 Configuration and d0 Transition Metal Ions. Chem Lett 1999; 28: 1103–1104.
  • [14 ] Cruz AM, Alfaro SO, Torres-Martínez LM, Ramírez IJ. Synthesis of Bi 2 W 2 O 9 from an amorphous complex precursor : characterization and evaluation of its photocatalytical properties. J Ceram Process Res 2008; 9: 490–494.
  • [15 ] Alfaro SO, Martínez-De La Cruz A. Synthesis, characterization and visible-light photocatalytic properties of Bi2WO6 and Bi2W2O9 obtained by co-precipitation method. Appl Catal A Gen 2010; 383: 128–133.
  • [16 ] Hassan MS, Amna T, Yang OB, Kim HC, Khil MS. TiO 2 nanofibers doped with rare earth elements and their photocatalytic activity. Ceram Int 2012; 38: 5925–5930.
  • [17 ] Sin JC, Lam SM, Lee KT, Mohamed AR. Preparation of rare earth-doped ZnO hierarchical micro/nanospheres and their enhanced photocatalytic activity under visible light irradiation. Ceram Int 2014; 40: 5431–5440.
  • [18 ] Stengll V, Bakardjieva S, Murafa N. Preparation and photocatalytic activity of rare earth doped TiO2 nanoparticles. Mater Chem Phys 2009; 114: 217–226.
  • [19 ] Xu X, Ge Y, Li B, Fan F, Wang F. Shape evolution of Eu-doped Bi2WO6 and their photocatalytic properties. Mater Res Bull 2014; 59: 329–336.
  • [20 ] Feldmann C, Jüstel T, Ronda CR, Schmidt PJ. Inorganic luminescent materials: 100 Years of research and application. Adv Funct Mater 2003; 13: 511–516.
  • [21 ] Guan M, Sun J, Tao F, Xu Z. A host crystal for the rare-earth ion dopants: Synthesis of pure and ln-doped urchinlike BiPO4 structure and its photoluminescence. Cryst Growth Des 2008; 8: 2694–2697.
  • [22 ] Zhang ZJ, Chen XY. Sb2MoO6, Bi2MoO6, Sb2WO6, and Bi2WO6 flake-like crystals: Generalized hydrothermal synthesis and the applications of Bi2WO6 and Bi2MoO6 as red phosphors doped with Eu3+ ions. Mater Sci Eng B 2016; : 1–7.
  • [23 ] Guan M, He X, Shang T, Sun J, Zhou Q. Hydrothermal synthesis of ultrathin Bi 2MO 6 (M=W, Mo) nanoplates as new host substances for red-emitting europium ion. Prog Nat Sci Mater Int 2012; 22: 334–340.
  • [24 ] Kumar BV, Veldurthi NK, Reddy JR, Vithal M. Solvothermal synthesis, characterisation, luminescence and photocatalytic activity of Bi2WO6:Eu nanocrystals. Micro Nano Lett 2012; 7: 544.
  • [25 ] Li Y-Y, Cheng W-D, Zhang H, Lin C-S, Zhang W-L, Geng L, Chai G-L, Luo Z-Z, He Z-Z. A series of novel rare-earth bismuth tungstate compounds LnBiW2O9 (Ln=Ce, Sm, Eu, Er): synthesis, crystal structure, optical and electronic properties. Dalton Trans 2011; 40: 7357–7364.
  • [26 ] Tian N, Zhang Y, Huang H, He Y, Guo Y. Influences of Gd substitution on the crystal structure and visible-light-driven photocatalytic performance of Bi2WO6. J Phys Chem C 2014; 118: 15640–15648.
  • [27 ] Feteira A, Sinclair DC. Microwave Dielectric Properties of Low Firing Temperature Bi 2 W 2 O 9 Ceramics. J Am Ceram Soc 2008; 91: 1338–1341.
  • [28 ] Tortosa M, Mollar M, Mari B. Synthesis of ZnCdO thin films by electrodeposition. J Cryst Growth 2007; 304: 97–102.
  • [29 ] Xu A-W, Gao Y, Liu H-Q. The Preparation, Characterization, and their Photocatalytic Activities of Rare-Earth-Doped TiO2 Nanoparticles. J Catal 2002; 207: 151–157.
  • [30 ] Tkachuk AM, Ivanova SE, Mirzaeva AA, Joubert M-F, Guyot Y. Spectroscopic characteristics of praseodymium-doped cubic double sodium-yttrium fluoride crystals Na0.4Y0.6F2.2:Pr3+. Intensities of optical transitions and luminescence kinetics. Opt Spectrosc 2014; 116: 392–407.
  • [31 ] Brown E, Hanley CB, Hömmerich U, Bluiett a. G, Trivedi SB. Spectroscopic study of neodymium doped potassium lead bromide for mid-infrared solid state lasers. J Lumin 2013; 133: 244–248.
  • [32 ] Yıldırım C, Birer Ö. Ultraviolet upconversion spectra of sonochemically synthesized doped NaYF4 crystals. Chem Phys 2014; 445: 46–52.
  • [33 ] Venkateswarlu M, Mahamuda S, Swapna K, Prasad MVVKS, Srinivasa Rao A, Shakya S, Mohan Babu A, Vijaya Prakash G. Holmium doped Lead Tungsten Tellurite glasses for green luminescent applications. J Lumin 2015; 163: 64–71.
  • [34 ] Reszczyńska J, Grzyb T, Sobczak JW, Lisowski W, Gazda M, Ohtani B, Zaleska A. Visible light activity of rare earth metal doped (Er3+, Yb3+ or Er3+/Yb3+) titania photocatalysts. Appl Catal B Environ 2015; 163: 40–49.
  • [35 ] Goodall JBM, Illsley D, Lines R, Makwana NM, Darr JA. Structure-property-composition relationships in doped zinc oxides: Enhanced photocatalytic activity with rare earth dopants. ACS Comb Sci 2015; 17: 100–112.
  • [36 ] Podhorodecki A, Nyk M, Misiewicz J, Strek W. Optical investigation of the emission lines for Eu3+ and Tb3+ ions in the GaN powder host. J Lumin 2007; 126: 219–224.
  • [37 ] Jayaramaiah JR, Lakshminarasappa BN, Nagabhushana BM. Luminescence studies of europium doped yttrium oxide nano phosphor. Sensors Actuators, B Chem 2012; 173: 234–238.
  • [38 ] Jha K, Jayasimhadri M. Structural and emission properties of Eu3+-doped alkaline earth zinc-phosphate glasses for white LED applications. J Am Ceram Soc 2017; 100: 1402–1411.
  • [39 ] Gupta SK, Ghosh PS, Pathak N, Kadam RM. Why host to dopant energy transfer is absent in the MgAl 2 O 4 :Eu 3+ spinel? And exploring Eu 3+ site distribution and local symmetry through its photoluminescence: interplay of experiment and theory. RSC Adv 2016; 6: 42923–42932.
  • [40 ] Gupta SK, Ghosh PS, Sahu M, Bhattacharyya K, Tewari R, Natarajan V. Intense red emitting monoclinic LaPO4:Eu3+ nanoparticles: host–dopant energy transfer dynamics and photoluminescence properties. RSC Adv 2015; 5: 58832–58842.
  • [41 ] Ma̧czka M, Macalika L, Hanuza J. Raman and IR spectra of the cation-deficient Aurivillius layered crystal Bi2W2O9. J Raman Spectrosc 2009; 40: 2099–2103.
  • [42 ] Boronat C, Rivera T, Garcia-Guinea J, Correcher V. Cathodoluminescence emission of REE (Dy, Pr and Eu) doped LaAlO3phosphors. Radiat Phys Chem 2017; 130: 236–242.
  • [43 ] Isasi-Marín J, Pérez-Estébanez M, Díaz-Guerra C, Castillo JF, Correcher V, Cuervo-Rodríguez MR. Structural, magnetic and luminescent characteristics of Pr 3+-doped ZrO2 powders synthesized by a sol-gel method. J Phys D Appl Phys 2009; 42.
  • [44 ] Shaban YA, Khan SUM. Photoresponse of visible light active CM-n-TiO 2, HM-n-TiO 2, CM-n-Fe 2O 3, and CM-p-WO 3 towards water splitting reaction. Int J Photoenergy 2012; 2012.
There are 44 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Ceren Yılmaz Akkaya This is me

Uğur Ünal This is me

Publication Date December 31, 2018
Published in Issue Year 2018 Volume: 19 Issue: 4

Cite

AMA Akkaya CY, Ünal U. Lanthanide doped bismuth tungstates: an investigation for LED and photocatalysis applications. Estuscience - Se. December 2018;19(4):1001-1012. doi:10.18038/aubtda.412443