Araştırma Makalesi
BibTex RIS Kaynak Göster
Yıl 2020, Cilt: 21 Sayı: 1, 72 - 85, 31.03.2020
https://doi.org/10.18038/estubtda.545380

Öz

Kaynakça

  • [1] Konstantinou IK, Albanis TA, Petrakis DE and Pomonis PJ, Removal of herbicides from aqueous solutions by adsorption on Al-pillared clays, Fe–Al pillared clays and mesoporous alumina aluminum phosphates, Water Res., vol. 34, no. 12, pp. 3123–3136, Aug. 2000.
  • [2] Muñoz A. et al., Studies on the atmospheric fate of propachlor (2-chloro-N-isopropylacetanilide) in the gas-phase, Atmos. Environ., vol. 49, pp. 33–40, Mar. 2012.
  • [3] Gençten M and Özcan A. A detailed investigation on electro-Fenton treatment of propachlor: Mineralization kinetic and degradation intermediates, Chemosphere, vol. 136, pp. 167–173, Oct. 2015.
  • [4] Gupta PK. Toxicity of herbicides, in Veterinary Toxicology, Elsevier, 2012, pp. 631–652.
  • [5] Martin M, Mengs G, Plaza E, Garbi C, Sanchez M, Gibello A, Gutierrez F and Ferrer E. Propachlor Removal by Pseudomonas Strain GCH1 in an Immobilized-Cell System," Appl. Environ. Microbiol., vol. 66, pp.1190-1194, 2000.
  • [6] Tuzimski T and Rejczak T, Application of HPLC–DAD after SPE/QuEChERS with ZrO2-based sorbent in d-SPE clean-up step for pesticide analysis in edible oils, Food Chem., vol. 190, pp. 71–79, Jan. 2016.
  • [7] Qu JR, Zhang JJ, Gao YF and Yang H. Synthesis and utilisation of molecular imprinting polymer for clean-up of propachlor in food and environmental media, Food Chem., vol. 135, no. 3, pp. 1148–1156, Dec. 2012.
  • [8] Atılır Özcan A and Demirli Ş. Molecular Imprinted Solid-Phase Extraction System for the Selective Separation of Oleuropein from Olive Leaf, Sep. Sci. Technol., vol. 49, no. 1, pp. 74–80, 2014.
  • [9] Ambrosini S, Serra M, Shinde S, Sellergren B and Lorenzi E. De, Synthesis and chromatographic evaluation of molecularly imprinted polymers prepared by the substructure approach for the class-selective recognition of glucuronides, J. Chromatogr. A, vol. 1218, no. 39, pp. 6961–6969, 2011.
  • [10] K. Tang, X. Gu, Q. Luo, S. Chen, L. Wu, and J. Xiong, Preparation of molecularly imprinted polymer for use as SPE adsorbent for the simultaneous determination of five sulphonylurea herbicides by HPLC, Food Chem., vol. 150, pp. 106–112, 2014.
  • [11] Guo L, Deng Q, Fang G, Gao W and Wang S. Preparation and evaluation of molecularly imprinted ionic liquids polymer as sorbent for on-line solid-phase extraction of chlorsulfuron in environmental water samples, J. Chromatogr. A, vol. 1218, no. 37, pp. 6271–6277, 2011.
  • [12] Zarejousheghani M, Fiedler P, Möder M and Borsdorf H. Selective mixed-bed solid phase extraction of atrazine herbicide from environmental water samples using molecularly imprinted polymer, Talanta, vol. 129, pp. 132–138, 2014.
  • [13] Azizi A, Bottaro CS. A critical review of molecularly imprinted polymers for the analysis of organic pollutants in environmental water samples, J. Chromatogr. A, https://doi.org/10.1016/j.chroma.2019.460603, 2019.
  • [14] Q. He, J-J. Liang, L-X. Chen, S-L. Chen, H-L. Zheng, H-X. Liu and H-J. Zhang, Removal of the environmental pollutant carbamazepine using molecular imprinted adsorbents: Molecular simulation, adsorption properties, and mechanisms, Wat. Res., vol.168, pp.1-13,2020.
  • [15] Baydemir G, Bereli N, Andaç M, Say R, Galaev IY and Denizli A. Supermacroporous poly(hydroxyethyl methacrylate) based cryogel with embedded bilirubin imprinted particles, React. Funct. Polym., vol. 69, no. 1, pp. 36–42, 2009.
  • [16] Ünlüer ÖB, Özcan A and Uzun L. Preparation of a novel hydrophobic affinity cryogel for adsorption of lipase and its utilization as a chromatographic adsorbent for fast protein liquid chromatography, Biotechnol. Prog., vol. 30, no. 2, pp. 376–382, 2014.
  • [17] Kanekiyo Y, Naganawa R and Tao H. pH-Responsive Molecularly Imprinted Polymers, Angew. Chem. Int. Ed., vol. 42, pp. 3014 – 3016, 2003.
  • [18] Akdamar HA, Yılmaz Sarıözlü N, Atılır Özcan A, Ersöz A, Denizli A, Say R. Separation and purification of hyaluronic acid by glucuronic acid imprintedmicrobeads, Mat. Sci. Engin. C, vol. 29, pp. 1404–1408, 2009.

A NEW MIP EMBEDDED CRYOGEL FOR SELECTIVE PRE-CONCENTRATION AND REMOVAL OF PROPACHLOR

Yıl 2020, Cilt: 21 Sayı: 1, 72 - 85, 31.03.2020
https://doi.org/10.18038/estubtda.545380

Öz

Propachlor is a pesticide
commonly used in the chloroacetanilide herbicide group. Propachlor
contamination occurs in groundwater resources and soil sources. Therefore
removal and also the determination of trace amounts of propachlor is a very
important issue. Molecularly imprinted polymers (MIPS) are preferred for their
advantages such as high affinity, strength, and selectivity in pesticide
removal and determination. In this study, MIP embedded cryogel was synthesized
for selective adsorption and removal of propachlor. MIP synthesis was performed
using the template molecule propachlor, functional monomer methacrylic acid,
crosslinker ethylene glycol dimethacrylate (EDGMA), solvent hexadecane and
2,2-azo-bis-isobutyronitrile (AIBN) as the initiator. Cryogels are a good
alternative for separation and purification because of their advantageous
properties such as short diffusion, low pressure and adsorption and elution in
a short time. The structure of MIP was determined using scanning electron
microscopy (SEM), Elemental analyze and Fourier transform infrared spectroscopy
(FT-IR), and the structure of MIP embedded cryogel was determined using
scanning electron microscopy (SEM). The highest adsorption capacity for MIP was
5.58 mg g-1 at pH 5. The highest adsorption capacity for MIP
embedded cryogel was found to be 14.38 mg g-1. MIP embedded cryogel
were used for selective adsorption and desorption of propachlor in
environmental samples. The concentration of propachlor in environmental samples
was analyzed by high-performance liquid chromatography (HPLC).



 

Kaynakça

  • [1] Konstantinou IK, Albanis TA, Petrakis DE and Pomonis PJ, Removal of herbicides from aqueous solutions by adsorption on Al-pillared clays, Fe–Al pillared clays and mesoporous alumina aluminum phosphates, Water Res., vol. 34, no. 12, pp. 3123–3136, Aug. 2000.
  • [2] Muñoz A. et al., Studies on the atmospheric fate of propachlor (2-chloro-N-isopropylacetanilide) in the gas-phase, Atmos. Environ., vol. 49, pp. 33–40, Mar. 2012.
  • [3] Gençten M and Özcan A. A detailed investigation on electro-Fenton treatment of propachlor: Mineralization kinetic and degradation intermediates, Chemosphere, vol. 136, pp. 167–173, Oct. 2015.
  • [4] Gupta PK. Toxicity of herbicides, in Veterinary Toxicology, Elsevier, 2012, pp. 631–652.
  • [5] Martin M, Mengs G, Plaza E, Garbi C, Sanchez M, Gibello A, Gutierrez F and Ferrer E. Propachlor Removal by Pseudomonas Strain GCH1 in an Immobilized-Cell System," Appl. Environ. Microbiol., vol. 66, pp.1190-1194, 2000.
  • [6] Tuzimski T and Rejczak T, Application of HPLC–DAD after SPE/QuEChERS with ZrO2-based sorbent in d-SPE clean-up step for pesticide analysis in edible oils, Food Chem., vol. 190, pp. 71–79, Jan. 2016.
  • [7] Qu JR, Zhang JJ, Gao YF and Yang H. Synthesis and utilisation of molecular imprinting polymer for clean-up of propachlor in food and environmental media, Food Chem., vol. 135, no. 3, pp. 1148–1156, Dec. 2012.
  • [8] Atılır Özcan A and Demirli Ş. Molecular Imprinted Solid-Phase Extraction System for the Selective Separation of Oleuropein from Olive Leaf, Sep. Sci. Technol., vol. 49, no. 1, pp. 74–80, 2014.
  • [9] Ambrosini S, Serra M, Shinde S, Sellergren B and Lorenzi E. De, Synthesis and chromatographic evaluation of molecularly imprinted polymers prepared by the substructure approach for the class-selective recognition of glucuronides, J. Chromatogr. A, vol. 1218, no. 39, pp. 6961–6969, 2011.
  • [10] K. Tang, X. Gu, Q. Luo, S. Chen, L. Wu, and J. Xiong, Preparation of molecularly imprinted polymer for use as SPE adsorbent for the simultaneous determination of five sulphonylurea herbicides by HPLC, Food Chem., vol. 150, pp. 106–112, 2014.
  • [11] Guo L, Deng Q, Fang G, Gao W and Wang S. Preparation and evaluation of molecularly imprinted ionic liquids polymer as sorbent for on-line solid-phase extraction of chlorsulfuron in environmental water samples, J. Chromatogr. A, vol. 1218, no. 37, pp. 6271–6277, 2011.
  • [12] Zarejousheghani M, Fiedler P, Möder M and Borsdorf H. Selective mixed-bed solid phase extraction of atrazine herbicide from environmental water samples using molecularly imprinted polymer, Talanta, vol. 129, pp. 132–138, 2014.
  • [13] Azizi A, Bottaro CS. A critical review of molecularly imprinted polymers for the analysis of organic pollutants in environmental water samples, J. Chromatogr. A, https://doi.org/10.1016/j.chroma.2019.460603, 2019.
  • [14] Q. He, J-J. Liang, L-X. Chen, S-L. Chen, H-L. Zheng, H-X. Liu and H-J. Zhang, Removal of the environmental pollutant carbamazepine using molecular imprinted adsorbents: Molecular simulation, adsorption properties, and mechanisms, Wat. Res., vol.168, pp.1-13,2020.
  • [15] Baydemir G, Bereli N, Andaç M, Say R, Galaev IY and Denizli A. Supermacroporous poly(hydroxyethyl methacrylate) based cryogel with embedded bilirubin imprinted particles, React. Funct. Polym., vol. 69, no. 1, pp. 36–42, 2009.
  • [16] Ünlüer ÖB, Özcan A and Uzun L. Preparation of a novel hydrophobic affinity cryogel for adsorption of lipase and its utilization as a chromatographic adsorbent for fast protein liquid chromatography, Biotechnol. Prog., vol. 30, no. 2, pp. 376–382, 2014.
  • [17] Kanekiyo Y, Naganawa R and Tao H. pH-Responsive Molecularly Imprinted Polymers, Angew. Chem. Int. Ed., vol. 42, pp. 3014 – 3016, 2003.
  • [18] Akdamar HA, Yılmaz Sarıözlü N, Atılır Özcan A, Ersöz A, Denizli A, Say R. Separation and purification of hyaluronic acid by glucuronic acid imprintedmicrobeads, Mat. Sci. Engin. C, vol. 29, pp. 1404–1408, 2009.
Toplam 18 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Makaleler
Yazarlar

Ayça Atılır Özcan 0000-0003-4402-6280

Melike Özhan Bu kişi benim 0000-0002-9861-5884

Yayımlanma Tarihi 31 Mart 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 21 Sayı: 1

Kaynak Göster

AMA Atılır Özcan A, Özhan M. A NEW MIP EMBEDDED CRYOGEL FOR SELECTIVE PRE-CONCENTRATION AND REMOVAL OF PROPACHLOR. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering. Mart 2020;21(1):72-85. doi:10.18038/estubtda.545380