PHOTOCATALYTIC OXIDATION AND HETEROGENEOUS FENTON APPLICATIONS WITH PAPER INDUSTRY WASTEWATER

Yıl 2020, Cilt: 21 Sayı: 3, 454 - 463, 30.09.2020

Şefika Kaya Yeliz Aşçı

https://doi.org/10.18038/estubtda.623530

Cited By: 1

Öz

Nowadays, leaving industrial
wastewater into receiving environment causes serious environmental problems. In
this study, experimental studies on color and chemical oxygen demand (COD)
removal of paper industrial wastewater were carried out. In this context,
heterogeneous Fenton and photocatalytic oxidation processes were applied and
removal efficiencies were compared. The Fe(III)/MnO₂ catalyst
containing 8% w/w of iron ion was synthesized to be used in experimental
studies. The effects of parameters such as pH, catalyst amount, hydrogen
peroxide concentration and reaction time were investigated. At the end of the
experimental studies, 90% color and 55% COD removal efficiencies were obtained
in heterogeneous Fenton process after 120 minutes reaction time under optimum
conditions. After 60 minutes reaction time under the same optimum conditions,
97% color and 91% COD removal efficiencies were achieved in photocatalytic
oxidation process.

Anahtar Kelimeler

Heterogeneous Fenton, photocatalytic oxidation, Paper,

Destekleyen Kurum

Eskişehir Osmangazi University Scientific Research Projects Commission

Proje Numarası

201615059

Kaynakça

• [1] Sevimli MF. Post-treatment of pulp and paper industry wastewater by advanced oxidation processes. Ozone Sci Eng 2005; 27: 37-43.
• [2] Aydıner C, Doğan EC, Mert BK, Narcı AO, Durna, E, Akbacak UA. Water recovery and concentrated waste minimization from paper wastewater with integrated membrane system. Sakarya University Journal of the Institute of Science and Technology 2017; 21(2): 252-260.
• [3] Catalkaya EC, Kargı F. Color, TOC and AOX removals from pulp mill effluent by advanced oxidation processes: A comparative study. J Hazard Mater 2007; 139: 244-253.
• [4] Kuo WG. Decoloriziting dye Wastewater with Fenton Reagent. Water Res 1992; 26(7): 881-886.
• [5] Mandal T, Maity S, Dasgupta D, Datta S. Advanced Oxidation Process and Biotreatment: Their Roles in Combined Industrial Wastewater Treatment. Desalination 2010; 250(1): 87-94.
• [6] Primo O, Rivero MJ, Ortiz I. Photo-Fenton process as an efficient alternative to the treatment of landfill leachates. J Hazard Mater 2008; 153 (1-2): 834-842.
• [7] Vandevivere PC, Bianchi R, Verstraete W. Treatment and reuse of wastewater from the textile wet‐processing industry: Review of emerging technologies. J Chem Technol Biotechnol 1998; 72(4): 289-302.
• [8] Badawy MI, Wahaab RA, El-Kalliny AS. Fenton-biological Treatment Processes for the Removal of Some Pharmaceuticals from Industrial Wastewater. J Hazard Mater 2009; 167: 567-574.
• [9] Kang S, Liao C, Chen M. Pre-oxidation and coagulation of textile wastewater by the Fenton process. Chemosphere 2002; 46: 923-928.
• [10] Ahn DH, Chang WS, Yoon TI. Dyestuff wastewater treatment using chemical oxidation, physical adsorption and fixed bed biofilm process. Process Biochem 1999; 34: 429-439.
• [11] Soon AN, Hameed BH. Degradation of Acid Blue 29 in visible light radiation using iron modified mesoporous silica as heterogeneous Photo-Fenton catalyst. Appl Catal A 2013; 450: 96-105.
• [12] Navalon S, Alvaro M, Garcia H. Heterogeneous Fenton catalysts based on clays, silicas and zeolites. Appl Catal B 2010; 99: 1-26.
• [13] Nikravan, A. 2015. Amoxicillin and Ampicillin Removal from Wastewater by Fenton and Photo-Fenton Processes. M.Sc. thesis, Hacettepe University, Turkey, 123 p.
• [14] Sun Y, Pignatello JJ. Photochemical reactions involved in the total mineralization of 2,4-D by Fe3+/H2O2/UV. Environ Sci Technol 1993; 27: 304-310.
• [15] Verma A, Chhikara I, Dixit D. Photocatalytic treatment of pharmaceutical industry wastewater over TiO2 using immersion well reactor: synergistic effect coupling with ultrasound. Desalin Water Treat 2014; 52: 6591-6597.
• [16] Argun M. Kinetic and thermodynamic evaluation of cod removal from pharmaceutical industry wastewater by Fenton oxidation. Pamukkale University Journal of Engineering Sciences 2017; 23(9): 1034-1040.
• [17] Alessandro DM, Maria EF, Vittorio P, Giuliana I. ZnO for application in photocatalysis: From thin films to nanostructures. Mater Sci Semicond Process 2017; 69: 44-51.
• [18] Gaya UI, Abdullah AH. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems. J Photochem Photobiol C 2008; 9(1): 1-12.
• [19] Zhang Y, Ram MK, Stefanakos EK, Goswami DY. Synthesis, characterization, and applications of ZnO nanowires. J Nanomater 2012; 2012: 1-22.
• [20] Chen H, Zhang B, Li F, Kuang M, Huang M, Yang Y, Zhang YX. Sculpturingthe core towards mesoporous manganese dioxides nanosheets-Builtnanotubes for pseudocapacitance. Electrochim Acta 2016; 187: 488-495.
• [21] Subramanian V, Zhu H, Vajtai R, Ajayan P, Wei B. Hydrothermal synthesis and pseudocapacitance properties of MnO2 nanostructures. J Phys Chem B 2005; 109: 20207-20214.
• [22] Ayas N, Asci Y, Yurdakul M. Using of Fe/ZrO2 catalyst to remove direct Orange 26 from water by Fenton oxidation at wide pH values. Fresenius Environ Bull 2016; 25: 3272-3279.
• [23] Asci Y, Cam M. Treatment of synthetic dye wastewater by using Fe/CuO particles prepared by co-precipitation: parametric and kinetic studies. Desalin Water Treat 2017; 73: 281-288.
• [24] Schmidt I, Boisen A, Gustavsson E, Staihl K, Pehrson S, Dahl S, Carlsson A, Jacobsen CJH. Carbon Nanotube Templated Growth of Mesoporous Zeolite Single Crystals. Chem Mater 2001; 13: 4416-4418.
• [25] Bautitz IR, Nogueira RFP. Degradation of tetracycline by photo-Fenton process-solar irradiation and matrix effects. J Photochem Photobiol A 2007; 187: 33-39.
• [26] Nomiyama K, Tanizaki TJ, Ishibashi HS, Arizono K, Shinohara R. Production mechanism of hydroxylated PCBs by oxidative degradation of selected PCBs using TiO2 in water and estrogenic activity of their intermediates. Environ Sci Technol 2005; 39: 8762-8769.
• [27] Lin Z, Ma X, Zhao L, Dong Y. Kinetics and products of PCB28 degradation through a goethite-catalyzed Fenton-like reaction. Chemosphere 2014; 101: 15-20.
• [28] Patil PN, Bote SD, Gogate PR. Degradation of imidacloprid using combined advanced oxidation processes based on hydrodynamic cavitation. Ultrason Sonochem 2014; 21: 1770-1777.
• [29] Gagol M, Przyjazny A, Boczkaj G. Wastewater Treatment by Means of Advanced Oxidation Processes Based on Cavtation-A Review. Chem Eng J 2018; 338: 599-627.
• [30] Muruganandham M, Swaminathan M. Decolourisation of Reactive Orange 4 by Fenton and photo-Fenton oxidation technology. Dyes Pigm 2004; 63: 315-321.
• [31] Parsons S. Advanced Oxidation Processes for Water and Wastewater Treatment. IWA Publishing London 2004; 368 p.
• [32] Karthikeyan S, Titus A, Gnanamani A, Mandal AB, Sekaran G. Treatment of textile wastewater by homogeneous and heterogeneous Fenton oxidation processes. Desalination 2011; 281: 438–445.
• [33] Elmolla E, Chaudhuri M. Degradation of the Antibiotics Amoxicillin, Ampicillin and Cloxacillin in Aqueous Solution by the Photo-Fenton Process. Journal of Hazardous Materials 2009; 172: 1476-1481.
• [34] Ju L, Chen Z, Fang L, Dong W, Zheng F, Shen M. Sol–gel synthesis and photo-fenton-like catalytic activity of EuFeO3 nanoparticles. J Am Ceram Soc 2011; 94: 3418-3424.
• [35] Neamtu M, Yediler A, Siminiceanu I, Kettrup A. Oxidation of commercial reactive azo dye aqueous solutions by the photo-Fenton and Fenton-like processes. J Photochem Photobiol 2003; 161: 87-93.
• [36] Akbal F, Balkaya N. Advanced oxidation technologies in removal of toxic organic pollutants. Yildiz Technical University Journal 2002; 4: 47-55.
• [37] Montaser YG, Georg H, Roland M, Roland H. Photochemical Oxidation of Pchlorophenol by UV/H2O2 and Photo-Fenton Process: A Comparative Study. Waste Manage 2001; 21(1): 41-47.