EFFECTS OF POLYMER CONCENTRATION AND TEMPERATURE ON MICELLIZATION OF CETYLTRIMETHYLAMMNIUM BROMIDE (CTAB) IN AQUEOUS PVP-CTAB MIXED SYSTEM

Year 2021, Volume: 22 Issue: 3, 299 - 311, 29.09.2021

Özgür Masalcı

https://doi.org/10.18038/estubtda.913914

Cited By: 2

Abstract

Polymeric micelles supply an environment, which can be cautiously regulated for drug delivery. The self-assembly of polymeric micellization is dynamic. Micellization thermodynamic describes how the system defines the formation of micelles. The present study enables the micellization behavior of the surfactants in the presence of polymer to be examined by conductometric and tensiometric methods. The effects of polymer concentration and temperature on the micellization thermodynamics of a neutral soluble polymer and cationic cetyltrimethylammomium bromide (CTAB) surfactant mixture in aqueous medium were investigated. To examine polymer-surfactant interaction, critical micellar concentration (CMC) and thermodynamic parameters such as standard free energy ∆G, enthalpy ∆H and entropy ∆S are calculated by using a pseudo-phase model. Based on CMC, ΔG, ΔH and ΔH, the dependence of the compensation temperature on the polymer effect is discussed. This advanced work to understand micelle stability and compatibility can be comprehensively feasible in polymeric systems.

Keywords

Polymer-surfactant interaction, micellization, thermodynamic parameters

References

• [1] Bharswaj P, Kamil M, Panda M. Surfactant-polymer interaction :effect of hydroxypropylmethyl cellulose on the surface an solution properties of gemini surfactants. Colloid Polym Sci, 2018; 296: 1879-1889.
• [2] Thiele MJ, Davari MD; Hoffmann I. Enzyme-Compatible Dynamic Nanoreactors from Electrostatically Bridged Like-Charged Surfactants and Polyelectrolytes. Angew Chem Int Ed, 2018; 57: 9402-9407
• [3] Slastanova A, Campbell RA, Snow T, Mould E, Li P, Welbourn RJL, Chen M, Robles E, Briscoe WH. Synergy, competition, and the ‘‘hanging” polymer layer: Interactions between a neutralamphiphilic ‘tardigrade’ combco-polymerwith ananionicsurfactant at the air-water interface, J Colloid Interf Sci, 2020; 561: 81–194
• [4] Kancharla S, Zoyhofski NA, Bufalini L, Chatelais BF, Alexandridis P. Association between Nonionic Amphiphilic Polymer and Ionic Surfactant in Aqueous Solutions: Effect of Polymer Hydrophobicity and Micellization. Polymers, 2020; 12: 1831
• [5] Yang J, Pal R. Investigation of Surfactant-Polymer Interactions Using Rheology and SurfaceTension Measurements. Polymers, 2020; 12: 2302
• [6] Bagheri A. Comparison of the interaction between propranolol hydrochloride (PPL) with anionic surfactant and cationic surface active ionic liquid in micellar phase. Colloids Surf, A Physicochem Eng Asp, 2021; 615: 126183
• [7] Hu C, Du Z, Tai X, Mao X, Liu X. The property study of sodium dodecyl benzenesulfonate and polyvinylpyrrolidone complexes. Colloid Polym Sci, 2018; 296: 335–340
• [8] Hansson P, Almgren M. Interaction of alkyltrimethylammonium surfactants with polyacrylate and poly (styrenesulfonate) in aqueous solution: phase behavior and surfactant aggregation numbers. Langmuir, 1994 ;10: 2115–2124.
• [9] Pettersson E, Topgaard D, Stilbs P, Söderman O. Surfactant/nonionic polymer interaction. A NMR diffusometry and NMR electrophoretic investigation. Langmuir, 2004; 20: 1138–1143.
• [10] Xu L, Yokoyama E, Satoh M. Specific interactions of poly(4-vinyl phenol) gel with cationic and anionic surfactants. Langmuir, 2005; 21: 7153–7160.
• [11] Tajik B, Sohrabi B, Amani R, Hashemianzadeh SM, The study of polymer–surfactant interaction in catanionic surfactant mixtures. Colloids Surf, A Physicochem Eng Asp, 2013; 436: 890–897
• [12] Zhang H, Deng L, Zeeb B, Weiss J, Solubilization of octane in cationic surfactant–anionic polymer complexes: Effect of polymer concentration and temperature, J Colloid Interf Sci, 2015; 450: 332–338
• [13] Nagarajan R. Polymer-Surfactant Interactions. In New Horizons: Detergents for the New Millennium Conference Invited Paper Fort Myers, Fla, USA, 2001.
• [14] Lindman B, Nylander T. Cosmetic Science and Technology, 1st ed. Elsevier, eBook, 2017.
• [15] Kocakülah G, Algül G, Köysal O. Effect of CdSeS/ZnS quantum dot concentration on the electro-optical and dielectric properties of polymer stabilized liquid crystal. J Mol Liq, 2020;299:112182.
• [16] Schreier S, Malheiros SVP, Paula E. Surface active drugs: self-association and interaction with mebranes and surfactants. Physicocehemical and biological aspects. Biochim Biophys Acta, 2000; 1508:210-234.
• [17] Grimaudo MA, Pescina S, Padula C, Santi P, Concheiro A, Alvarez-Lorenzo C, Nicoli S. Topical application of polymeric nanomicelles in ophthalmology: a review on research efforts for the noninvasive delivery of ocular therapeutics. Expert Opin Drug Deliv, 2019;16:397-413.
• [18] Hammer J, Haftka JJH, Scherpenisse P, Hermens JLM, De Voogt P. Investigation hydrophilic and electrostatic properties of surfactants using retention on two mixed-mode liquid chromatographic columns. J Chromatogr A, 2018;1571:185-192.
• [19] Rangel-Yagui CO, Pessoa-Jr A, Tavares LC. Micellar solubilization of drugs. J Pharm Pharmaceut Sci, 2005; 8: 147-163.
• [20] Chiappisi L, Leach SD, Gradzielski M, Precipitating polyelectrolyte–surfactant systems by admixing a nonionic surfactant – a case of cononsurfactancy. Soft Matter 2017; 13: 4988-4996.
• [21] Sardar N, Kamil M, Kabir-ud-Din. Studies on Solution Behavior of Aqueous Mixtures of Nonionic Polymer in Presence of Cationic Surfactants. J Surfact Deterg, 2017; 20: 631–645.
• [22] Rahman F, Ali MS, Al-Lohedan HA, Aazam E, Aldhayan DM, Rafiquee MZA. Influence of PVP-PEG mixed aggregates and electrolytes on the rate of alkaline hydrolysis of benzocaine in aqueous and surfactant medium. J Mol Liq, 2020; 317: 113963
• [23] Cabane B. Structure of some polymer–detergent aggregates in water. J Phys Chem, 1977; 81: 1639–1645
• [24] Gelgec U, Iscan M. Interactions of Polyglycol Ethers with Anionic Surfactants in Water. J Disper Sci Technol, 2010; 31:1667-1672
• [25] Rauf A, Baloch MK, Khan A, Khan Z, Rauf S, Effect of Concentration and Molecular Mass of PEO on The Micellization and Thermodynamic Behaviour of Cetyltrimethylammnium Bromide(CTAB) in Aqueous PEO-CTAB Mixed System. J Chil Chem Soc, 2016; 61: 3013-3017
• [26] Jönsson B, Lindman B, Holmberg K, Kronberg B. Surfactant and Polymers in Aqueous Solution. 1st ed. Chichester, England:John Willey& Sons, 1999.
• [27] Chang H, Du Z, Tai X, Mao X, Liu X. The property study of sodium dodecyl benzenesulfonate and polyvinylpyrrolidone complexes. Colloid Polym Sci, 2018;23:296-335
• [28] Higuchia A, Shiranoa K, Harashimaa M, Yoona BO, Haraa M, Hattorib M, Imamura K. Chemically modified polysulfone hollow fibers with vinylpyrrolidone having improved blood compatibility. Biomaterials, 2002;23:2659:2666.
• [29] Barut KD, Coşkun Arı FF, Öner F. Development and Characterization of a Cationic Emulsion Formulation as a Potential pDNA Carrier System.Turk J Chem, 2005;29:27-40.
• [30] Bali M, Masalci O. Interactions of Cationic Surfactants with Polyvinylpyrrolidone (PVP): Effects of Counter Ions and Temperature. J Mol Liq, 2020; 303: 112576
• [31] Sardar N, Kamil M, Kabir-ud-Din. Interactions between Polyvinylpyrrolidone and Cationic Gemini/Conventional Surfactants. Chem. Eng. Comm, 2013;200: 1683-1700.
• [32] Sanz MA, Granizo N, Gradzielski M, Rodrigo MM, Valiente M. Mixed micellar systems of octylβ,d-glucopyranoside with a nonionic surfactant and a water-soluble polymer. Colloid Polym Sci, 2005; 283: 646–652.
• [33] Capalbi A, La Mesa C. Polymer Surfactant Interactions, J Therm Anal Calorim, 2001; 66: 233-241
• [34] Singh R, Chauhan S, Sharma K, Surface Tension, Viscosity, and Refractive Index of Sodium Dodecyl Sulfate (SDS) in Aqueous Solution Containing Poly(ethylene glycol) (PEG), Poly(vinyl pyrrolidone) (PVP) and Their Blends. J Chem Eng Data, 2017;62: 1955−1964.
• [35] Mahbub S, Molla MR, Saha M, Shahriar I, Hoque MA, Halim MA, Rub MA, Khan MA, Azum N. Conductometric and molecular dynamics studies of the aggregation behavior of sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB) in aqueous and electrolytes solution. J Mol Liq, 2019;283: 263–275.
• [36] Sultana S, Alam MDH, Shumon MAH. Physico-chemical study of the interaction between levofloxacin hemihydrate Drug with Cetylpyridinium chloride in aqueous medium: Conductometric and spectrophotometric investigation. Int J Chem Stud, 2020; 8: 15-26
• [37] Ali A, Uzair S, Malik NA, Ali M. Study of interaction between cationic surfactants and cresol red dye by electrical conductivity and spectroscopy methods. J Mol Liq, 2014; 196: 395–403.
• [38] Soni SS, Sastry NV, Aswal VK, Goyal PS. Micellar Structure of Silicone Surfactants in Water from Surface Activity, SANS and Viscosity Studies. J Phys Chem B, 2002; 106: 2606–2617
• [39] Hoque MA, Patoary MOF, Rashid M, Molla MR, Rub MA. Physico-chemical Investigation of Mixed Micelle Formation Between Tetradecyltrimethylammonium Bromide and Dodecyltrimethylammonium Chloride in Water and Aqueous Solutions of Sodium Chloride. J Solution Chem, 2017; 46: 682–703.
• [40] Khan Z, Malik MA, AL-Thabaiti SA, Alshehri A, Nabi F. Micellization and Thermodynamic Properties of Cationic Surfactant Cetyltrimethylammonium Bromide in non-Aqueous Mixture of Lauric Acid. Int J Electrochem Sci, 2017; 12: 4528–4542
• [41] Gharibi H, Rafat AA, Feizollahi A, Razavizadeh BM, Safarpour MA. Thermodynamic studies of interaction between cationic surfactants and polyvinylpyrrolidone using potentiometric techniques. Colloid Surface A, 1998; 145: 47–60.
• [42] Dubey N. CTAB aggregation in solutions of higher alcohols: Thermodynamic and spectroscopic studies. J Mol Liq, 2013; 184: 60–67.
• [43] Rahman M, Hoque MA, Rub MA, Khan MA. Interaction of cetyltrimethylammonium bromide with cefixime trihydrate drug at different temperatures and compositions: Effect of different electrolytes. Chin J Chem Eng, 2019; 27: 1895-1903.
• [44] Nusselder JJH, Engberts JBFN. Toward a better understanding of the driving force for micelle formation and micellar growth. J Colloid Interface Sci, 1992; 148 : 353-361
• [45] Molla MR, Rub MA, Ahmed A, Hoque MA. Interaction between tetradecyltrimethylammonium bromide and benzyldimethylhexadecylammonium chloride in aqueous/urea solution at various temperatures: An experimental and theoretical investigation. J Mol Liq, 2017; 238: 62-70.
• [46] Chauhan S, Singh R, Sharma K, Kumar K. Interaction Study of Anionic Surfactant with Aqueous Non-Ionic Polymers from Conductivity, Density and Speed of Sound Measurements. J Surfact Deterg, 2015; 18: 225-232.
• [47] Chauhan S, Sharma K. Effect of temperature and additives on the critical micelle concentration and thermodynamics of micelle formation of sodium dodecyl benzene sulfonate and dodecyltrimethylammonium bromide in aqueous solution: A conductometric study. J. Chem. Thermodyn, 2014; 71: 205–211.
• [48] Bao H, Li L, Gan LH, Zhang H. Interactions between Ionic Surfactants and Polysaccharides in Aqueous Solutions. Macromolecules, 2008; 41:9406-9412.