THE INFLUENCE OF PROCESS PARAMETERS ON THE PROPERTIES OF GLASS FOAM PRODUCED FROM INDUSTRIAL WASTE GLASS USING SiC AS THE FOAMING AGENT

Year 2022, Volume: 23 Issue: 1, 21 - 36, 30.03.2022

Abdulkadir Sarı , Recep Akdeniz , Ali Murat Soydan , Ömer Yıldız

https://doi.org/10.18038/estubtda.798575

Abstract

Keywords

Insulation materials, Glass foam, Waste glass, Foaming agent, SiC

Supporting Institution

Vefa Prefabrike Yapılar San. Tic. A.Ş.

Project Number

Tübitak 1501/Vefa Prefabike Yapılar San. Tic. A.Ş.

THE INFLUENCE OF PROCESS PARAMETERS ON THE PROPERTIES OF GLASS FOAM PRODUCED FROM INDUSTRIAL WASTE GLASS USING SiC AS THE FOAMING AGENT

Abstract

Glass foams having a low bulk density, 0.22-0.36 g.cm-3 were produced using waste glass as the raw material and SiC as the foaming agent.. The produced glass foam has very high insulation performance with a very low thermal conductivity of 0.045-0.065 W.m-1.K-1, making it suitable for thermal and acoustic applications. Despite its highly porous structure, it exhibits a very high compressive strength between 0.08-6.99 MPa and a good dimensional stability. The environmentally friendly glass foam produced in this study has a potential as a structural and insulation material in construction applications. Nano-sized foaming agents enhances the efficiency of the reaction in the manufacturing process. The properties such as volume change, weight loss, microstructure, the mineralogical structure, the sintered bulk density, and the porosity of the prepared samples were measured and analyzed. The characterization of the thermal and the mechanical properties of the samples was performed by testing their compressive strength, and thermal conductivity.

Keywords

insulation materials, glass foam, waste glass, foaming agent, SiC

Project Number

Tübitak 1501/Vefa Prefabike Yapılar San. Tic. A.Ş.

References

• [1] Scarinci G, BrusatinG, Bernardo E, “Glass foams”, p. 158–176, in “Cellular ceramics: structure, manufacturing, properties and applications”. Edited by M. Scheffler, P. Colombo, Wiley-VCH Verlag GmbH & Co., Weinheim, 2005.
• [2] Bayer G. Foaming of borosilicate glasses by chemical reactions in the temperature range 950-1150ºC, Journal of Non-Crystalline Solids, 1980; 38 & 39,855–860.
• [3] Bernardo E, Cedro R, Florean M, Hreglich S. Reutilization and stabilization of wastes by the production of glass foams, Ceramics International, 2007; 33, 963–968.
• [4] Bernardo E, Albertini F. Glass foams from dismantled cathode ray tubes, Ceramics International, 2006; 32, 603–608.
• [5] Fernandes HR, Tulyaganov DU, Ferreira JMF. Preparation and characterization of foams from sheet glass and fly ash using carbonates as foaming agents, Ceramics International, 2009; 35 229–235.
• [6] Arriagada C, Navarrete I, Lopez M, Understanding the effect of porosity on the mechanical and thermal performance of glass foam lightweight aggregates and the influence of production factors. Construction and Building Materials, 2019; 228, 116746.
• [7] Rincón A. Novel ‘inorganic gel casting’process for the manufacturing of glass foams. Journal of the European Ceramic Society, 2017; 37(5), 2227–2234.
• [8] Gong Y et al. Recycling of waste amber glass and porcine bone into fast sintered and high strength glass foams. Journal of Cleaner Production, 2016; 112, 4534–4539.
• [9] Souza MT. Glass foams produced from glass bottles and eggshell wastes. Process Safety and Environmental Protection, 2017; 111, 60–64.
• [10] Fernandes HR, Tulyaganov DU, Ferreira JMF. Production and characterisation of glass ceramic foams from recycled raw materials, Advances in Applied Ceramics, 2009; 108 9–13.
• [11] Zhang Q, He F, Shu H et al. Xie, Preparation of high strength glass ceramic foams from waste cathode ray tube and germanium tailings, Construction and Building Materials, 2016; 111, 105–110.
• [12] Qu Y-N, Xu J, Su Z-G, et al. Lightweight and high-strength glass foams prepared by a novel green spheres hollowing technique, Ceramics International, 2016; 42, 2370–2377.
• [13] Zhu M, Ji R, Li Z, et al. Preparation of glass ceramic foams for thermal insulation applications from coal fly ash and waste glass, Construction and Building Materials 112 (2016) 398–405.
• [14] Spiridonov YA, Orlova LA. Problems of foam glass production, Glass and Ceramics, 2003; 60 (9-10) 313–314.
• [15] König J, Petersen RR, Yue Y. Influence of the glass particle size on the foaming process and physical characteristics of foam glasses, Journal of Non-Crystalline Solids, 2016; 447 190–197.
• [16] Nommeots-Nomm A. Highly degradable porous melt-derived bioactive glass foam scaffolds for bone regeneration. Acta biomaterialia, 2017; 57 449–461.
• [17] Poologasundarampillai G. Compressive strength of bioactive sol–gel glass foam scaffolds. International Journal of Applied Glass Science, 2016; 7(2) 229–237.
• [18] Attila Y, Güden M, Taşdemirci A. Foam glass processing using a polishing glass powder residue, Ceramics International, 2013; 39 5869–5877.
• [19] Liao Y-C, Huang C-Y. Glass foam from the mixture of reservoir sediment and Na2CO3, Ceramics International, 2012; 38 4415–4420.
• [20] Qu Y-N, Su, Z-G, Xu J, et al. Preparation of ultralight glass foams via vacuum-assisted foaming, Materials Letters, 2016; 166 35–38.
• [21] Méar F, Yot P, Viennois R, Ribes M. Mechanical behaviour and thermal and electrical properties of foam glass, Ceramics International, 2007; 33 543–550.
• [22] Méar F, Yot P, Cambon M, Ribes M. The changes in lead silicate glasses induced by the addition of a reducing agent (TiN or SiC), Journal of Non-Crystalline Solids, 2005; 351 3314–3319.
• [23] Méar F, Yot P, Ribes M. Effects of temperature, reaction time and reducing agent content on the synthesis of macroporous foam glasses from waste funnel glasses, Materials Letters 2006; 60 929–934.
• [24] König J, Petersen RR, Yue Y.Influence of the glass–calcium carbonate mixture’s characteristics on the foaming process and the properties of the foam glass, Journal of the European Ceramic Society, 2014; 34 1591–1598.
• [25] Bento AC, Kubaski ET, SequinelT. et al. Glass foam of macroporosity using glass waste and sodium hydroxide as the foaming agent, Ceramics International, 2013; 39, 2423–2430.
• [26] Hesky D, Aneziris CG, Groß U, Horn A. Water and water glass mixtures for foam glass production, Ceramics International, 2015; 41, 12604–12613.
• [27] Llaudis AS, Tari MJO, Ten FJG, et al. Foaming of flat glass cullet using Si3N4 and MnO2 powders, Ceramics International, 2009; 35 1953–1959.
• [28] Wang X. Effect of KNO3 on the microstruture and physical properties of glass foam from solid waste glass and SiC powder. Materials Letters, 2016; 169, 21–23.
• [29] Petersen RR, König J and YueY. The viscosity window of the silicate glass foam production. Journal of Non-Crystalline Solids, 2017; 456 49–54.
• [30] Gibson LJ, Ashby MF, Cellular solids: Structure and properties, second ed., Cambridge Solid state Press, Cambridge University Press, 1997.