gummfd

Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi

1300-1884 1304-4915

Gazi Üniversitesi

10.17341/gazimmfd.1250471

Engineering

Mühendislik

Kombucha çayı kullanarak yeşil sentez ve kimyasal sol-jel yöntemi ile ZnO nanoparçacıklarının sentezlenmesi ve fotokatalitik aktivitelerinin karşılaştırılması

https://orcid.org/0000-0001-7783-9515

Özserçe Haste

Zeynep

Sivas Cumhuriyet Üniversitesi

https://orcid.org/0000-0001-5421-0474

Cetınkaya Gürer

Sevil

SİVAS CUMHURİYET ÜNİVERSİTESİ

08 16 2024

40 1 43 58 02 15 2023 01 27 2024

1986

Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi

Bu çalışmada Kombucha çayı (KÇ) kullanılarak yeşil sentez ve kimyasal sol-jel yöntemleri ile çinko oksit nanoparçacıkları sentezlenerek özellikleri incelendi. Kombucha çayı ile çinko oksit nanoparçacıklarının ( ZnO-NP(KÇ) ) en uygun sentez şartlarını belirlemek amacı ile reaksiyon sıcaklığı 25, 40 ve 60 0C ve 1, 2, 3 ve 4 h reaksiyon süresini alınarak deneyler gerçekleştirildi. . İncelenen bu parametrelerde 60 0C sıcaklık ve reaksiyon süresi 3 olarak belirlendi. Karşılaştırma amacı ile kimyasal bir yöntem olan sol-jel yöntemiyle de çinko oksit nanoparçacıkları ( ZnO-NP(SJ) ) 60 0C reaksiyon sıcaklığında ve 3 h reaksiyon süresinde sentezi gerçekleştirildi. Her iki yöntemle kullanılarak hazırlanan ZnO-NP’nin karakterizasyon UV/Vis, FTIR, XRD, SEM teknikleri kullanılarak incelendi. Her iki yöntem kullanılarak sentezlenen ZnO-NP(KÇ) ve ZnO-NP(SJ)”nin ortalama kristalit boyutu sırasıyla 22 nm ve 89 nm Debye Schrerrer denklemi ile belirlendi. Çalışmanın ikinci bölümünde her iki yöntemle hazırlanan ZnO-NP’nin, UV lamba altında ve 180 min sonunda, metilen mavisi (MM) çözeltisinde boya giderimi incelenerek fotokatalitik aktiviteleri karşılaştırıldı. Hazırlanan ZnO-NP(KÇ)’nin %76 ve ZnO-NP(SJ)’nin %67 sulu çözeltiden MM’yi giderdiği belirlendi. Her iki yöntemle de sentezlenen ZnO-NP’i kullanarak MM’nin fotokatalitik bozunma kinetiğinin birinci dereceden reaksiyon kinetiğine uyduğu belirlendi.

Çinko oksit nanoparçacık kombucha çayı yeşil sentez metilen mavisi fotokatalitik aktivite

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