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Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan

Yıl 2024, Cilt: 37 Sayı: 3, 1094 - 1105
https://doi.org/10.35378/gujs.1349867

Öz

In the range of 278-293 K, the structural-mechanical properties of high-viscosity asphaltene-resinous and highly solidifying paraffinic oils of the Muradkhanly and Sangachal-deniz fields of Azerbaijan, which exhibit abnormal viscosity at various shear rates and are characterized by non-Newtonian, viscoplastic and thixotropic properties, have been studied. According to the Eyring-Frenkel equation, the activation energies of the viscous flow Ea and the change in the entropy ΔS of these oils are calculated for the indicated temperature range. Various algorithms for estimating the thermodynamic parameters of the flow ΔH and ΔS published in the literature are analyzed, and the scatter of the values of the estimates of parallel calculations is shown. It is shown that with a decrease in temperature, phase transitions in oils are activated, in particular, for the highly solidifying paraffin oil Sangachal-deniz, it originates from 297 K. For the oils under consideration for the selected shear rate of 64 s-1, the values of the temperature of the beginning of structure formation, static and limiting dynamic shear stresses were determined: for Muradkhanly oil T = 282.83 K, Sangachal-deniz - T = 297.23 K. The results obtained can be used to predict the behavior of oils.

Kaynakça

  • [1] Devlikamov V.V., Khabibullin Z.A., Kabirov M.M., “Anomalous oil”, Nedra, Moscow, (1975).
  • [2] Ibragimov N.G., Tronov V.P., Guskova I.A., “Theory and practice of methods of combating organic deposits at a late stage of oil field development”, Oil industry, (2008).
  • [3] Samedova F.I., “Azerbaijani Oils”, Baku, Elm, (2014).
  • [4] Uriev, N.B., “Technology of Dispersed Systems and Materials: Physicochemical Dynamics of Structure Formation and Rheology”, Germany: Wiley-VCH, (2016). https://www.wiley.com/en-cn/9783527806188
  • [5] Mustafayeva G.R., “Rheological models of non–newtonian oils flows”, Journal Transport and storage of oil products and hydrocarbons, 4: 40-42, (2018). DOI: https://doi.org/10.24411/0131-4270-2018-10406
  • [6] Matveenko, V.N., Kirsanov, E.A., “Structural rationale of a non-Newtonian flow”, Moscow University Chemistry Bulletin, 72: 69-91, (2017). DOI: https://doi.org/10.3103/S0027131417020031
  • [7] Lawson, Ch., Hanson, R., “Solving Least Squares Problems”, Journal of the American Statistical Association, 72: 930-931, (1977). DOI: https://doi.org/10.2307/2286501
  • [8] Mirzajanzade, A.Kh., Khasanov, M.M., Bakhtizin, R.N., “Studies on modeling complex oil production systems. Non-linearity, non-equilibrium, heterogeneity”, Ufa: Gilem, (1999).
  • [9] Kirsanov, E.A., Matveenko, V.N., “Non-Newtonian behavior of structured systems”, Technosfera, Moscow, (2016). https://www.technosphera.ru/files/book_pdf/0/book_481_489.pdf
  • [10] Glasstone, S., Laidler, K., Eyring, H., “The Theory of Rate Processes”, Journal of Chemical Education, 19: 249, (1942). DOI: https://doi.org/10.1021/ed019p249.1
  • [11] Frenkel Ya, I., “Kinetic theory of liquids”. Publishing house "Science", Leningrad., (1975).
  • [12] Tager, A.A., Botvinnik, G.O., Dreval, V.E., “Energy and entropy of activation of the viscous flow of concentration of polymer solutions”., Chemistry, Moscow, (1970).
  • [13] Froishteter, G.B., Danilevich, S.Yu., Radionova, N.V., “Flow and heat exchange of non-Newtonian liquids in pipes”, Naukova Dumka, Kyiv, (1990).
  • [14] Aleksandrov A.N., Rogachev M.K., Raupov I.R., “Research of Rheological Properties of High-Wax Oil”, J. Neftegas, 6: 52-62, (2018).
  • [15] Rogachev, M.K., Kondrasheva, N.K., “The rheology of oil and oil products”, Ufa State Oil Technical University, Publ. House Ugnuta: Ufa, Russia, (2000).
  • [16] Semikhina, L.P., Shtykov, S.V., Karelin, E.A., Kovaleva, I.V., Tarasova, E.V., “Kinetic and Thermodynamic Parameters of Interaction Between Aqueous Solutions of Surfactants and Oil Films”, Bulletin of the South Ural State University. Chemistry series, 11: 5-17, (2019). DOI: 10.14529/chem190101.
  • [17] Semikhina, L.P., Pashnin, A.M., Kovaleva, I.V., Semikhin, D.V., “Temperature and Shear Stress Effect on Reological Properties of Oil-Disperse Systems”, Tyumen State University Herald. Physical and Mathematical Modeling, Oil, Gas, Energy, 4: 36-52, (2018). DOI: 10.21684/2411-7978-2018-4-3-36-52
  • [18] Kondrasheva, N.K., Baitalov, F.D., Boitsova, A.A., “Comparative assessment of structural-mechanical properties of heavy oils of timano-pechorskaya province”, Journal of Mining Institute, 225: 320-329, (2017). DOI: 10.18454/PMI.2017.3.320.
  • [19] Tager, A.A., “Physical chemistry of polymers”, Mir Publishers, (1972).
  • [20] Schramm, G., “Fundamentals of practical rheology and rheometry”, Kolos, Moscow, (2003).
Yıl 2024, Cilt: 37 Sayı: 3, 1094 - 1105
https://doi.org/10.35378/gujs.1349867

Öz

Kaynakça

  • [1] Devlikamov V.V., Khabibullin Z.A., Kabirov M.M., “Anomalous oil”, Nedra, Moscow, (1975).
  • [2] Ibragimov N.G., Tronov V.P., Guskova I.A., “Theory and practice of methods of combating organic deposits at a late stage of oil field development”, Oil industry, (2008).
  • [3] Samedova F.I., “Azerbaijani Oils”, Baku, Elm, (2014).
  • [4] Uriev, N.B., “Technology of Dispersed Systems and Materials: Physicochemical Dynamics of Structure Formation and Rheology”, Germany: Wiley-VCH, (2016). https://www.wiley.com/en-cn/9783527806188
  • [5] Mustafayeva G.R., “Rheological models of non–newtonian oils flows”, Journal Transport and storage of oil products and hydrocarbons, 4: 40-42, (2018). DOI: https://doi.org/10.24411/0131-4270-2018-10406
  • [6] Matveenko, V.N., Kirsanov, E.A., “Structural rationale of a non-Newtonian flow”, Moscow University Chemistry Bulletin, 72: 69-91, (2017). DOI: https://doi.org/10.3103/S0027131417020031
  • [7] Lawson, Ch., Hanson, R., “Solving Least Squares Problems”, Journal of the American Statistical Association, 72: 930-931, (1977). DOI: https://doi.org/10.2307/2286501
  • [8] Mirzajanzade, A.Kh., Khasanov, M.M., Bakhtizin, R.N., “Studies on modeling complex oil production systems. Non-linearity, non-equilibrium, heterogeneity”, Ufa: Gilem, (1999).
  • [9] Kirsanov, E.A., Matveenko, V.N., “Non-Newtonian behavior of structured systems”, Technosfera, Moscow, (2016). https://www.technosphera.ru/files/book_pdf/0/book_481_489.pdf
  • [10] Glasstone, S., Laidler, K., Eyring, H., “The Theory of Rate Processes”, Journal of Chemical Education, 19: 249, (1942). DOI: https://doi.org/10.1021/ed019p249.1
  • [11] Frenkel Ya, I., “Kinetic theory of liquids”. Publishing house "Science", Leningrad., (1975).
  • [12] Tager, A.A., Botvinnik, G.O., Dreval, V.E., “Energy and entropy of activation of the viscous flow of concentration of polymer solutions”., Chemistry, Moscow, (1970).
  • [13] Froishteter, G.B., Danilevich, S.Yu., Radionova, N.V., “Flow and heat exchange of non-Newtonian liquids in pipes”, Naukova Dumka, Kyiv, (1990).
  • [14] Aleksandrov A.N., Rogachev M.K., Raupov I.R., “Research of Rheological Properties of High-Wax Oil”, J. Neftegas, 6: 52-62, (2018).
  • [15] Rogachev, M.K., Kondrasheva, N.K., “The rheology of oil and oil products”, Ufa State Oil Technical University, Publ. House Ugnuta: Ufa, Russia, (2000).
  • [16] Semikhina, L.P., Shtykov, S.V., Karelin, E.A., Kovaleva, I.V., Tarasova, E.V., “Kinetic and Thermodynamic Parameters of Interaction Between Aqueous Solutions of Surfactants and Oil Films”, Bulletin of the South Ural State University. Chemistry series, 11: 5-17, (2019). DOI: 10.14529/chem190101.
  • [17] Semikhina, L.P., Pashnin, A.M., Kovaleva, I.V., Semikhin, D.V., “Temperature and Shear Stress Effect on Reological Properties of Oil-Disperse Systems”, Tyumen State University Herald. Physical and Mathematical Modeling, Oil, Gas, Energy, 4: 36-52, (2018). DOI: 10.21684/2411-7978-2018-4-3-36-52
  • [18] Kondrasheva, N.K., Baitalov, F.D., Boitsova, A.A., “Comparative assessment of structural-mechanical properties of heavy oils of timano-pechorskaya province”, Journal of Mining Institute, 225: 320-329, (2017). DOI: 10.18454/PMI.2017.3.320.
  • [19] Tager, A.A., “Physical chemistry of polymers”, Mir Publishers, (1972).
  • [20] Schramm, G., “Fundamentals of practical rheology and rheometry”, Kolos, Moscow, (2003).
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Petrokimya
Bölüm Chemical Engineering
Yazarlar

Yusif Rzayev 0000-0003-3952-1869

Sevinj Osmanova 0000-0003-2960-8450

Etibar Ismailov 0000-0003-3687-4781

Erken Görünüm Tarihi 19 Nisan 2024
Yayımlanma Tarihi
Yayımlandığı Sayı Yıl 2024 Cilt: 37 Sayı: 3

Kaynak Göster

APA Rzayev, Y., Osmanova, S., & Ismailov, E. (t.y.). Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan. Gazi University Journal of Science, 37(3), 1094-1105. https://doi.org/10.35378/gujs.1349867
AMA Rzayev Y, Osmanova S, Ismailov E. Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan. Gazi University Journal of Science. 37(3):1094-1105. doi:10.35378/gujs.1349867
Chicago Rzayev, Yusif, Sevinj Osmanova, ve Etibar Ismailov. “Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan”. Gazi University Journal of Science 37, sy. 3 t.y.: 1094-1105. https://doi.org/10.35378/gujs.1349867.
EndNote Rzayev Y, Osmanova S, Ismailov E Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan. Gazi University Journal of Science 37 3 1094–1105.
IEEE Y. Rzayev, S. Osmanova, ve E. Ismailov, “Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan”, Gazi University Journal of Science, c. 37, sy. 3, ss. 1094–1105, doi: 10.35378/gujs.1349867.
ISNAD Rzayev, Yusif vd. “Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan”. Gazi University Journal of Science 37/3 (t.y.), 1094-1105. https://doi.org/10.35378/gujs.1349867.
JAMA Rzayev Y, Osmanova S, Ismailov E. Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan. Gazi University Journal of Science.;37:1094–1105.
MLA Rzayev, Yusif vd. “Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan”. Gazi University Journal of Science, c. 37, sy. 3, ss. 1094-05, doi:10.35378/gujs.1349867.
Vancouver Rzayev Y, Osmanova S, Ismailov E. Structural And Mechanical Properties Of Oils From The Muradkhanly And Sangachal-Deniz Fields Of Azerbaijan. Gazi University Journal of Science. 37(3):1094-105.