Multivariate Statistical Evaluation of Geochemical Properties of “Alanya Emperador Dark” Marbles

Year 2021, Volume: 8 Issue: 3, 361 - 372, 29.09.2021

İpek Yazıcı , Mustafa Gurhan Yalcın , Özge Özer Atakoğlu , Füsun Yalçın

Abstract

The formation of marbles, which are regarded as natural stones, can be attributed to various rock origins and formation conditions. The study area is located in the Obaalacami village of Alanya district in the province of Antalya, which is located in the Taurus belt, and it covers an area of about 100 hectares. In this study, the major and trace element components of the "Emperador Dark" marbles found in the Alanya region were interpreted using geostatistical analyses. Geostatistical methods can be used to reveal and interpret the origin of marble and its formation conditions. In this context, X-ray fluorescence (XRF) spectrometry was employed to analyze samples collected from various locations within the marble quarry. The CaO values of the marble quarry were found to have a normal distribution, and this was interpreted using the histogram values together with the measures of central tendency such as the mode, median, and arithmetic mean values. The major and trace element contents of the "Emperador Dark" marbles, which meet the assumption of normality, were obtained using the Pearson correlation coefficient. The strong negative correlation of CaO, which played a major role in the formation of marbles, with SiO2 and MgO was associated with the mineralogical composition that played a role in marble formation. These correlations were also tested by regression analysis, and it was proved that a statistically significant model had been obtained.

Keywords

Limestone, Multivariate Statistics, Mineralogy, Geochemistry

References

• Ahmad, A. H. M., Noufal, K. N., Masroor, A. M., & Khan, T. (2014). Petrography and geochemistry of Jumara Dome sediments, Kachchh Basin: implications for provenance, tectonic setting and weathering intensity. Chinese Journal of Geochemistry, 33, 9-23. doi:10.1007/s11631-014-0656-4
• Atakoglu, O. O., & Yalcin, M. G. (2021). Geochemical characterization of the Sutlegen bauxite deposit, SW Antalya. Mining of Mineral Deposits, 15(3), 108-121. doi:10.33271/mining15.03.108
• Atakoglu, O. O., Yalcin, M. G., & Ozmen, S. F. (2021). Determination of radiological hazard parameters and radioactivity concentrations in bauxite samples: the case of the Sutlegen Mine Region (Antalya, Turkey). Journal of Radioanalytical and Nuclear Chemistry, 329(2), 701-715. doi:10.1007/s10967-021-07826-5
• Aydin, B., Yalcin, F., Ozer, O., & Yalcin, M. G. (2020). Regression analysis and statistical examiantion of knoop hardness on abrasion resistance in Lyca beige marbles. Filomat, 34(2), 609-614. doi:10.2298/FIL2002609A
• Brownflow, A. H. (1996). Sedimentary Rocks. Geochemistry, 2nd. Edition, Prentice Hall, New York, cap, 1996, 7
• Ince, Z, Atakoglu, O. O., & Yalcin, M. G. (2021). Multivariate and spatial statistical analysis of geochemical data of dolomite: the case of industrial raw materials’ differentiation. Montes Taurus J Pure Appl Math, 3(2), 8-28
• Kalayci, S. (2010). SPSS Applied Multivariate Statistical Techniques, 5th Edition, Asil Publication, Ankara.
• Leventeli, Y., & Yalcin, F. (2021). Data analysis of heavy metal content in riverwater: multivariate statistical analysis and inequality expressions. Journal of Inequalities and Applications, 2021(1), 1-22. doi:10.1186/s13660-021-02549-3
• Li, H. M., Liu, M. J., Li, Li-Xing., Yang Xiuqing Chen, J., Yao, L. D., Hong, X. K., & Yao, T. (2012). Geology and geochemistry of the marble in the Gongchangling iron deposit in Liaoning Province and their metallogenic significance. Acta Petrologica Sinica, 28(11), 3497-3512.
• Mirza, T. A. (2019). Geochemical and isotopic characteristics of Zangalline marble, Ranya area, Qandil Series, northeastern Iraqi Kurdistan Region: implications for genesis. Arabian Journal of Geosciences, 12(4), 1-11. doi:10.1007/s12517-019-4284-5
• Munyanyiwa, H., & Hanson, R. E. (1988). Geochemistry of marbles and calc-silicate rocks in the Pan-African Zambezi belt, Zambia. Precambrian Research, 38(3), 177-200. doi:10.1016/0301-9268(88)90001-0
• Oz, C., & Ozer, O. (2019). Seramik Arkeometrisi’nde Spektroskopik Yöntemlerin Uygulanması ve Yorumlanması: XRF, XRD. Seramik Araştırmaları Dergisi, 1, 136-153.
• Ozer, O., & Yalcin, M. G. (2020). Correlation of chemical contents of Sutlegen (Antalya) bauxites and regression analysis. AIP Conference Proceedings, 2293(1), 180008-180012. doi:10.1063/5.0026731
• Ozer, O., Yalcin, F., Nyamsari, D. G., Yalcin, M. G. (2019). Appraisal of metal accumulation in beach sand using contamination indices and multivariate statistical analysis. In: Proceedings Book of the 2nd Mediterranean International Conference of Pure Applied Mathematics and Related Areas, Paris, France, 28-31 August, 1-5.
• Ozer, O., Yalcin, F., Tarinc, O. K., & Yalcin, M. G. (2020). Investigation of suitability of marbles to standards with inequality expressions and statistical approach using some physical and mechanical properties. Journal of Inequalities and Applications, 97, 1-15. doi:10.1186/s13660-020-02360-6
• Tarinc, O. K., Ozer, O., Aydin, B., & Yalcin, M. G. (2019a). Comparison of physical-mechanical properties of Clova and Lyca marbles in Akcay (Antalya) region by using independent-samples T-test statistics. In: Proceedings Book of the 2nd Mediterranean International Conference of Pure Applied Mathematics and Related Areas, Paris, France, 28-31 August.
• Tarinc, O. K., Ozer, O., Yalcin, F., & Yalcin, M. G. (2019b). Statistical evaluation of the chemical characteristics on marble in Akcay village (Elmali, Antalya) region. International Symposium on Advanced Engineering Technologies, Kahramanmaras, Turkey, 1333-1338.
• Yalcin, M. G., Battaloglu, R., Ilhan, S., Tümüklü, A., & Topuz, D. (2007). Heavy metal contamination along the Nigde-Adana highway, Turkey. Asian Journal of Chemistry, 19(2), 1506.
• Yalcin, M. G., Aydin, O., & Elhatip, H. (2008). Heavy metal contents and the water quality of Karasu Creek in Nigde, Turkey. Environmental Monitoring and Assessment, 137, 169. doi:10.1007/s10661-007-9737-8
• Yalcin, M. G., Cevik, O., & Karaman, M. E. (2013). Use of multivariate statistics methods to determine grain size, heavy metal distribution and origins of heavy metals in Mersin Bay (Eastern Mediterranean) coastal sediments. Asian Journal of Chemistry, 25(5), 2696-2702. doi:10.14233/ajchem.2013.13683
• Yalcin, M. G., Setti, M., Karakaya, F., Sacchi, E., & Ilbeyli, N. (2015). Geochemical and mineralogical characteristics of beach sediments along the coast between Alanya and Silifke (southern Turkey). Clay Minerals, 50(2), 233-248. doi:10.1180/claymin.2015.050.2.07
• Yalcin, F., Kilic, S., Nyamsari, D. G., Yalcin, M. G., & Kilic, M. (2016a). Principal component analysis of integrated metal concentrations of bogacayi riverbank sediments in Turkey. Polish Journal of Environmental Studies, 25(2), 471-485. doi:10.15244/pjoes/61009
• Yalcin, M. G., Akturk, O., & Paksu, E. (2016b). The contribution of west mediterranean cities (Antalya, Isparta and Burdur) to Turkey's natural stones-marble export. International Multidisciplinary Scientific GeoConference: SGEM: Surveying Geology & Mining Ecology Management, 2, 875-880.
• Yalcin, F., Nyamsari, D. G., Paksu, E., & Yalcin, M. G. (2016c). Statistical assessment of heavy metal distribution and contamination of beach sands of Antalya-Turkey: an approach to the multivariate analysis techniques. Filomat, 30(4). 945-952. doi:10.2298/FIL1604945Y
• Yalcin, F., Ozer, O., Nyamsari, D. G., & Yalcin, M. G. (2019a). Statistical evaluation of the geochemical content of beach sand along the Sarisu-Kemer coastline of Antalya, Turkey. AIP Conference Proceedings 2116, 100005-100009. doi:10.1063/1.5114081
• Yalcin, M. G., Coskun, B., Nyamsari, D. G., & Yalcin, F. (2019b). Geomedical, ecological risk, and statistical assessment of hazardous elements in shore sediments of the Iskenderun Gulf, Eastern Mediterranean, Turkey. Environmental Earth Sciences, 78(15), 438. doi:10.1007/s12665-019-8435-5
• Yalcin, F., Unal, S., Yalcin, M. G., Akturk, O., Ocak, S. B., & Ozmen, S. F. (2020). Investigation of the Effect of Hydrothermal Waters on Radionuclide Activity Concentrations in Natural Marble with Multivariate Statistical Analysis. Symmetry, 12(8), 1219. doi:10.3390/sym12081219
• Yalcin, M. G., Nyamsari, D. G., Atakoglu, O. O., Yalcin, F. (2021). Chemical and statistical characterization of beach sand sediments: implication for natural and anthropogenic origin and paleo-environment. International Journal of Environmental Science and Technology. doi:10.1007/s13762-021-03280-8
• Yalcin, F., & Mert, M. (2018). Determination of hedonic hotel room prices with spatial effect in Antalya. Economía, Sociedad y Territorio, 18(58), 697-734. doi:10.22136/est20181228
• Yalcin, M. G., & Ilhan, S. (2013). Major and trace element geochemistry of bauxites of Ayranci, Karaman, central Bolkardag, Turkey. Asian Journal of Chemistry, 25(5), 2893-2904, doi:10.14233/ajchem.2013.14275
• Yalcin, M. G., & Unal, S. (2018). Natural radioactivity levels and associated radiation hazards in ophiolites around Tekirova, Kemer, and Kumluca Touristic Regions in Antalya, Turkey. Journal of Radioanalytical and Nuclear Chemistry, 316(1), 321-330. doi:10.1007/s10967-018-5760-1
• Yazici, I. (2020). Evaluation of Obaalacami Village Alanya (Antalya) region by Emperador Marble by physical-mechanical properties and tse standards. Akdeniz University Institute of Science and Technology, Master Thesis, Antalya, 70 p, (Turkish). Yazici, I., Ozer, O., & Yalcin, M. G. (2019). The evaluation of physical and mechanical properties of Alanya (Antalya) region dark films by TurkStat standards. In: International Symposium on Advanced Engineering Technologies, Kahramanmaras, Turkey, 2-4 May, 1339-1344.