Hirfanlı baraj gölünde eser elementlerin ICP-OES ile tayini

Yıl 2020, Cilt: 8 Sayı: 2, 451 - 457, 28.06.2020

Şükrü Kalaycı

https://doi.org/10.29109/gujsc.718105

Cited By: 2

Öz

Bu çalışmada, Kızılırmak üzerine kurulmuş olan Hirfanlı Baraj Gölü`nde eser elementlerin tayin için ICP-OES kullanıldı. Hirfanlı Baraj Gölü`nün değişik yerlerinden polietilen şişelere bir iki mililitre HCl eklenerek su örnekleri alındı. Bu örneklerdeki eser elementler, Perkin Elmer marka ICP-OES cihazıyla tayin edildi.
ICP-OES cihazıyla, barajdan gelen su örneklerindeki demir, bakır, kurşun, krom, çinko, molibden ve selenyum elementleri tayin edildi. Uygun standart çözeltilerle belirli dalga boylarında elementlerin kalibrasyon işlemi yapıldı. Cihaz önce sertifikalı örnekteki elementlerin ölçümleri yapılarak duyarlılığı tespit edildi. Daha sonra su örneklerindeki elementlerin analizleri yapıldı. Baraj gölünde yapılan ölçümlere göre; Fe (III) 40 ± 0,3 µg/L, Cu (II) 10 ± 0,1 µg/L, Pb (II) 25 ± 0,1 µg/L, Cr (III) 15 ± 0,2 µg/L, Zn (II) 22 ± 0,2 µg/L, Mo (VI) 8 ± 0,1 µg/L, Se (IV) 35 ± 0,3 µg/L olarak % 95 güven aralığı ve 4 ölçümün sonunda bulunmuştur.

Anahtar Kelimeler

ICP-OES, Tayin, Eser elementler, Hirfanlı Baraj Gölü

Kaynakça

• [1] Sönmez A.Y., Hisar O., Karataş M., Arslan G., Aras M.S. (2008). Sular Bilgisi. Nobel Bilim ve Araştırma Merkezi, Nobel Basımevi, Ankara.
• [2] Iyengar G.V., Kasperek K., Feindenegen L.E. (1978). Retention of the metabolized trace elements in biological tissues following different drying procedures: I. Antimony, cobalt, iodine, mercury, selenium and zinc in rat tissues, Science of the environment, 10 (1), 1-16.
• [3] Williams P.B., Buhr M.P., Weber R.W., Volz M.A., Koepke J.W., Selner J.C. ( 1995). Latex allergen in respirable particulate air pollution, Journal of allergy and clinical immunology, 95 (1), 88-95.
• [4] Srikumar T.S. (1993). The mineral and trace element composition of vegetables, pulses and cereals of southern India, Food chemistry, 6 (2), 163-167.
• [5] Ikem A., Egiebor N.O., Nyavor K. (2003). Trace elements in water, fish and sediment from Tuskegee Lake, Southeastern Usa, Water, Air, and Soil Pollution, 149, 51–75.
• [6] Shigehiro K., Emiko M., Yoshinori I., Waka K., Takehiro K., Hideyuki Y., Mitsuru S., Koji T. (2009). A solid phase extraction using a chelate resin immobilizing carboxymethylated pentaethylenehexamine for separation and preconcentration of trace elements in water samples, Talanta, 79 (2), 146-152.
• [7] Baytak S., Zeren F., Arslan Z. (2011). Preconcentration of trace elements from water samples on a minicolumn of yeast (Yamadazyma spartinae) immobilized TiO2 nanoparticles for determination by ICP-AES, talanta, 84 (2), 319-323.
• [8] Meng Q., Zhang J., Zhang Z., Wu T. (2016). Geochemistry of dissolved trace elements and heavy metals in the Dan River Drainage (China): distribution, sources, and water quality assessment, Environmental Science and Pollution Research, 23, 8091–8103.
• [9] Min X., Weiwei S., Rong W. (2019). Spatial distribution and ecological risk assessment of potentially harmful trace elements in surface sediments from Lake Dali, North China, Water, 2544-2548.
• [10] İnam R., Somer G. (2000). A direct method for the determination of selenium and lead in cow's milk by differential pulse stripping voltammetry, Food Chem., 69, 345-349.
• [11] Somer G., Guliyeva G., Ekmekci G., Şendil O. (2003). Simultaneous determination of copper,lead, cadmium, zinc, and selenium in cow liver by DPP. Can. J. Chem., 81, 31-36.
• [12] Somer G., Ünal Ü. (2004). A new and direct method for the trace element determination in cauliflower by differential pulse polarography, Talanta, 62, 323-327.
• [13] Somer G., Nakışcı A., Kalaycı Ş., Şahin F. (2006). Trace element determination in Brassica oleraceae var. acephale by differential pulse polarography, Turkish Journal of chemistry, 30, 419-427.
• [14] Somer G., Almas Z. (2006). Differential pulse polarographic determination of trace quantities of arsenic using catalytic hydrogen wave and its application, Journal of electroanalytical chemistry, 593 (1-2), 179-184.
• [15] Somer G., Kalaycı Ş. (2015). A new and simple method for the simultaneous determination of Fe, Cu, Pb, Zn, Bi Cr, Mo, Se, and Ni in dried red grapes using differential pulse polarography, Food Analytical Methods, 8, 604-611.
• [16] Lu Y., Liang X., Niyungeko C., Zhou J., Xu J., Tian G. (2018). A review of the identification and detection of heavy metal ions in the environment by voltammetry, Talanta, 178, 324-338.
• [17] Kumar S. S., Sangilimuthu S. N. ( 2018). Synthesis and characterization of carbon nanotubes/asymmetric novel tetradentate ligand forming complexes on PIGE modified electrode for simultaneous determination of Pb(II) and Hg(II) in sea water, Lake water and well water using anodic stripping voltammetry, Journal electroanalytical chemistry, 810, 176-184.