Ayçiçeği pektiniyle enkapsüle edilen hidrofilik ve lipofilik kırmızı renklendiricilerin hidrojel ve emülsiyon hidrojellerindeki stabilitesi

Yıl 2018, Cilt: 22 Sayı: 3, 403 - 412, 24.09.2018

Özgenur Coşkun İbrahim Gülseren

https://doi.org/10.29050/harranziraat.396502

Cited By: 1

Öz

Hidrojeller ve parçacık
içeren hidrojeller (emülsiyon jelleri), hidrofilik ve lipofilik boyaların enkapsülasyonunda
kullanıma uygunluk arz eden enkapsülasyon sistemleridir. Bu çalışmada, ayçiçeği
pektini bazlı hidrojellerde ve emülsiyon hidrojellerinde sırasıyla hidrofilik
(Ponceau S) ve lipofilik kırmızı (metil kırmızısı) model boyar maddelerin stabilize
edilmesi incelenmiştir. Bütün deneylerde, pektin hidrojellerinin kırmızı boyar
maddeleri enkapsüle etme kabiliyeti bulgulanmıştır. Hidrofilik Ponceau S
taşıyan hidrojellere kıyasla parçacık içeren emülsiyon jellerinde daha yüksek miktarlarda
metil kırmızısı taşınması mümkün olmuştur. Her iki durumda da, boyar maddelerin
jel matrislerinden salınımı 2 hafta boyunca izlenmiştir. Enkapsülasyon veriminin
(%EV) pektin konsantrasyonunun ve boyar maddenin kimyasal özelliklerinin bir
fonksiyonu olduğu anlaşılmıştır. Boya salınım miktarları genellikle <%10
olarak gerçekleştiği için enkapsülasyon sistemleri kararlı olarak
nitelendirilmiştir. Dolayısıyla
bu çalışmada hem boyaların etkili bir yöntemle stabilizasyonu, hem de tarımsal
bir yan ürünümüzün değerlendirilmesi söz konusudur.

Anahtar Kelimeler

Pektin hidrojelleri; emülsiyon jelleri; boyar madde enkapsülasyonu; depolama kararlılığı; atıkların değerlendirilmesi.

Kaynakça

• Sriamornsak, P., Thirawong, N., Puttipipatkhachorn, S., 2005. Emulsion gel beads of calcium pectinate capable of floating on the gastric fluid: effect of some additives hardening agent or coating on release behavior of metronidazole. European Journal of Pharmaceutical Sciences, 24: 363–373.
• Iglesias, M.T., Lozano, J.E., 2004. Extraction and characterization of sunflower pectin. Journal of Food Engineering, 62: 215–223.
• Shi, X.Q., Chang, K.C., Schwarz, J.G., Wiesenborn, D.P., Shih, M.C., 1996. Optimizing pectin extraction from sunflower heads by alkaline washing. Bioresource Technology, 58: 291-297.
• Miyamoto, A., Chang, K.C., 1992. Extraction and physicochemical characterization of pectin from sunflower head residues. Journal of Food Science, 57: 1439-43.
• Sahari, M.A., Akbarian, A.M., Hameedi, M., 2003. Effect of variety and acid washing method on extraction yield and quality of sunflower head pectin. Food Chemistry, 83: 43–47.
• Rubinstein, A., Radai, R., Ezra, M., Pathak, S., Rokem, J.S., 1993. In vitro evaluation of calcium pectinate: a potential colon-specific drug delivery carrier. Pharmaceutical Research, 10: 258–263.
• Ashford, M., Fell, J., Attwood, D., Sharma, H., Woodhead, P., 1994. Studies on pectin formulations for colonic drug delivery. Journal of Controlled Release, 30: 225–232.
• Çakır, B., Gülseren, İ., 2017. 5-Fluorouracil release from sunflower pectin hydrogels in simulated intestinal medium and its corresponding anti-carcinogenic activity. International Journal of Pharmaceutical Research, 9(2): 95-98.
• Chan, E.S., Lee, B.B., Ravindra, P., Denis, P., 2009. Prediction models for shape and size of ca-alginate macrobeads produced through extrusion–dripping method. Journal of Colloid and Interface Science, 338(1): 63-72.
• McClements, D.J., Decker, E.A., Weiss, J., 2007. Emulsion based delivery systems for lipophilic bioactive components. Journal of Food Science, 72: R109–R124.
• McClements, D.J., Decker, E.A., Park, Y., Weiss, J., 2009. Structural design principles for delivery of bioactive components in nutraceuticals and functional foods. Critical Reviews in Food Science and Nutrition, 49: 577–606.
• Wang, W., Liu, X.D., Xie, Y.B., Zhang, H., Yu, W.T., Xiong, Y., Xie, W.Y., Ma, X.J., 2006. Microencapsulation using natural polysaccharides for drug delivery and cell implantation. Journal of Materials Chemistry, 16: 32-52.
• Arad, S.M., Yaron, A., 1992. Natural pigments from red microalgae for use in foods and cosmetics. Trends in Food Science and Technology, 3: 92-97.
• Dufosse, L., Fouillaud, M., Caro, Y., Mapari, S.A., Sutthiwong, N., 2014. Filamentous Fungi are large-scale producers of pigments and colorants for the food industry. Current Opinion in Biotechnology, 26:56-61.
• Sowbhagya, H.B., Chitra, V.N., 2010. Enzyme-assisted extraction of flavorings and colorants from plant materials. Critical Reviews in Food Science and Nutrition, 50(2): 146-161.
• Zhang, Y., Zhong, Q., 2013. Encapsulation of bixin in sodium caseinate to deliver the colorant in transparent dispersions. Food Hydrocolloids, 33(1): 1-9.
• Al-Amoudi, M.S., Salman, M., Al-Majthoub, M.M., Adam, A.M.A., Alshanbari, N.A., Refat, M.S., 2015. Spectral studies to ıncrease the efficiency and stability of laser dyes by charge-transfer reactions for using in solar cells: charge-transfer complexes of ponceau s with p-chloranil, chloranilic and picric acids. Research on Chemical Intermediates, 41(5): 3089-3108.
• Clarke, H.T., Kirner, W.R., 1941. Methyl red. Organic Syntheses, 47.
• Peppas, N.A., Langer, R. (1994). New challenges in biomaterials. Science, 263: 1715-20.
• Anthony, C.Y., Chen, H., Chan, D., Agmon, G., Stapleton, L.M., Sevit, A.M. vd. 2016. Scalable manufacturing of biomimetic moldable hydrogels for ındustrial applications. Proceedings of the National Academy of Sciences of the USA, 201618156.
• Hoffman, A.S., 2002. Hydrogels for biomedical applications. Advanced Drug Delivery Reviews, 54: 3–12.
• Matalanis, A., Jones, O.G., McClements, D.J., 2011. Structured biopolymer-based delivery systems for encapsulation, protection and release of lipophilic compounds. Food Hydrocolloids, 25: 1865–80.
• Filippidi, E., Patel, A.R., Bouwens, E.C.M., Voudouris, P., Velikov, K.P., 2014. All-natural oil-filled microcapsules from water-insoluble proteins. Advanced Functional Materials, 24: 5962–68.
• Zeeb, B., Gibis, M., Fischer, L., Weiss, J., 2012. Crosslinking of interfacial layers in multilayered oil-in-water emulsions using laccase: characterization and pH-stability. Food Hydrocolloids, 27: 126–136.
• Çakır, B., Gülseren, İ., 2017. Dissolution kinetics of polyphenol bearing calcium pectate hydrogels in simulated gastric or ıntestinal media and their anti-carcinogenic capacities. Food Hydrocolloids, 70: 69-75.
• Glibowski, P., 2009. Rheological properties and structure of inulin–whey protein gels. International Dairy Journal, 19(8): 443-449.