Chemical Oxidation of 5-amino quinoline with NH4 2S2O8: Synthesis and Characterization

Year 2017, Volume: 45 Issue: 4, 563 - 571, 01.11.2017

Ali Bilici

Abstract

5-amino quinoline AQ was chemically oxidized in NH4 2S2O8/HCI system, whose structure was identified by UV-vis, FTIR, 1HNMR and 13CNMR analysis. Spectral analysis results indicated the formation of phenazine like units in the oxidation product and C3, C6, C8 positions of quinoline ring were suggested as a possible polymerization sites. Size exclusion chromatography indicated the oxidation product OAQ consisted of oligomeric units 1200 g/mol . OAQ was thermally stable and half of its mass was decomposed at 1000°C.

Keywords

Oxidative polymerization, 5-amino quinoline, thermal stability, fluorescent

5-Amino Kinolinin NH SO ile Kimyasal Oksidasyonu: Sentez ve Karakterizasyon

Abstract

amino kinolin monomeri NH4 2S2O8/HCI varlığında kimyasal olarak yükseltgendi. Elde edilen oksidasyon ürününün OAQ yapısı, UV-vis, FTIR, 1HNMR ve 13CNMR analizleri ile aydınlatıldı. Spektral analizler sonucunda oksidasyon ürünün yapısında fenazin birimlerinin bulunduğu ve momomerik birimlerin birbirleri ile 3,6 ve 8 pozisyonları ile birleştiği belirlendi. Büyüklükçe ayırma tekniği, ürünün oligomerik birimlerden oluştuğunu gösterdi. OAQ ısısal bozunmaya karşı dayanıklıdır. Yarı bozunma sıcaklığının 1000ºC olduğu belirlendi

Keywords

Oksidatif polimerizasyon, 5 –amino kinolin, termal dayanıklılık, floresans

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