Research Article
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Structural characterization of FeNiCuTiW type high entropy alloys

Year 2025, Volume: 9 Issue: 3, 162 - 168, 25.12.2025
https://doi.org/10.35860/iarej.1659159

Abstract

High-entropy alloys represent a significant advancement in the field of material science. These alloys offer a combination of high strength, excellent corrosion resistance and unique thermal properties, which makes them suitable for a wide range of applications across various industries. In this study, it is aimed to design and produce materials that can be used in high temperature applications with the concept of high entropy alloy (HEA). FeNiCuTiW high entropy alloys with different atomic percentages of Tungsten (W) were produced by arc melting. Hardness tests, optical microscopy and XRD (X-ray Diffraction) analysis were carried out on specimens. Results show that the alloys compose of three different phases i.e. two bcc (W based and Iron based) and one fcc structure (Cu based) and the increase in W content increases hardness up to 0.8 mol but at equal atomic ratio, the hardness drop dramatically due to the excessive W segregation.

Project Number

Afyon Kocatepe University Scientific Research Projects Coordination Unit with Project number of 22.FEN.BİL.27

Thanks

This work supported by the Afyon Kocatepe University under Scientific Research Projects Coordination Unit (Project no: 22.FEN.BİL.27), Turkiye.

References

  • 1. Zou B., Huang C., Song J., Liu Z., Liu L. and Zhao Y., Effects of sintering processes on mechanical properties and microstructure of TiB2–TiC+8wt% nano-Ni composite ceramic cutting tool material. Materials Science and Engineering A, 2012. 540: p. 235-244.
  • 2. Vallauri D., Atías Adrián I.C. and Chrysanthou A., TiC–TiB2 composites: a review of phase relationships, processing and properties. Journal of the European Ceramic Society, 2008. 28(8): p. 1697-1713.
  • 3. Yeh, JW; Chen, SK; Lin, SJ; Gan, JY; Chin, TS; Shun, TT; Tsau, CH; Chang, SY (May 2004). "Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes". Advanced Engineering Materials. 6 (5): 299–303.
  • 4. Svensson D.O., High Entropy Alloys: Breakthrough materials for aero engine applications at department of materials and manufacturing technology Chalmers Unıversıty of Technology, 2014. Master Thesis.
  • 5. Aristeidakis I.S. and Tzini M.I.T., High Entropy Alloys University of Thessaly Department of Mechanical Engineering Laboratory of Materials, 2016. Master Thesis.
  • 6. Gao M.C., Yeh J.W., Liaw P.K. and Zhang Y., High-Entropy Alloys: Fundamentals and Applications. Springer, 2016. p. 1-516.
  • 7. Tsai M.H. and Yeh J.W., High-entropy alloys: a critical review. Materials Research Letters, 2014. 2: p. 107-123.
  • 8. Yurkova A.I., Cherniavsky V.V., Bolbut V., Krüger M. and Bogomol I., Structure formation and mechanical properties of the high-entropy AlCuNiFeCr alloy prepared by mechanical alloying and spark plasma sintering. Journal of Alloys and Compounds, 2019. 786: p. 139-148.
  • 9. Tsai M.H., Tsai K.Y., Tsai C.W., Lee C., Juan C.C. and Yeh J.W., Criterion for sigma phase formation in Cr-and V-containing high- entropy alloys. Materials Research Letters, 2013. 1(4): p. 207-212.
  • 10. Gludovatz B., Hohenwarter A., Catoor D., Chang E.H., George E.P., and Ritchie R.O., A fracture-resistant high-entropy alloy for cryogenic applications. Science, 2014. 345(6201): p. 1153-1158.
  • 11. Li W., Liaw P.K. and Gao Y., Fracture resistance of high entropy alloys: A review. Intermetallics, 2018. 99: p. 69-83.
  • 12. Stepanov N.D., Shaysultanov D.G., Salishchev G.A., Tikhonovsky M.A., Oleynik E.E., Tortika A.S. and Senkov O.N., Effect of V content on microstructure and mechanical properties of the CoCrFeMnNiVx high entropy alloys. Journal of Alloys and Compounds, 2015. 628: p. 170–185.
  • 13. Miao Z., Zhu F. and Liu Q., Study on microstructure and corrosion resistance of CoCrFeNiCuTi x high-entropy alloy. Powder Metallurgy Technology, 2020. 38(1): p. 10-17.
  • 14. Soni V.K., Sanyal S., and Sinha S.K., Influence of tungsten on microstructure evolution and mechanical properties of selected novel FeCoCrMnWx high entropy alloys. Intermetallics, 2021. 132: p. 107161.
  • 15. Liu L., Zhu J., Zhang C., Li J. and Jiang Q., Microstructure and the properties of FeCoCuNiSnx high entropy alloys. Materials Science and Engineering: A, 2012. 548: p. 64-68.
  • 16. Singh A.K. and Subramaniam A., On the formation of disordered solid solutions in multi-component alloys. Journal of Alloys and Compounds, 2014. 587: p. 113-119.
  • 17. Unnikrishnan T.G., Paul C., Sellamuthu R. and Arul S., An investigation on the effects of Co, Ti and Si on microstructure, hardness and wear properties of AlCuNiFe based entropy alloys. Materials Today, 2017. 4: p. 178–187.
  • 18. Xiao D.H., Zhou P.F., Wu W.Q., Diao H.Y., Gao M.C., Song M. and Liaw P.K., Microstructure, mechanical and corrosion behaviors of AlCoCuFeNi-(Cr,Ti) high entropy alloys. Materials and Design, 2017. 116: p. 438-447.
  • 19. Amar A., Li J., Xianga S., Liu X., Zhou Y., Le G., Wang X., Qu F., Ma S., Dong X. and Li Q., Additive manufacturing of high-strength CrMnFeCoNi-based High Entropy Alloys with TiC addition. Intermetallics, 2019. 109: p. 162-166.
  • 20. Ångqvist M., Rahm J.M., Gharaee L., and Erhart P., Structurally driven asymmetric miscibility in the phase diagram of W-Ti. Physical Review Materials, 2019. 3(7): p. 073605. doi: 10.1103/PhysRevMaterials.3.073605
  • 21. Elghazaly W.S., and Elkady O., Influence of Tungsten and Cobalt contents on the microstructure changes and fracture behavior of New Carbon-Free Steel-alloy Composites. J. Mater. Sci. Eng. B., 2018. 8: p. 181-187.
  • 22. Yeh J.W., Physical Metallurgy. In: Gao M., Yeh JW., Liaw P. and Zhang Y. (eds) High-Entropy Alloys. Springer, 2016. Cham. https://doi.org/10.1007/978-3-319-27013-5_3
  • 23. Murray J.L., The Ti−W (Titanium-Tungsten) system. Bulletin of Alloy Phase Diagrams, 1981. 2(2): p. 192-196. https://doi.org/10.1007/BF02881477
  • 24. Yu J.H, Tanigawa H., Hamaguchi D. and Nozawa T., Mechanical properties of three kinds of ITER-Grade pure tungsten with different manufacturing processes. Fusion Engineering and Design, 2020. 157: p. 111679.
  • 25. Talas S, Intermetallic Matrix Composites: Properties and Applications. Chapter: Nickel aluminides, 2017, Woodhead Publishing, Elsevier, Eds:Rahul Mitra, ISBN:9780857093462
There are 25 citations in total.

Details

Primary Language English
Subjects Material Design and Behaviors, Material Characterization, Material Production Technologies
Journal Section Research Article
Authors

Başar Ersegün Çelik 0000-0002-3015-2553

Şükrü Talaş

Project Number Afyon Kocatepe University Scientific Research Projects Coordination Unit with Project number of 22.FEN.BİL.27
Submission Date March 16, 2025
Acceptance Date September 13, 2025
Publication Date December 25, 2025
Published in Issue Year 2025 Volume: 9 Issue: 3

Cite

APA Çelik, B. E., & Talaş, Ş. (2025). Structural characterization of FeNiCuTiW type high entropy alloys. International Advanced Researches and Engineering Journal, 9(3), 162-168. https://doi.org/10.35860/iarej.1659159
AMA Çelik BE, Talaş Ş. Structural characterization of FeNiCuTiW type high entropy alloys. Int. Adv. Res. Eng. J. December 2025;9(3):162-168. doi:10.35860/iarej.1659159
Chicago Çelik, Başar Ersegün, and Şükrü Talaş. “Structural Characterization of FeNiCuTiW Type High Entropy Alloys”. International Advanced Researches and Engineering Journal 9, no. 3 (December 2025): 162-68. https://doi.org/10.35860/iarej.1659159.
EndNote Çelik BE, Talaş Ş (December 1, 2025) Structural characterization of FeNiCuTiW type high entropy alloys. International Advanced Researches and Engineering Journal 9 3 162–168.
IEEE B. E. Çelik and Ş. Talaş, “Structural characterization of FeNiCuTiW type high entropy alloys”, Int. Adv. Res. Eng. J., vol. 9, no. 3, pp. 162–168, 2025, doi: 10.35860/iarej.1659159.
ISNAD Çelik, Başar Ersegün - Talaş, Şükrü. “Structural Characterization of FeNiCuTiW Type High Entropy Alloys”. International Advanced Researches and Engineering Journal 9/3 (December2025), 162-168. https://doi.org/10.35860/iarej.1659159.
JAMA Çelik BE, Talaş Ş. Structural characterization of FeNiCuTiW type high entropy alloys. Int. Adv. Res. Eng. J. 2025;9:162–168.
MLA Çelik, Başar Ersegün and Şükrü Talaş. “Structural Characterization of FeNiCuTiW Type High Entropy Alloys”. International Advanced Researches and Engineering Journal, vol. 9, no. 3, 2025, pp. 162-8, doi:10.35860/iarej.1659159.
Vancouver Çelik BE, Talaş Ş. Structural characterization of FeNiCuTiW type high entropy alloys. Int. Adv. Res. Eng. J. 2025;9(3):162-8.



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