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Year 2025, Volume: 9 Issue: 2, 254 - 261, 29.12.2025
https://doi.org/10.32571/ijct.1749462

Abstract

References

  • Agilent Technologies. (2016). ICP-MS analysis of trace and major elements in drinking water according to US EPA Method 200.8 using the Agilent 7850 ICP-MS with ISIS 3. Agilent Technologies.
  • Anderson, T. W., & Riche, W. H. le. (1971). Sudden Death from Ischemic Heart Disease in Ontario. Canadian Medical Association Journal, 105(2), 155.
  • Arias, L. M. E., & Naranjo, J. (2014). Inductıvely Coupled Plasma—Mass Spectrometry SW-846. Applied Microbiology and Biotechnology, 85(1), 2071–2079.
  • Atlas Scientific. (n.d.). What is the typical water conductivity range? Atlas Scientific. Access June 28, 2025, from https://www.atlasscientific.com
  • Azoulay, A., Garzon, P., & Eisenberg, M. J. (2001). Comparison of the mineral content of tap water and bottled waters. Journal of General Internal Medicine, 16(3), 168–175.
  • Başar, Y., Gül, F., Nas, M. S., Alma, M. H., & Çalımlı, M. H. (2024). Investigation of value-added compounds derived from oak wood using hydrothermal processing techniques and comprehensive analytical approaches (HPLC, GC-MS, FT-IR, and NMR). International Journal of Chemistry and Technology, 8(1), 51-59.
  • Bondy, M. (2009). Cancer epidemiology and prevention. JAMA, 301(10), 1070-1076.
  • Brown, K. G., & Ross, G. L. (2002). Arsenic, Drinking Water, and Health: A Position Paper of the American Council on Science and Health. Regulatory Toxicology and Pharmacology, 36(2), 162–174.
  • Bueno, C., A. J., & Enzweiler, J. (2009). Quantification of major and trace elements in water samples by ICP-MS and collision cell to attenuate Ar and Cl-based polyatomic ions. Journal of Analytical Atomic Spectrometry, 24(10), 1406–1413.
  • Çavuş, A., Atıcı, A. A., & Şen, F. (2017). Van-Merkez İçme Sularının Su Kalite Kriterlerinin İncelenmesi. Yuzuncu Yil Universitesi Journal of Agricultural Sciences (YYU J Agr Sci), 27(3).
  • Chandel, M., Sharma, A. K., Thakur, K., Sharma, D., Brar, B., Mahajan, D., … Kumar, R. (2024). Poison in the water: Arsenic’s silent assault on fish health. Journal of Applied Toxicology, 44(9), 1282–1301.
  • Columbia University Mailman School of Public Health. (2025, June 17). Exposure to low levels of arsenic in public drinking water linked to lower birthweight, preterm birth. [News article]. Access October 6, 2025.
  • Crawford, M. D., Gardner, M. J., & Morris, J. N. (1968). Mortalıty and Hardness of Local Water-Supplıes. The Lancet, 291(7547), 827–831.
  • Döll, P., Fiedler, K., & Zhang, J. (2009). Global-scale analysis of river flow alterations due to water withdrawals and reservoirs. Hydrology and Earth System Sciences, 13(12), 2413–2432.
  • Famiglietti, J. S. (2014). The global groundwater crisis. Nature Climate Change, 4(11), 945–948.
  • Gabelica, V., & Marklund, E. (2018). Fundamentals of ion mobility spectrometry. Current Opinion in Chemical Biology, 42, 51–59.
  • Gemici, Ü., & Tarcan, G. (2002). Distribution of boron in thermal waters of western Anatolia, Turkey, and examples of their environmental impacts. Environmental Geology, 43(1), 87–98.
  • Gleeson, T., Wada, Y., Bierkens, M. F. P., & Van Beek, L. P. H. (2012). Water balance of global aquifers revealed by groundwater footprint. Nature, 488(7410), 197–200.
  • Hussain, M. M., Wang, J., Bibi, I., Shahid, M., Niazi, N. K., Iqbal, J., … Rinklebe, J. (2021). Arsenic speciation and biotransformation pathways in the aquatic ecosystem: The significance of algae. Journal of Hazardous Materials, 403, 124027.
  • International Organization for Standardization. (2001). ISO 15061:2001 Water quality—Determination of dissolved bromate—Method by liquid chromatography of ions. ISO. Retrieved July 22, 2025.
  • International Organization for Standardization. (2023). ISO 17294-2:2023 Water quality—Application of inductively coupled plasma mass spectrometry (ICP-MS)—Part 2: Determination of selected elements including uranium isotopes. ISO. https://www.iso.org.
  • Kim, D. H., Lee, Y. K., Hur, J., Yoo, H. J., Ko, K. S., Lee, J. M., … Cho, K. (2022). Analysis of Natural Organic Matter in Water from Cold and Hot Mineral Springs in South Korea Using 15T FT-ICR-MS. ACS Omega, 7(46), 41859–41871.
  • Li, Y., Duvert, C., Xu, P., & Bian, J. (2025). Contrasting origins of spring water in a ‘water tower’ of Northeast Asia: Evidence from stable isotopes and tritium. Journal of Hydrology, 652, 132661.
  • Marmara Üniversitesi, Doğa Bitkileri ve Su Ürünleri Araştırma ve Uygulama Merkezi. (n.d.). İçme suyu kabul edilebilir değerler. Marmara Üniversitesi. Retrieved June 28, 2025.
  • Minnesota Department of Health. (n.d.). Nitrate in drinking water. Access June 23, 2025. Nadeau, K., Mester, Z., & Yang, L. (2018). The direct and accurate determination of major elements Ca, K, Mg and Na in water by HR-ICPMS. Scientific Reports, 8(1), 1–6.
  • Note, A. (2024). ICP-MS Analysis of Water in Compliance with Directive (EU) 2020 / 2184 and ISO 17294-2.
  • Olympian Water Testing, LLC. (n.d.). Spring water minerals: Essential elements for optimal health. Olympian Water Testing, LLC. Access June 23, 2025.
  • Rahmani, A., Khamutian, S., Doosti-Irani, A., Shokoohizadeh, M. J., Shirmohammadi-Khorram, N., Sahraeei, F., Ahangaran, N. (2023).
  • The association of arsenic exposure with mortality due to cancer, diabetes, Alzheimer’s and congenital anomalies usin27. 27. Poisson regression. Scientific Reports, 13(1), 1–10.
  • Smedley, P. L., & Kinniburgh, D. G. (2002). A review of the source, behaviour and distribution of arsenic in natural waters. Applied geochemistry, 17(5), 517-568.
  • Smith, K. (2012). Aridland Springs in North America: Ecology and Conservation.
  • Thermo Fisher Scientific. (n.d.). Speciation analysis by IC-ICP-MS. Thermo Fisher Scientific. Retrieved June 23, 2025, from https://www.thermofisher.com.
  • Turkish Standards Institute (TSE). (2010). TSE standard. Turkish Standards Institute. Access July 22, 2025. U.S. Environmental Protection Agency. (n.d.). National primary drinking water regulations. U.S. Environmental Protection Agency. Access June 23, 2025
  • Wilschefski, S. C., & Baxter, M. R. (2019). Inductively Coupled Plasma Mass Spectrometry: Introduction to Analytical Aspects. The Clinical Biochemist Reviews, 40(3), 115. doi:10.33176/AACB-19-00024.
  • World Health Organization. (2004). Guidelines for drinking-water quality (Vol. 1). World Health Organization.
  • World Health Organization. (2017, April 24). Guidelines for drinking-water quality (4th ed., incorporating the 1st addendum). World Health Organization.
  • Yönetmelik. (2005). Resmi Gazete. Retrieved 21 July 2025.
  • Zhang, W., Miao, A. J., Wang, N. X., Li, C., Sha, J., Jia, Y. S. (2022). Arsenic bioaccumulation and biotransformation in aquatic organisms. Environment International, 163, 107221.

Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods

Year 2025, Volume: 9 Issue: 2, 254 - 261, 29.12.2025
https://doi.org/10.32571/ijct.1749462

Abstract

In this study, six different spring waters within the province of Van were analyzed using advanced and highly reliable ICP-MS and ion chromatography methods. The analyzed water sources, known as Ayanis Entrance (Ayanis Giriş), Castle Entrance (Kale Giriş), Next to the Castle (Kale Yanı), Old Van (Eski Van), Mollakasım (Mollakasım), and Kalecik (Kalecik) springs, are frequently used by the city's residents. The locations of each water source were identified, and samples were collected for inorganic elemental analysis, ion measurement, pH testing, and conductivity testing. The data on elements, ions, pH, and conductivity were used to assess potability and health risks. The analyses revealed that the water sources had quite normal values in terms of color, appearance, pH, and conductivity. Additionally, the concentrations of required elements and ions in these spring waters were compared with the standards of the WHO, EU, US, and TS 266. Generally, all water sources were found to have normal values in terms of physical appearance and pH. However, the arsenic (15.15 ppb) and boron (1.624 ppm) levels in Next to the Castle, located northwest of Van Castle and heavily utilized by local residents, were found to exceed the limit values (As: 10 ppb and B:1 ppm). This result indicates that the arsenic and boron levels, which pose a significant health risk for humans and other living organisms, exceed the limit values in the Next to Castle water source. Therefore, this study concluded that consuming the water from the spring next to the Castle would cause serious health problems.

References

  • Agilent Technologies. (2016). ICP-MS analysis of trace and major elements in drinking water according to US EPA Method 200.8 using the Agilent 7850 ICP-MS with ISIS 3. Agilent Technologies.
  • Anderson, T. W., & Riche, W. H. le. (1971). Sudden Death from Ischemic Heart Disease in Ontario. Canadian Medical Association Journal, 105(2), 155.
  • Arias, L. M. E., & Naranjo, J. (2014). Inductıvely Coupled Plasma—Mass Spectrometry SW-846. Applied Microbiology and Biotechnology, 85(1), 2071–2079.
  • Atlas Scientific. (n.d.). What is the typical water conductivity range? Atlas Scientific. Access June 28, 2025, from https://www.atlasscientific.com
  • Azoulay, A., Garzon, P., & Eisenberg, M. J. (2001). Comparison of the mineral content of tap water and bottled waters. Journal of General Internal Medicine, 16(3), 168–175.
  • Başar, Y., Gül, F., Nas, M. S., Alma, M. H., & Çalımlı, M. H. (2024). Investigation of value-added compounds derived from oak wood using hydrothermal processing techniques and comprehensive analytical approaches (HPLC, GC-MS, FT-IR, and NMR). International Journal of Chemistry and Technology, 8(1), 51-59.
  • Bondy, M. (2009). Cancer epidemiology and prevention. JAMA, 301(10), 1070-1076.
  • Brown, K. G., & Ross, G. L. (2002). Arsenic, Drinking Water, and Health: A Position Paper of the American Council on Science and Health. Regulatory Toxicology and Pharmacology, 36(2), 162–174.
  • Bueno, C., A. J., & Enzweiler, J. (2009). Quantification of major and trace elements in water samples by ICP-MS and collision cell to attenuate Ar and Cl-based polyatomic ions. Journal of Analytical Atomic Spectrometry, 24(10), 1406–1413.
  • Çavuş, A., Atıcı, A. A., & Şen, F. (2017). Van-Merkez İçme Sularının Su Kalite Kriterlerinin İncelenmesi. Yuzuncu Yil Universitesi Journal of Agricultural Sciences (YYU J Agr Sci), 27(3).
  • Chandel, M., Sharma, A. K., Thakur, K., Sharma, D., Brar, B., Mahajan, D., … Kumar, R. (2024). Poison in the water: Arsenic’s silent assault on fish health. Journal of Applied Toxicology, 44(9), 1282–1301.
  • Columbia University Mailman School of Public Health. (2025, June 17). Exposure to low levels of arsenic in public drinking water linked to lower birthweight, preterm birth. [News article]. Access October 6, 2025.
  • Crawford, M. D., Gardner, M. J., & Morris, J. N. (1968). Mortalıty and Hardness of Local Water-Supplıes. The Lancet, 291(7547), 827–831.
  • Döll, P., Fiedler, K., & Zhang, J. (2009). Global-scale analysis of river flow alterations due to water withdrawals and reservoirs. Hydrology and Earth System Sciences, 13(12), 2413–2432.
  • Famiglietti, J. S. (2014). The global groundwater crisis. Nature Climate Change, 4(11), 945–948.
  • Gabelica, V., & Marklund, E. (2018). Fundamentals of ion mobility spectrometry. Current Opinion in Chemical Biology, 42, 51–59.
  • Gemici, Ü., & Tarcan, G. (2002). Distribution of boron in thermal waters of western Anatolia, Turkey, and examples of their environmental impacts. Environmental Geology, 43(1), 87–98.
  • Gleeson, T., Wada, Y., Bierkens, M. F. P., & Van Beek, L. P. H. (2012). Water balance of global aquifers revealed by groundwater footprint. Nature, 488(7410), 197–200.
  • Hussain, M. M., Wang, J., Bibi, I., Shahid, M., Niazi, N. K., Iqbal, J., … Rinklebe, J. (2021). Arsenic speciation and biotransformation pathways in the aquatic ecosystem: The significance of algae. Journal of Hazardous Materials, 403, 124027.
  • International Organization for Standardization. (2001). ISO 15061:2001 Water quality—Determination of dissolved bromate—Method by liquid chromatography of ions. ISO. Retrieved July 22, 2025.
  • International Organization for Standardization. (2023). ISO 17294-2:2023 Water quality—Application of inductively coupled plasma mass spectrometry (ICP-MS)—Part 2: Determination of selected elements including uranium isotopes. ISO. https://www.iso.org.
  • Kim, D. H., Lee, Y. K., Hur, J., Yoo, H. J., Ko, K. S., Lee, J. M., … Cho, K. (2022). Analysis of Natural Organic Matter in Water from Cold and Hot Mineral Springs in South Korea Using 15T FT-ICR-MS. ACS Omega, 7(46), 41859–41871.
  • Li, Y., Duvert, C., Xu, P., & Bian, J. (2025). Contrasting origins of spring water in a ‘water tower’ of Northeast Asia: Evidence from stable isotopes and tritium. Journal of Hydrology, 652, 132661.
  • Marmara Üniversitesi, Doğa Bitkileri ve Su Ürünleri Araştırma ve Uygulama Merkezi. (n.d.). İçme suyu kabul edilebilir değerler. Marmara Üniversitesi. Retrieved June 28, 2025.
  • Minnesota Department of Health. (n.d.). Nitrate in drinking water. Access June 23, 2025. Nadeau, K., Mester, Z., & Yang, L. (2018). The direct and accurate determination of major elements Ca, K, Mg and Na in water by HR-ICPMS. Scientific Reports, 8(1), 1–6.
  • Note, A. (2024). ICP-MS Analysis of Water in Compliance with Directive (EU) 2020 / 2184 and ISO 17294-2.
  • Olympian Water Testing, LLC. (n.d.). Spring water minerals: Essential elements for optimal health. Olympian Water Testing, LLC. Access June 23, 2025.
  • Rahmani, A., Khamutian, S., Doosti-Irani, A., Shokoohizadeh, M. J., Shirmohammadi-Khorram, N., Sahraeei, F., Ahangaran, N. (2023).
  • The association of arsenic exposure with mortality due to cancer, diabetes, Alzheimer’s and congenital anomalies usin27. 27. Poisson regression. Scientific Reports, 13(1), 1–10.
  • Smedley, P. L., & Kinniburgh, D. G. (2002). A review of the source, behaviour and distribution of arsenic in natural waters. Applied geochemistry, 17(5), 517-568.
  • Smith, K. (2012). Aridland Springs in North America: Ecology and Conservation.
  • Thermo Fisher Scientific. (n.d.). Speciation analysis by IC-ICP-MS. Thermo Fisher Scientific. Retrieved June 23, 2025, from https://www.thermofisher.com.
  • Turkish Standards Institute (TSE). (2010). TSE standard. Turkish Standards Institute. Access July 22, 2025. U.S. Environmental Protection Agency. (n.d.). National primary drinking water regulations. U.S. Environmental Protection Agency. Access June 23, 2025
  • Wilschefski, S. C., & Baxter, M. R. (2019). Inductively Coupled Plasma Mass Spectrometry: Introduction to Analytical Aspects. The Clinical Biochemist Reviews, 40(3), 115. doi:10.33176/AACB-19-00024.
  • World Health Organization. (2004). Guidelines for drinking-water quality (Vol. 1). World Health Organization.
  • World Health Organization. (2017, April 24). Guidelines for drinking-water quality (4th ed., incorporating the 1st addendum). World Health Organization.
  • Yönetmelik. (2005). Resmi Gazete. Retrieved 21 July 2025.
  • Zhang, W., Miao, A. J., Wang, N. X., Li, C., Sha, J., Jia, Y. S. (2022). Arsenic bioaccumulation and biotransformation in aquatic organisms. Environment International, 163, 107221.
There are 38 citations in total.

Details

Primary Language English
Subjects Chemical Engineering (Other)
Journal Section Research Article
Authors

Serkan Tekçe 0009-0009-2002-8450

Gülşah Saydan Kanberoğlu 0000-0003-4265-6086

Nurcan Kaya 0000-0002-8178-1878

Mehmet Harbi Çalımlı 0000-0001-9756-191X

Submission Date July 24, 2025
Acceptance Date October 8, 2025
Early Pub Date November 25, 2025
Publication Date December 29, 2025
Published in Issue Year 2025 Volume: 9 Issue: 2

Cite

APA Tekçe, S., Saydan Kanberoğlu, G., Kaya, N., Çalımlı, M. H. (2025). Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods. International Journal of Chemistry and Technology, 9(2), 254-261. https://doi.org/10.32571/ijct.1749462
AMA Tekçe S, Saydan Kanberoğlu G, Kaya N, Çalımlı MH. Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods. Int. J. Chem. Technol. December 2025;9(2):254-261. doi:10.32571/ijct.1749462
Chicago Tekçe, Serkan, Gülşah Saydan Kanberoğlu, Nurcan Kaya, and Mehmet Harbi Çalımlı. “Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods”. International Journal of Chemistry and Technology 9, no. 2 (December 2025): 254-61. https://doi.org/10.32571/ijct.1749462.
EndNote Tekçe S, Saydan Kanberoğlu G, Kaya N, Çalımlı MH (December 1, 2025) Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods. International Journal of Chemistry and Technology 9 2 254–261.
IEEE S. Tekçe, G. Saydan Kanberoğlu, N. Kaya, and M. H. Çalımlı, “Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods”, Int. J. Chem. Technol., vol. 9, no. 2, pp. 254–261, 2025, doi: 10.32571/ijct.1749462.
ISNAD Tekçe, Serkan et al. “Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods”. International Journal of Chemistry and Technology 9/2 (December2025), 254-261. https://doi.org/10.32571/ijct.1749462.
JAMA Tekçe S, Saydan Kanberoğlu G, Kaya N, Çalımlı MH. Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods. Int. J. Chem. Technol. 2025;9:254–261.
MLA Tekçe, Serkan et al. “Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods”. International Journal of Chemistry and Technology, vol. 9, no. 2, 2025, pp. 254-61, doi:10.32571/ijct.1749462.
Vancouver Tekçe S, Saydan Kanberoğlu G, Kaya N, Çalımlı MH. Determination of Trace Elements and Anions in Six Different Natural Spring Waters in Van Province by ICP-MS and Ion Chromatography Methods. Int. J. Chem. Technol. 2025;9(2):254-61.