Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies

Ali Kara; Muhsin Kılıç; Nalan Tekin; Nuray Dinibütün; Akif Şafaklı

doi:10.32571/ijct.341542

EN

Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies

Abstract

For removal of Cu(II) ions from aqueous solution, a novel composite was prepared from 1-vinyl imidazole and sepiolite by the technique of in-situ polymerization. Adsorption of Cu(II) ions from aqueous solution onto Sepiolite-Poly(vinylimidazole) composite has been studied at 277, 298, 318, and 338 K and the experimental data were analyzed using fourteen isotherm models. The determination coefficients (R²) were determined for each isotherm analysis. The determination coefficients demonstrated that in general the accuracy of models to fit experimental data improves with the number of parameters. The Langmuir model provided the best fit to the experimental data among the two-parameter isotherms. The Toth model provided the best fit to the data among the three-parameter models. Adsorption isotherm modeling shows that the interaction of Cu(II) with Sepiolite-Poly(vinylimidazole) composite surface is localized to monolayer sorption and adsorption is an endothermic process. Additionally, adsorption experiments showed that Sepiolite-Poly(vinylimidazole) composite can be used as an effective adsorbent for the removal of Cu(II) ions from aqueous solution.

Keywords

Clay,composite,heavy metal,isotherms,nonlinear methods

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Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Ali Kara ^*
Uludag Univ
0000-0003-2457-6314
Türkiye

Muhsin Kılıç
Türkiye

Nalan Tekin

Nuray Dinibütün This is me
Türkiye

Akif Şafaklı This is me
Türkiye

Publication Date

February 16, 2018

Submission Date

October 3, 2017

Acceptance Date

February 13, 2018

Published in Issue

Year 2018 Volume: 2 Number: 1

DOI

https://doi.org/10.32571/ijct.341542

IZ

https://izlik.org/JA84TC35HC

Cite

RIS / Bibtex

APA

Kara, A., Kılıç, M., Tekin, N., Dinibütün, N., & Şafaklı, A. (2018). Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. International Journal of Chemistry and Technology, 2(1), 20-33. https://doi.org/10.32571/ijct.341542

AMA

1.Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A. Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. Int. J. Chem. Technol. 2018;2(1):20-33. doi:10.32571/ijct.341542

Chicago

Kara, Ali, Muhsin Kılıç, Nalan Tekin, Nuray Dinibütün, and Akif Şafaklı. 2018. “Application of Sepiolite-Poly(vinylimidazole) Composite for the Removal of Cu(II) from Aqueous Solution: Isotherm and Thermodynamics Studies”. International Journal of Chemistry and Technology 2 (1): 20-33. https://doi.org/10.32571/ijct.341542.

EndNote

Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A (June 1, 2018) Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. International Journal of Chemistry and Technology 2 1 20–33.

IEEE

[1]A. Kara, M. Kılıç, N. Tekin, N. Dinibütün, and A. Şafaklı, “Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies”, Int. J. Chem. Technol., vol. 2, no. 1, pp. 20–33, June 2018, doi: 10.32571/ijct.341542.

ISNAD

Kara, Ali - Kılıç, Muhsin - Tekin, Nalan - Dinibütün, Nuray - Şafaklı, Akif. “Application of Sepiolite-Poly(vinylimidazole) Composite for the Removal of Cu(II) from Aqueous Solution: Isotherm and Thermodynamics Studies”. International Journal of Chemistry and Technology 2/1 (June 1, 2018): 20-33. https://doi.org/10.32571/ijct.341542.

JAMA

1.Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A. Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. Int. J. Chem. Technol. 2018;2:20–33.

MLA

Kara, Ali, et al. “Application of Sepiolite-Poly(vinylimidazole) Composite for the Removal of Cu(II) from Aqueous Solution: Isotherm and Thermodynamics Studies”. International Journal of Chemistry and Technology, vol. 2, no. 1, June 2018, pp. 20-33, doi:10.32571/ijct.341542.

Vancouver

1.Ali Kara, Muhsin Kılıç, Nalan Tekin, Nuray Dinibütün, Akif Şafaklı. Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. Int. J. Chem. Technol. 2018 Jun. 1;2(1):20-33. doi:10.32571/ijct.341542