Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine

Yeliz İpek; M. Kasım Şener; Atıf Koca

doi:10.32571/ijct.342498

EN

Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine

Abstract

In this study, a biomimetic selective pesticide electrochemical sensor based on copper phthalocyanine-anthraquinone hybrid (CuPc-AQ) was studied. Electrochemical activities based on Pc ring and anthraquinone substituent of the CuPc-AQ make it valuable material for electrochemical sensor studies in detecting of pesticides. Thin film of CuPc-AQ on ITO electrode (ITO/CuPc-AQ) was exposed to water samples containing eserine and carbofuran pesticides, separately. Then in order to observe the sensor behavior of the modified electrode, square wave voltammetry (SWV), electrochemical impedance spectroscopy (EIS), and double potential step chronocoulometry (DPSCC) techniques were used. When the ITO/CuPc-AQ electrode was doped with nano-platinum (nPt) or nano-gold (nAu) particles, the sensitivity of ITO/CuPc-AQ electrode increased. The lowest detection limit (DL) (1.23x10-9 mol dm-3) was obtained with ITO/CuPc-AQ-nAu electrode using electrochemical impedance spectroscopy technique.

Keywords

Electrochemistry,Phthalocyanine,Pesticide sensor,Langmuir-Blodgett

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Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Yeliz İpek
MUNZUR ÜNİVERSİTESİ
0000-0002-9390-9875
Türkiye

M. Kasım Şener This is me
Yıldız Technical University
0000-0003-3560-2995
Türkiye

Atıf Koca
Marmara University
0000-0003-0141-5817
Türkiye

Publication Date

December 29, 2017

Submission Date

October 19, 2017

Acceptance Date

December 26, 2017

Published in Issue

Year 2017 Volume: 1 Number: 1

DOI

https://doi.org/10.32571/ijct.342498

IZ

https://izlik.org/JA49GT24UU

Cite

RIS / Bibtex

APA

İpek, Y., Şener, M. K., & Koca, A. (2017). Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine. International Journal of Chemistry and Technology, 1(1), 74-85. https://doi.org/10.32571/ijct.342498

AMA

1.İpek Y, Şener MK, Koca A. Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine. Int. J. Chem. Technol. 2017;1(1):74-85. doi:10.32571/ijct.342498

Chicago

İpek, Yeliz, M. Kasım Şener, and Atıf Koca. 2017. “Electrochemical Pesticide Sensor Based on Anthraquinone Substituted Copper Phthalocyanine”. International Journal of Chemistry and Technology 1 (1): 74-85. https://doi.org/10.32571/ijct.342498.

EndNote

İpek Y, Şener MK, Koca A (December 1, 2017) Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine. International Journal of Chemistry and Technology 1 1 74–85.

IEEE

[1]Y. İpek, M. K. Şener, and A. Koca, “Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine”, Int. J. Chem. Technol., vol. 1, no. 1, pp. 74–85, Dec. 2017, doi: 10.32571/ijct.342498.

ISNAD

İpek, Yeliz - Şener, M. Kasım - Koca, Atıf. “Electrochemical Pesticide Sensor Based on Anthraquinone Substituted Copper Phthalocyanine”. International Journal of Chemistry and Technology 1/1 (December 1, 2017): 74-85. https://doi.org/10.32571/ijct.342498.

JAMA

1.İpek Y, Şener MK, Koca A. Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine. Int. J. Chem. Technol. 2017;1:74–85.

MLA

İpek, Yeliz, et al. “Electrochemical Pesticide Sensor Based on Anthraquinone Substituted Copper Phthalocyanine”. International Journal of Chemistry and Technology, vol. 1, no. 1, Dec. 2017, pp. 74-85, doi:10.32571/ijct.342498.

Vancouver

1.Yeliz İpek, M. Kasım Şener, Atıf Koca. Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine. Int. J. Chem. Technol. 2017 Dec. 1;1(1):74-85. doi:10.32571/ijct.342498

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