Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel

Leyla Kule; Bilal Acemioğlu; Evrim Baran

doi:10.32571/ijct.344732

EN

Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel

Abstract

Kinetics, thermodynamics and isotherm studies of malachite green (MG) adsorption by orange peel (OP) modified with ethanol, calcium chloride and sodium hydroxide were performed. Effects of initial dye concentration, temperature and pH on the adsorption were studied at the different contact times. The amounts of MG adsorbed onto OP increased with increasing contact time, initial dye concentration, solution temperature, and pH. Maximum dye adsorption was about 92.90% under all the experimental conditions. Percent desorption of MG from the surface of OP was lower in the alkali and HCl solutions and higher in an acetone-water mixture of 50%. Adsorption kinetics was best fit the pseudo-second order model with correlation coefficients of 0.99 and 1 for the concentrations studied. Thermodynamic results indicated a spontaneous adsorption. Adsorption isotherm obeyed the Langmuir model. The Langmuir adsorption capacity was determined as 14.55 mg g^-1. FT-IR and SEM analyses were also recorded before and after the adsorption.

Keywords

: Adsorption kinetics,thermodynamics,malachite green,orange peel

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Details

Primary Language

English

Subjects

Environmental Engineering, Chemical Engineering

Journal Section

Research Article

Authors

Leyla Kule
0000-0002-2222-9186
Türkiye

Bilal Acemioğlu
0000-0002-0728-2747
Türkiye

Evrim Baran
0000-0003-3551-8451
Türkiye

Publication Date

November 27, 2017

Submission Date

October 17, 2017

Acceptance Date

November 25, 2017

Published in Issue

Year 2017 Volume: 1 Number: 1

DOI

https://doi.org/10.32571/ijct.344732

IZ

https://izlik.org/JA69HT93XH

Cite

RIS / Bibtex

APA

Kule, L., Acemioğlu, B., & Baran, E. (2017). Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel. International Journal of Chemistry and Technology, 1(1), 58-66. https://doi.org/10.32571/ijct.344732

AMA

1.Kule L, Acemioğlu B, Baran E. Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel. Int. J. Chem. Technol. 2017;1(1):58-66. doi:10.32571/ijct.344732

Chicago

Kule, Leyla, Bilal Acemioğlu, and Evrim Baran. 2017. “Kinetics, Thermodynamics and Isotherm Studies of Malachite Green Adsorption by Modified Orange Peel”. International Journal of Chemistry and Technology 1 (1): 58-66. https://doi.org/10.32571/ijct.344732.

EndNote

Kule L, Acemioğlu B, Baran E (December 1, 2017) Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel. International Journal of Chemistry and Technology 1 1 58–66.

IEEE

[1]L. Kule, B. Acemioğlu, and E. Baran, “Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel”, Int. J. Chem. Technol., vol. 1, no. 1, pp. 58–66, Dec. 2017, doi: 10.32571/ijct.344732.

ISNAD

Kule, Leyla - Acemioğlu, Bilal - Baran, Evrim. “Kinetics, Thermodynamics and Isotherm Studies of Malachite Green Adsorption by Modified Orange Peel”. International Journal of Chemistry and Technology 1/1 (December 1, 2017): 58-66. https://doi.org/10.32571/ijct.344732.

JAMA

1.Kule L, Acemioğlu B, Baran E. Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel. Int. J. Chem. Technol. 2017;1:58–66.

MLA

Kule, Leyla, et al. “Kinetics, Thermodynamics and Isotherm Studies of Malachite Green Adsorption by Modified Orange Peel”. International Journal of Chemistry and Technology, vol. 1, no. 1, Dec. 2017, pp. 58-66, doi:10.32571/ijct.344732.

Vancouver

1.Leyla Kule, Bilal Acemioğlu, Evrim Baran. Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel. Int. J. Chem. Technol. 2017 Dec. 1;1(1):58-66. doi:10.32571/ijct.344732

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Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel

Abstract

Kinetics, thermodynamics and isotherm studies of malachite green adsorption by modified orange peel

Abstract

Keywords

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

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