Adsorption of safranin-O dye by peanut shell-based polyurethane type foam

Bilal Acemioğlu; Melike Hilal Bilir; Mehmet Hakkı Alma

doi:10.32571/ijct.454516

EN

Adsorption of safranin-O dye by peanut shell-based polyurethane type foam

Abstract

The adsorption of safranin-O dye was performed in batch and continuous column sysytems by polyurethane-type rigid foam produced from peanut shell. In batch system, effects of contact time, initial dye concentration, solution pH and temperature on the adsorption were investigated. In column system, solution flow rate and initial dye concentration effect were studied. Under conditions studied, the adsorption of safranin-O was 95-99% for batch system, and 93-99% for column system. Adsorption isotherm best followed the Langmuir model (R² = 0.986). Adsorption kinetics was in consistent with best the pseudo-second order model (R²values ≥ 0.998). Adsorption was of sponteneous nature and in favor of increasing temperature (i.e. endothermic nature). For example, when the temperature was increased from 20 to 60°C, standard Gibbs free energy change (ΔG°) dereased regularitly from -5303 to -8170 J mol^-1. The values of standard enthalpy (ΔH°) and standard entropy (ΔS°) were estimated as 13.35 kJ mol^-1 and 0.64 kJ mol^-1K^-1, respectively. Moreover, FTIR and SEM analyses were done, and the results were interpreated in detail.

Keywords

Peanut shell,polyurethane foam,safranin-O,adsorption

References

1. Naseem, K.; Farooqi, Z. H.; Begum, R.; Ghufran, M.; UrRehman, M. Z.; Najeeb, J.; Irfan, A.; .Al-Sehemi, A.G. J. Mol. Liq. 2018, 268, 229-238.
2. Fu, J.; Xin, Q.; Wu, X.; Chen, Z.; Yan, Y.; Liu, S.; Wang, M.; Xu, Q. J. Colloid Interf. Sci. 2016, 461, 292-304.
3. Acemioğlu, B. J. Colloid Interf. Sci. 2004, 274, 371-379.
4. Acemioğlu, B. Chem. Eng. J. 2005, 106, 73-81.
5. Uğurlu, M. Microporous Mesoporous Mater. 2009, 119, 276-283.
6. Vanaamudan, A.; Pathan, N.; Pamidimukkala, P. Desalin. Water Treat. 2014, 52 (7-9) 1589-1599.
7. Bankole, P.O.; Adekunle, A.A.; Govindwar, S.P. J. Environ. Chem. Eng. 2018, 6(2), 1589-1600.
8. Acemioğlu, B.; Kertmen, M.; Digrak, M.; Alma, M.H.; Temiz, F. Asian J. Chem. 2010, 22(2), 1394-1402.

9. Martorell, M. M.; Pajot, H. F.; de Figueroa, L. I. C. J. Environ. Chem. Eng. 2017, 5987-5993.
10. Errgene, A.; Ada, K.; Tan, S.; Katırcıoğlu, H. Desalination 2009, 249, 1308-1314.
11. Sartape, A.S.; Mandhare, A.M.; Jadhav, V.V.; Raut, P.D.; Kolekar, S.S. Arabian J. Chem. 2017, 3229-3238.
12. Şen, A.; Pereira, H.; Olivella, M. A.; Villaescusa, I. Int. J. Environ. Sci. Technol. 2015, 12, 391-404.
13. Acemioğlu, B.; Alma, M. H.; Demirkıran, A. R. J. Chem. Soc. Pak. 2004, 26(1), 82-89.
14. Ning-chuan, F.; Xue-yi, G. Trans. Nonferrous Met. Soc. China 2012, 22, 1224-1231.
15. Temesgen, F.; Gabbiye, N.; Sahu, O. Surfaces Interfaces 2018, 12, 151-159.
16. Amela, K.; Hassen, M. A.; Kerroum, D. Energy Proced. 2012,19, 286-295.
17. Kule, L.; Acemioğlu, B.; Baran, E. Int. J. Chem. Technol. 2017, 1, 58-66.
18. Tanyildizi, M.Ş. Chem. Eng. J. 2011, 168(3), 1234-1240.
19. Kara, A.; Acemioğlu, B.; Alma, M.H.; Cebe, M. J. Appl. Polym. 2006, 101, 2838-2846.
20. Kupeta, A. J. K.; Naidoo, E. B.; Ofomaja, A. E. J. Clean. Prod. 2018, 179, 191-209.
21. Domínguez-Robles, J.; Peresin, M.S.; Tamminen, T.; Rodríguez, A.; Jääskeläinen, A.S. Int. J. Biol. Macromol. 2018, 115, 1249-1259.
22. Bilir, M. H.; Sakalar, N.; Acemioğlu, B.; Baran, E.; Alma, M. H. J. Appl. Polym. Sci. 2013, 6, 4340-4350.
23. Sakalar, N.; Bilir, M. H.; Acemioğlu, B.; Hakkı Alma, M. H. Asian J. Chem. 2010, 22(7), 5649-5662.
24. Sahu, M.K.; Patel, R.K. RSC Adv. 2015, 5, 78491-78501.
25. Dmitrienko, S. G.; Siviridova, O. A.; Pyatkova, L. N.; Senyamin, V. M. Anal. Bioanal. Chem. 2002, 374(3), 361-368.
26. Hameed, B. H.; Mahmoud, D. K.; Ahmad, A.L.; J. Hazard. Mater. 2008, 158(2-3) 499-506.
27. Bayramoğlu, G.; Arica, M. Y. J. Hazard. Mater. 2007, 143(1-2), 135-143.
28. Dwivedi, M. K., Neeraj Jain, Pragati Sharma and Chanchala Alawa, J. Appl. Chem. 2015, 8, 27-35.
29. Liu, R.; Zhang, B.; Mei, D.; Zhang, H.; Liu, J. Desalination 2011, 268, 111-116.
30. Lakshmi Prasanna, M.; Sumithra, S.; Madakka, M. Int. J. Recent Scientific Research 2016, 7 (4), 10401-10405.
31. Weber, W.J.; Morris, J.C. J. Sanit Eng. Div. 1963, 89, 31-59.
32. Lagergren, S. Kung. Sven. Veten. Hand. 1898, 24, 1-39.
33. Y. S. Ho, G. Mckay, Chem. Eng. J. 1998, 70(2), 115-124.
34. Azizian, S.; Haerifar, M.; Bashiri, H. Chem. Eng. J. 2009, 146, 36-41.
35. Moawed, E.A.; Abulkibash, A.B. J. Saudi Chem. Soc. 2016, 20, S178-S185.
36. Acemioğlu, B. Bioresour. Technol. 2004, 93, 99-102.
37. Hema M.; Arivoli, S. Int. J. Phys. Sci. 2007, 2, 10-17.
38. Fayazi, M.; Afzali, D.; Taher, M.A.; Mostafavi, A.; Gupta, V.K. J. Mol. Liq. 2015, 212, 675-685.
39. Adebowale, K. A.; Olu-Owalabi, B. I.; Chigbundu, E. C. J. Encapsulation Adsorption Sci. 2014, 4, 89-104.
40. Yusuf, M.; Elfghi, F. M.; Mallak, S. K. Iranica J. Energy Environ. 2015, 6, 173-180.
41. Kumar, K.V.; Sivanesan, S. Dyes Pigm. 2007, 72,130-133.
42. Dehury, K. K. MSc. Thesis, Removal of Safranin-O dye from aqueous solution using acid activated red mud. National Institute of Technology, Rourkela, 2014.
43. Laskar, N.; Kumar, U. IOP Conf. Ser. Mater. Sci. Eng. 2017, 225, 012105.
44. Farahani, M.; Kashisaz, M.; Abdullah. S.R.S. Inter. J. Ecol. Sci. Environ. Eng. 2015, 2(3), 17-29.

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Bilal Acemioğlu ^*
0000-0002-0728-2747
Türkiye

Melike Hilal Bilir This is me
0000-0001-9987-1882
Türkiye

Mehmet Hakkı Alma
0000-0001-6323-7230

Publication Date

December 28, 2018

Submission Date

August 18, 2018

Acceptance Date

October 1, 2018

Published in Issue

Year 2018 Volume: 2 Number: 2

DOI

https://doi.org/10.32571/ijct.454516

IZ

https://izlik.org/JA95KN53KH

Cite

RIS / Bibtex

APA

Acemioğlu, B., Bilir, M. H., & Alma, M. H. (2018). Adsorption of safranin-O dye by peanut shell-based polyurethane type foam. International Journal of Chemistry and Technology, 2(2), 95-104. https://doi.org/10.32571/ijct.454516

AMA

1.Acemioğlu B, Bilir MH, Alma MH. Adsorption of safranin-O dye by peanut shell-based polyurethane type foam. Int. J. Chem. Technol. 2018;2(2):95-104. doi:10.32571/ijct.454516

Chicago

Acemioğlu, Bilal, Melike Hilal Bilir, and Mehmet Hakkı Alma. 2018. “Adsorption of Safranin-O Dye by Peanut Shell-Based Polyurethane Type Foam”. International Journal of Chemistry and Technology 2 (2): 95-104. https://doi.org/10.32571/ijct.454516.

EndNote

Acemioğlu B, Bilir MH, Alma MH (December 1, 2018) Adsorption of safranin-O dye by peanut shell-based polyurethane type foam. International Journal of Chemistry and Technology 2 2 95–104.

IEEE

[1]B. Acemioğlu, M. H. Bilir, and M. H. Alma, “Adsorption of safranin-O dye by peanut shell-based polyurethane type foam”, Int. J. Chem. Technol., vol. 2, no. 2, pp. 95–104, Dec. 2018, doi: 10.32571/ijct.454516.

ISNAD

Acemioğlu, Bilal - Bilir, Melike Hilal - Alma, Mehmet Hakkı. “Adsorption of Safranin-O Dye by Peanut Shell-Based Polyurethane Type Foam”. International Journal of Chemistry and Technology 2/2 (December 1, 2018): 95-104. https://doi.org/10.32571/ijct.454516.

JAMA

1.Acemioğlu B, Bilir MH, Alma MH. Adsorption of safranin-O dye by peanut shell-based polyurethane type foam. Int. J. Chem. Technol. 2018;2:95–104.

MLA

Acemioğlu, Bilal, et al. “Adsorption of Safranin-O Dye by Peanut Shell-Based Polyurethane Type Foam”. International Journal of Chemistry and Technology, vol. 2, no. 2, Dec. 2018, pp. 95-104, doi:10.32571/ijct.454516.

Vancouver

1.Bilal Acemioğlu, Melike Hilal Bilir, Mehmet Hakkı Alma. Adsorption of safranin-O dye by peanut shell-based polyurethane type foam. Int. J. Chem. Technol. 2018 Dec. 1;2(2):95-104. doi:10.32571/ijct.454516