EN
SUPER PLASTICIZER POLYMER SYNTHESIS
Abstract
In this study, it is aimed to synthesize more environmentally friendly and low-cost biopolymer based super plasticizers (SP) by using biopolymers (starch, chitosan polysaccharide, floral oils, etc.), acrylic acid, maleic anhydride, sodium vinyl sulphonate and various corn starches and various catalysts. These raw materials have been examined in terms of their water holding capacity, viscosity, bond structures and renewability. For the structure determination of the synthesized products, FT-IR, fluidity and compressive strength tests are performed. Because it is aimed also to meet the local consumption of cement materials additives in Turkey. In this process, it is to protect our environment by making it bio-based as much as we can, away from today's chemicals and petroleum derivatives. Three different types of polymer are synthesized: flower oil, bowine gelatine and mpeg5000. The ratio of sand:cement:water in the cement mixture used in the study is 2:1:0.45. Synthesized SP polymers were added to the cement mixture at a rate of 0.75%. In the experiments by connecting a plurality of parameters when selecting the appropriate optimal values according to the appropriate product and polymerizing bond products it was synthesized. FTIR results match the peaks in each raw material. So detailed generalization of the bond structure is appropriate. It can be said that bio raw material synthesis is encouraging in the future, and it can be found that form the compressive strength test, the flower oil being more resistant. As a result of this study, three types of polymeric additives were successfully synthesized and analyzed and performance tests were completed.
Keywords
References
- [1] Liu X., Wang Z., Zheng Y., Cui S., Lan M., Li H., Zhu J., Liang X. Preparation, Characterization and Performances of Powdered Polycarboxylate Superplasticizer with Bulk Polymerization. College of Materials Science and Engineering 2014; 7: 6169-6183.
- [2] Arat R. Synthesis and Characterization of New Generationpolymeric Additives for Cem I Cement Mortar, MSc, İstanbul Technical University, İstanbul, Turkey, 2010, 1-68.
- [3] Hui W., Huiling G., Jiaheng L., Ronguo Z., Yong L. Research on synthesis and action mechanism of polycarboxylate superplasticizer. Front. Chem. China 2007, 2(3): 322–325.
- [4] Flatt R., Schober I. Superplasticizers and the Rheology of Concrete. In Nicolas Roussel. 1 st ed. Understanding the Rheology of Concrete. Woodhead, 2012.
- [5] Houst Yves F., Bowen P., Perche F., Kauppi A., Borget P., Galmiche L., Le Meins J.F., Lafuma F., Flatt R.J., Schober I. Design and Function of Novel Superplasticizers for more Durable High performance Concrete (Superplast Project). Cement and Concrete Research, 2008, 38: 1197–1209.
- [6] Liu X., Guan J. Yunsheng Z., Wang Z., Ren X. Synthesis of High Performance Polycarboxylate Superplasticizer through Redox Initiation System and its Application in Concrete. College of Materials Science and Engineering, 2016, 723: 681-686.
- [7] Rongguo Z., Qiong L., Anfu Z., Yong L., Jiaheng L. The Synthesis Technique of Polyacrylic Acid Superplasticizer. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2008, 23, (6): 830-833.
- [8] Dinakar, P., & Manu, S. N. Concrete Mix Design for High Strength Selfcompacting Concrete using Metakaolin. Materials and Design, 2014, 60: 661–668.
Details
Primary Language
English
Subjects
Chemical Engineering (Other)
Journal Section
Research Article
Publication Date
June 10, 2024
Submission Date
January 11, 2024
Acceptance Date
June 10, 2024
Published in Issue
Year 2024 Volume: 9 Number: 1
APA
Davuça, O., & Uraz, C. (2024). SUPER PLASTICIZER POLYMER SYNTHESIS. The International Journal of Energy and Engineering Sciences, 9(1), 29-41. https://izlik.org/JA22XS52UC
AMA
1.Davuça O, Uraz C. SUPER PLASTICIZER POLYMER SYNTHESIS. IJEES. 2024;9(1):29-41. https://izlik.org/JA22XS52UC
Chicago
Davuça, Onur, and Canan Uraz. 2024. “SUPER PLASTICIZER POLYMER SYNTHESIS”. The International Journal of Energy and Engineering Sciences 9 (1): 29-41. https://izlik.org/JA22XS52UC.
EndNote
Davuça O, Uraz C (June 1, 2024) SUPER PLASTICIZER POLYMER SYNTHESIS. The International Journal of Energy and Engineering Sciences 9 1 29–41.
IEEE
[1]O. Davuça and C. Uraz, “SUPER PLASTICIZER POLYMER SYNTHESIS”, IJEES, vol. 9, no. 1, pp. 29–41, June 2024, [Online]. Available: https://izlik.org/JA22XS52UC
ISNAD
Davuça, Onur - Uraz, Canan. “SUPER PLASTICIZER POLYMER SYNTHESIS”. The International Journal of Energy and Engineering Sciences 9/1 (June 1, 2024): 29-41. https://izlik.org/JA22XS52UC.
JAMA
1.Davuça O, Uraz C. SUPER PLASTICIZER POLYMER SYNTHESIS. IJEES. 2024;9:29–41.
MLA
Davuça, Onur, and Canan Uraz. “SUPER PLASTICIZER POLYMER SYNTHESIS”. The International Journal of Energy and Engineering Sciences, vol. 9, no. 1, June 2024, pp. 29-41, https://izlik.org/JA22XS52UC.
Vancouver
1.Onur Davuça, Canan Uraz. SUPER PLASTICIZER POLYMER SYNTHESIS. IJEES [Internet]. 2024 Jun. 1;9(1):29-41. Available from: https://izlik.org/JA22XS52UC