Araştırma Makalesi
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Yıl 2021, Cilt 8, Sayı 3, 344 - 349, 05.09.2021
https://doi.org/10.30897/ijegeo.881056

Öz

Kaynakça

  • Al-Ghezawi, N., Şanli, O., & Işiklan, N. (2006). Permeation and separation characteristics of acetic acid-water mixtures by pervaporation through acrylonitrile and hydroxy ethyl methacrylate grafted poly(vinyl alcohol) membrane. Separation Science and Technology, 41(13), 2913–2931. https://doi.org/10.1080/01496390600786010
  • Ang, M. B. M. Y., Huang, S. H., Chang, M. W., Lai, C. L., Tsai, H. A., Hung, W. S., … Lee, K. R. (2020). Ultraviolet-initiated graft polymerization of acrylic acid onto thin-film polyamide surface for improved ethanol dehydration performance of pervaporation membranes. Separation and Purification Technology, 235(July 2019), 116155. https://doi.org/10.1016/j.seppur.2019.116155
  • Asman, G., & Şanli, O. (2006). Separation characteristics of acetic acid-water mixtures using poly(vinyl alcohol-g-4-vinyl pyridine) membranes by pervaporation and temperature difference evapomeation techniques. Journal of Applied Polymer Science, 100(2), 1385–1394. https://doi.org/10.1002/app.23676
  • Bowen, T. C., Noble, R. D., & Falconer, J. L. (2004). Fundamentals and applications of pervaporation through zeolite membranes. Journal of Membrane Science, 245(1–2), 1–33. https://doi.org/10.1016/j.memsci.2004.06.059
  • Bui, T. D., Wong, Y., Thu, K., Oh, S. J., Kum Ja, M., Ng, K. C., … Chua, K. J. (2017). Effect of hygroscopic materials on water vapor permeation and dehumidification performance of poly(vinyl alcohol) membranes. Journal of Applied Polymer Science, 134(17), 1–9. https://doi.org/10.1002/app.44765
  • Dmitrenko, M., Kuzminova, A., Zolotarev, A., Ermakov, S., Roizard, D., & Penkova, A. (2020). Enhanced pervaporation properties of PVA-based membranes modified with polyelectrolytes. application to IPA dehydration. Polymers, 12(1), 1–22. https://doi.org/10.3390/polym12010014
  • Fan, S., Wang, Y., Li, C., Lee, K., Liaw, D., & Lai, J. (2003). Permselectivities of 2,2’-Dimethyl-4,4’-bis(aminophenoxyl)- biphenyl Diphenyl Methane–Based Aromatic Polyamide Membranes for Aqueous Alcohol Mixtures in Pervaporation and Evapomeation. Journal of Applied Polymer Science, 88, 2688–2697.
  • George, S. P., & Barto, B. (1910). Vapor Pressure Data for Isopropyl Alcohol and Tertiary Butyl Alcohol. Contribution From The Chemistry Department of Stanford University, 50, 24–26.
  • Işiklan, N., & Şanli, O. (2004). Permeation and separation characteristics of acetic acid/water mixtures through poly(vinyl alcohol-g-itaconic acid) membranes by pervaporation, evapomeation, and temperature-difference evapomeation. Journal of Applied Polymer Science, 93(5), 2322–2333. https://doi.org/10.1002/app.20710
  • Işiklan, N., & Şanli, O. (2005). Permeation and separation characteristics of acetic acid-water mixtures through poly(vinyl alcohol)/malic acid membranes by evapomeation and temperature difference controlled evapomeation. Separation Science and Technology, 40(5), 1083–1101. https://doi.org/10.1081/SS-200048179
  • Kahya, S., Solak, E. K., & Şanli, O. (2010). Sodium alginate/poly(vinyl alcohol) alloy membranes for the pervaporation, vapour permeation and vapour permeation with temperature difference separation of dimethylformamide/water mixtures: A comparative study. Vacuum, 84(9), 1092–1102. https://doi.org/10.1016/j.vacuum.2010.01.033
  • Kurşun, F. (2020). Application of PVA-b-NaY zeolite mixture membranes in pervaporation method. Journal of Molecular Structure, 1201. https://doi.org/10.1016/j.molstruc.2019.127170
  • Kwon, Y., Chaudhari, S., Kim, C., Son, D., Park, J., Moon, M., … Nam, S. (2018). Ag-exchanged NaY zeolite introduced polyvinyl alcohol/polyacrylic acid mixed matrix membrane for pervaporation separation of water/isopropanol mixture. RSC Advances, 8(37), 20669–20678. https://doi.org/10.1039/c8ra03474e
  • Park, J. Y., Jung, H. C., Raju, G. S. R., Moon, B. K., Jeong, J. H., Choi, H. Y., & Kim, J. H. (2013). Facile solvothermal synthesis and polarity based tunable morphologies of ZnO nanocrystals. Ceramics International, 39(6), 6599–6606. https://doi.org/10.1016/j.ceramint.2013.01.095
  • Petrucci, R.H., Harwood, W.S., Herring, F. G. (2010). Genel Kimya. (S. Uyar, T., Aksoy, Ed.). Ankara: Palme Yayıncılık.
  • Salehian, P., & Chung, T. S. (2017). Two-dimensional (2D) particle coating on membranes for pervaporation dehydration of isopropanol: A new approach to seal defects and enhance separation performance. Journal of Membrane Science, 544(June), 378–387. https://doi.org/10.1016/j.memsci.2017.09.038
  • Uragami, T. (2017). Pervaporation and Evapomeation with Si-Containing Polymers. In Membrane Materials for Gas and Vapor Separation (Vol. 10, pp. 335–372). John Wiley & Sons, Ltd. https://doi.org/https://doi.org/10.1002/9781119112747.ch10
  • Uragami, T. (2018). Functional Separation Membranes From Grafted Biopolymers. Biopolymer Grafting: Synthesis and Properties. Elsevier Inc. https://doi.org/10.1016/B978-0-323-48104-5.00002-0
  • Uragami, T., & Morikawa, T. (1989). Permeation of ethanol through poly(dimethylsiloxane) membranes using temperature differences in membrane permeation processes of the evapomeation method. Die Makromolekulare Chemie, Rapid Communications, 10(6), 287–291. https://doi.org/10.1002/marc.1989.030100609

The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes

Yıl 2021, Cilt 8, Sayı 3, 344 - 349, 05.09.2021
https://doi.org/10.30897/ijegeo.881056

Öz

In this study, the permeation and separation characteristics during the evapomeation and temperature-difference controlling evapomeation (TDEV) of an isopropyl alcohol/water (IPA/water) azeotrope through poly(vinyl alcohol)/NaY (PVA/NaY) membranes were studied. The effects of operation temperature and feed concentration on the membrane separation factor and flux have been carried out for evapomeation and TDEV. It was observed that the separation factor decreased and the total and partial flux values increased, with increasing the water percentage in the feed concentration and the temperature by using evapomeation and TDEV. The permeation and diffusion activation energies for IPA/water mixture through PVA/NaY membrane were calculated as 23.69 and 41.61 kj/mol, respectively. The results of PVA and PVA/NaY membranes were supported by swelling behaviors. The best separation factor was obtained as 2097.38 using the evaporation method and 2483.75 using the TDEV method.

Kaynakça

  • Al-Ghezawi, N., Şanli, O., & Işiklan, N. (2006). Permeation and separation characteristics of acetic acid-water mixtures by pervaporation through acrylonitrile and hydroxy ethyl methacrylate grafted poly(vinyl alcohol) membrane. Separation Science and Technology, 41(13), 2913–2931. https://doi.org/10.1080/01496390600786010
  • Ang, M. B. M. Y., Huang, S. H., Chang, M. W., Lai, C. L., Tsai, H. A., Hung, W. S., … Lee, K. R. (2020). Ultraviolet-initiated graft polymerization of acrylic acid onto thin-film polyamide surface for improved ethanol dehydration performance of pervaporation membranes. Separation and Purification Technology, 235(July 2019), 116155. https://doi.org/10.1016/j.seppur.2019.116155
  • Asman, G., & Şanli, O. (2006). Separation characteristics of acetic acid-water mixtures using poly(vinyl alcohol-g-4-vinyl pyridine) membranes by pervaporation and temperature difference evapomeation techniques. Journal of Applied Polymer Science, 100(2), 1385–1394. https://doi.org/10.1002/app.23676
  • Bowen, T. C., Noble, R. D., & Falconer, J. L. (2004). Fundamentals and applications of pervaporation through zeolite membranes. Journal of Membrane Science, 245(1–2), 1–33. https://doi.org/10.1016/j.memsci.2004.06.059
  • Bui, T. D., Wong, Y., Thu, K., Oh, S. J., Kum Ja, M., Ng, K. C., … Chua, K. J. (2017). Effect of hygroscopic materials on water vapor permeation and dehumidification performance of poly(vinyl alcohol) membranes. Journal of Applied Polymer Science, 134(17), 1–9. https://doi.org/10.1002/app.44765
  • Dmitrenko, M., Kuzminova, A., Zolotarev, A., Ermakov, S., Roizard, D., & Penkova, A. (2020). Enhanced pervaporation properties of PVA-based membranes modified with polyelectrolytes. application to IPA dehydration. Polymers, 12(1), 1–22. https://doi.org/10.3390/polym12010014
  • Fan, S., Wang, Y., Li, C., Lee, K., Liaw, D., & Lai, J. (2003). Permselectivities of 2,2’-Dimethyl-4,4’-bis(aminophenoxyl)- biphenyl Diphenyl Methane–Based Aromatic Polyamide Membranes for Aqueous Alcohol Mixtures in Pervaporation and Evapomeation. Journal of Applied Polymer Science, 88, 2688–2697.
  • George, S. P., & Barto, B. (1910). Vapor Pressure Data for Isopropyl Alcohol and Tertiary Butyl Alcohol. Contribution From The Chemistry Department of Stanford University, 50, 24–26.
  • Işiklan, N., & Şanli, O. (2004). Permeation and separation characteristics of acetic acid/water mixtures through poly(vinyl alcohol-g-itaconic acid) membranes by pervaporation, evapomeation, and temperature-difference evapomeation. Journal of Applied Polymer Science, 93(5), 2322–2333. https://doi.org/10.1002/app.20710
  • Işiklan, N., & Şanli, O. (2005). Permeation and separation characteristics of acetic acid-water mixtures through poly(vinyl alcohol)/malic acid membranes by evapomeation and temperature difference controlled evapomeation. Separation Science and Technology, 40(5), 1083–1101. https://doi.org/10.1081/SS-200048179
  • Kahya, S., Solak, E. K., & Şanli, O. (2010). Sodium alginate/poly(vinyl alcohol) alloy membranes for the pervaporation, vapour permeation and vapour permeation with temperature difference separation of dimethylformamide/water mixtures: A comparative study. Vacuum, 84(9), 1092–1102. https://doi.org/10.1016/j.vacuum.2010.01.033
  • Kurşun, F. (2020). Application of PVA-b-NaY zeolite mixture membranes in pervaporation method. Journal of Molecular Structure, 1201. https://doi.org/10.1016/j.molstruc.2019.127170
  • Kwon, Y., Chaudhari, S., Kim, C., Son, D., Park, J., Moon, M., … Nam, S. (2018). Ag-exchanged NaY zeolite introduced polyvinyl alcohol/polyacrylic acid mixed matrix membrane for pervaporation separation of water/isopropanol mixture. RSC Advances, 8(37), 20669–20678. https://doi.org/10.1039/c8ra03474e
  • Park, J. Y., Jung, H. C., Raju, G. S. R., Moon, B. K., Jeong, J. H., Choi, H. Y., & Kim, J. H. (2013). Facile solvothermal synthesis and polarity based tunable morphologies of ZnO nanocrystals. Ceramics International, 39(6), 6599–6606. https://doi.org/10.1016/j.ceramint.2013.01.095
  • Petrucci, R.H., Harwood, W.S., Herring, F. G. (2010). Genel Kimya. (S. Uyar, T., Aksoy, Ed.). Ankara: Palme Yayıncılık.
  • Salehian, P., & Chung, T. S. (2017). Two-dimensional (2D) particle coating on membranes for pervaporation dehydration of isopropanol: A new approach to seal defects and enhance separation performance. Journal of Membrane Science, 544(June), 378–387. https://doi.org/10.1016/j.memsci.2017.09.038
  • Uragami, T. (2017). Pervaporation and Evapomeation with Si-Containing Polymers. In Membrane Materials for Gas and Vapor Separation (Vol. 10, pp. 335–372). John Wiley & Sons, Ltd. https://doi.org/https://doi.org/10.1002/9781119112747.ch10
  • Uragami, T. (2018). Functional Separation Membranes From Grafted Biopolymers. Biopolymer Grafting: Synthesis and Properties. Elsevier Inc. https://doi.org/10.1016/B978-0-323-48104-5.00002-0
  • Uragami, T., & Morikawa, T. (1989). Permeation of ethanol through poly(dimethylsiloxane) membranes using temperature differences in membrane permeation processes of the evapomeation method. Die Makromolekulare Chemie, Rapid Communications, 10(6), 287–291. https://doi.org/10.1002/marc.1989.030100609

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya, Ortak Disiplinler
Bölüm Research Articles
Yazarlar

Fatma KURŞUN (Sorumlu Yazar)
KIRKLARELİ ÜNİVERSİTESİ
0000-0003-0212-0973
Türkiye

Destekleyen Kurum Kırklareli University Research Foundation
Proje Numarası KLUBAP/204
Teşekkür The author thanks Kırklareli University Research Foundation for its financial support (KLUBAP/204).
Yayımlanma Tarihi 5 Eylül 2021
Yayınlandığı Sayı Yıl 2021, Cilt 8, Sayı 3

Kaynak Göster

Bibtex @araştırma makalesi { ijegeo881056, journal = {International Journal of Environment and Geoinformatics}, issn = {}, eissn = {2148-9173}, address = {}, publisher = {Cem GAZİOĞLU}, year = {2021}, volume = {8}, pages = {344 - 349}, doi = {10.30897/ijegeo.881056}, title = {The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes}, key = {cite}, author = {Kurşun, Fatma} }
APA Kurşun, F. (2021). The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes . International Journal of Environment and Geoinformatics , 8 (3) , 344-349 . DOI: 10.30897/ijegeo.881056
MLA Kurşun, F. "The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes" . International Journal of Environment and Geoinformatics 8 (2021 ): 344-349 <https://dergipark.org.tr/tr/pub/ijegeo/issue/61200/881056>
Chicago Kurşun, F. "The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes". International Journal of Environment and Geoinformatics 8 (2021 ): 344-349
RIS TY - JOUR T1 - The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes AU - Fatma Kurşun Y1 - 2021 PY - 2021 N1 - doi: 10.30897/ijegeo.881056 DO - 10.30897/ijegeo.881056 T2 - International Journal of Environment and Geoinformatics JF - Journal JO - JOR SP - 344 EP - 349 VL - 8 IS - 3 SN - -2148-9173 M3 - doi: 10.30897/ijegeo.881056 UR - https://doi.org/10.30897/ijegeo.881056 Y2 - 2021 ER -
EndNote %0 International Journal of Environment and Geoinformatics The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes %A Fatma Kurşun %T The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes %D 2021 %J International Journal of Environment and Geoinformatics %P -2148-9173 %V 8 %N 3 %R doi: 10.30897/ijegeo.881056 %U 10.30897/ijegeo.881056
ISNAD Kurşun, Fatma . "The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes". International Journal of Environment and Geoinformatics 8 / 3 (Eylül 2021): 344-349 . https://doi.org/10.30897/ijegeo.881056
AMA Kurşun F. The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes. International Journal of Environment and Geoinformatics. 2021; 8(3): 344-349.
Vancouver Kurşun F. The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes. International Journal of Environment and Geoinformatics. 2021; 8(3): 344-349.
IEEE F. Kurşun , "The Separation Characteristics of an Isopropyl Alcohol/water Azeotrope Using Evapomeation and Temperature-difference Controlling Evapomeation Methods with PVA/NaY Membranes", International Journal of Environment and Geoinformatics, c. 8, sayı. 3, ss. 344-349, Eyl. 2021, doi:10.30897/ijegeo.881056