Araştırma Makalesi
BibTex RIS Kaynak Göster

Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi

Yıl 2021, Cilt: 7 Sayı: 2, 276 - 287, 20.07.2021
https://doi.org/10.29132/ijpas.897898

Öz

Nadir toprak elementleri (NTE), sahip olduğu özellikler sayesinde yüksek teknoloji gerektiren ürünlerde ve savunma sanayiinde kullanılmakta olup, stratejik öneme sahip olmaları ile son zamanlarda gündemdedirler. Üretim ve rezerv konusunda tekel konumda olan Çin’in ihracata getirdiği sınırlamalar ile birlikte yüksek teknoloji üreten ülkeler kaynak arayışına başlamıştır. Ticari olarak birincil NTE mineralleri bastnazit, monazit ve ksenotimdir. Bu minerallere sahip olmayan ülkeler ikincil NTE minerallerinden [Eudialyte (Ödalit), loparit, piroklor, anklisit, aegirine (egrin)] üretimleri araştırmaya ve işlemeye başlamışlardır.
Bu çalışma kapsamında NTE mineralleri, dünyadaki rezerv ve üretim durumu, kullanım alanları gibi genel bilgilere değinildikten sonra, birincil ve ikincil mineral kaynaklarından konsantre elde edilmesinde uygulanan yöntemler, yapılan çalışmalar ve proses akım şemaları ile ilgili bilgiler derlenmiştir.

Destekleyen Kurum

İstanbul Teknik Üniversitesi

Kaynakça

  • Abaka-Wood, G., Addai-Mensah, J. ve Skinner, W. (2016). Review of flotation and physical separation of rare earth element minerals. 4th UMaT Biennial International Mining and Mineral Conference, pp. 55-62, Tarkwa.
  • Anderson, C. D., Taylor, P. R. ve Anderson, C. G. (2016). Rare earth flotation fundamentals: A review. IMPC 2016: XXVIII International Mineral Processing Congress Proceedings, pp. 1-15, Quebec. Canadian Institute of Mining, Metallurgy and Petroleum.
  • Balaram, V. (2019). Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact, Geoscience Frontiers, 10, 1285-1303.
  • Bulatovic, S. M. (2010). Flotation of REO Minerals. Handbook of Flotation Reagents: Chemistry, Theory and Practice, 151–173. doi:10.1016/b978-0-444-53082-0.00024-x
  • Campbell, G. A. (2014). Rare earth metals: A strategic concern. Miner Econ, 27, 21-31. doi:10.1007/s13563-014-0043-y
  • Chen, W., Honghui, H., Bai, T. ve Jiang, S. (2017). Geochemistry of monazite within carbonatite related REE deposits, Resources.
  • Costis, S., Mueller, K. K., Coudert, L., Neculita, C. M., Reynier, N. ve Blais, J.-F. (2021). Recovery potential of rare earth elements from mining and industrial residues: A review and cases studies, Journal of Geochemical Exploration.
  • Dostal, J. (2017). Rare earth element deposits of alkaline igneous rocks. Resources.
  • Dushyanthaa, N., Batapolaa, N., Ilankoonb, I., Rohithaa, S., Premasiria, R., Abeysinghea, B. ve Dissanayakea, K. (2020). The story of rare earth elements (Rees): Occurrences, global Distribution, genesis, geology, mineralogy and global production, Ore Geology Reviews, 122, 1-17.
  • Faris, N., Ram, R., Tardio, J., Bhargava, S., McMaster, S. ve Pownceby, M. I. (2017). Application of ferrous pyrometallurgy to the beneficiation of rare earth bearing iron ores – A review. Minerals Engineering, 110, 20-30.
  • Goodenough, K. M., Wall, F. ve Merriman, D. (2018). The rare earth elements: Demand, global resources, and challenges for resourcing future generations. Natural Resources Research, 27, 201-216.
  • Gupta, C. K. ve Krishnamurthy, N. (2005). Extractive metallurgy of rare earths. CRC Press.
  • Hao, C. ve Corby, A. G. (2017). Alternative flowsheet for rare earth beneficiation of bear lodge ore. Minerals Engineering, 110, 166-178. doi:10.1016/j.mineng.2017.04.016
  • Haque, N., Hughes, A., Lim, S. ve Vernon, C. (2014). Rare earth elements: Overview of mining, mineralogy, uses, sustainability and environmental impact. Resources, 614-635. doi:10.3390/resources3040614
  • Hedrick, J. B., Sinha, S. P. ve Kosynkin, V. D. (1997). Loparite, A rare-earth ore (Ce, Na, Sr, Ca)(Ti, Nb, Ta, Fe )O3, Journal of Alloys and Compounds, 250, 467–470.
  • Jordens, A., Cheng, Y. P. ve Waters, K. E. (2013). A review of the beneficiation of rare earth element bearing minerals. Minerals Engineering, 4, 97-114.
  • Jordens, A., Christopher M., Grammatikopoulos, T., Hart, B. ve Waters, K. E. (2016). Beneficiation of the nechalacho rare earth deposit: Flotation response using benzohydroxamic acid. Minerals Engineering, 99, 158-169.
  • Jyothi, R. K., Thenepalli, T., Ahn, J. W., Parhi, P. K., Chung, K. W. ve Lee, J.-Y. (2020). Review of rare earth elements recovery from secondary resources for clean energy technologies: Grand opportunities to create wealth from waste. Journal of Cleaner Production.
  • Kumari, A., Panda, R., Jha, M. K., Kumar, J. R. ve Lee, J. Y. (2015). Process development to recover rare earth metals from monazite mineral: A review. Minerals Engineering, 79, 102-115.
  • Kurşun, İ., Terzi, M. ve Özdemir, O. (2019). Determination of surface chemistry and flotation properties of rare earth mineral: Allanite. Minerals Engineering, 132, 113-120.
  • Li, L. Z. ve Yang, X. (2014). China’s rare earth ore deposits and beneficiation. ERES 2014: 1st European Rare Earth Resources Conference, pp: 26-36, Milos.
  • Liu, M., Li, H., Jiang, T. ve Liu, Q. (2019). Flotation of coarse and fine pyrochlore using octyl hydroxamic acid and sodium oleate. Minerals Engineering, 132, 191-201.
  • Lynas Rare Earth. (t.y.). Retrieved from https://lynasrareearths.com/about-us/locations/mt-weld-western-australia/
  • Mancheri, N. A. (2015). World trade in rare earths, Chinese export restrictions, and implications. Resources Policy, 46, 262-271. doi:10.1016/j.resourpol.2015.10.009
  • Moustafa, M. I. ve Abdelfattah, N. A. (2010). Physical and chemical beneficiation of the Egyptian beach monazit. Resource Geology, 60, 288–299.
  • Schüler, D., Buchert, M., Liu, R., Dittrich, S. ve Merz, C. (2011). Study on rare earths and their recycling. Darmstadt: Öko-Institut e.V.
  • Suli, L. M., Ibrahim, W. H., Aziz, B. A., Deraman, M. R. ve Ismail, N. A. (2017). A review of rare earth mineral processing technology, Chemical Engineering Research Bulletin, 19, 20-35. Erişim adresi: https://doi.org/10.3329/cerb.v19i0.33773
  • Terzi, M. (2017). Isparta Yöresi nadir toprak elementlerinin kazanımı için yeni proseslerin geliştirilmesi (Doktora Tezi). Yöktez Erişim No: 483710, İstanbul: İstanbul Üniversitesi.
  • U.S. Geological Survey, 2021. Mineral Commodity Summaries 2021. U.S. Geological Survey, Reston, Virginia. Vaccarezza, V. ve Anderson, C. (2018). Beneficiation and leaching study of Norra Kärr ödalit mineral. In H. K. al., Rare Metal Technology, The Minerals, Metals & Materials Society.
  • Wall, F. (2014). 13. Rare earth elements. Gunn,G. (Der). Critical metals handbook, pp. 312-340.
  • Yang, X., Satur, J. V., Sanematsu, K., Laukkanen, J. ve Saastamoinen, T. (2015). Beneficiation studies of a complex REE ore. Minerals Engineering, 71, 55-64.
  • Yıldız, N. (2016). Nadir toprak elementleri. Ankara.
  • Zhang, Y. (2016). Froth flotation of xenotime. (YL Tezi). Colorado School of Mines, Arthur Lakes Library. Erişim adresi: http://hdl.handle.net/11124/170057
  • Zhang, W., Noble, A., Yang, X. ve Honaker, R. (2020). A comprehensive review of rare earth elements recovery from coal-related materials. Minerals. doi:10.3390/min10050451

The Investigation of Concentration Processes of Rare Earth Elements from Primary and Secondary Mineral Resources by Physical and Physico-chemical Methods

Yıl 2021, Cilt: 7 Sayı: 2, 276 - 287, 20.07.2021
https://doi.org/10.29132/ijpas.897898

Öz

Rare earth elements (REE) are used in products requiring high technology and the defense industry and they have recently been on the agenda with their strategic importance. With the restrictions imposed on exports by China, which has a monopoly in terms of production and reserve, other countries producing high technology have started to search for new REE resources. Primary commercial REE minerals are bastnasite, monazite, and xenotime. Countries that do not have these mineral resources have begun to search for new sources and new processes using secondary REE minerals such as eudialyte, loparite, pyrochlore, anklicite and aegirine.
Within the scope of this study, after giving general information such as REE minerals, reserves and production status in the world, and their usage areas, information about the concentration methods from primary and secondary mineral resources, case studies, and process flow charts are compiled.

Kaynakça

  • Abaka-Wood, G., Addai-Mensah, J. ve Skinner, W. (2016). Review of flotation and physical separation of rare earth element minerals. 4th UMaT Biennial International Mining and Mineral Conference, pp. 55-62, Tarkwa.
  • Anderson, C. D., Taylor, P. R. ve Anderson, C. G. (2016). Rare earth flotation fundamentals: A review. IMPC 2016: XXVIII International Mineral Processing Congress Proceedings, pp. 1-15, Quebec. Canadian Institute of Mining, Metallurgy and Petroleum.
  • Balaram, V. (2019). Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact, Geoscience Frontiers, 10, 1285-1303.
  • Bulatovic, S. M. (2010). Flotation of REO Minerals. Handbook of Flotation Reagents: Chemistry, Theory and Practice, 151–173. doi:10.1016/b978-0-444-53082-0.00024-x
  • Campbell, G. A. (2014). Rare earth metals: A strategic concern. Miner Econ, 27, 21-31. doi:10.1007/s13563-014-0043-y
  • Chen, W., Honghui, H., Bai, T. ve Jiang, S. (2017). Geochemistry of monazite within carbonatite related REE deposits, Resources.
  • Costis, S., Mueller, K. K., Coudert, L., Neculita, C. M., Reynier, N. ve Blais, J.-F. (2021). Recovery potential of rare earth elements from mining and industrial residues: A review and cases studies, Journal of Geochemical Exploration.
  • Dostal, J. (2017). Rare earth element deposits of alkaline igneous rocks. Resources.
  • Dushyanthaa, N., Batapolaa, N., Ilankoonb, I., Rohithaa, S., Premasiria, R., Abeysinghea, B. ve Dissanayakea, K. (2020). The story of rare earth elements (Rees): Occurrences, global Distribution, genesis, geology, mineralogy and global production, Ore Geology Reviews, 122, 1-17.
  • Faris, N., Ram, R., Tardio, J., Bhargava, S., McMaster, S. ve Pownceby, M. I. (2017). Application of ferrous pyrometallurgy to the beneficiation of rare earth bearing iron ores – A review. Minerals Engineering, 110, 20-30.
  • Goodenough, K. M., Wall, F. ve Merriman, D. (2018). The rare earth elements: Demand, global resources, and challenges for resourcing future generations. Natural Resources Research, 27, 201-216.
  • Gupta, C. K. ve Krishnamurthy, N. (2005). Extractive metallurgy of rare earths. CRC Press.
  • Hao, C. ve Corby, A. G. (2017). Alternative flowsheet for rare earth beneficiation of bear lodge ore. Minerals Engineering, 110, 166-178. doi:10.1016/j.mineng.2017.04.016
  • Haque, N., Hughes, A., Lim, S. ve Vernon, C. (2014). Rare earth elements: Overview of mining, mineralogy, uses, sustainability and environmental impact. Resources, 614-635. doi:10.3390/resources3040614
  • Hedrick, J. B., Sinha, S. P. ve Kosynkin, V. D. (1997). Loparite, A rare-earth ore (Ce, Na, Sr, Ca)(Ti, Nb, Ta, Fe )O3, Journal of Alloys and Compounds, 250, 467–470.
  • Jordens, A., Cheng, Y. P. ve Waters, K. E. (2013). A review of the beneficiation of rare earth element bearing minerals. Minerals Engineering, 4, 97-114.
  • Jordens, A., Christopher M., Grammatikopoulos, T., Hart, B. ve Waters, K. E. (2016). Beneficiation of the nechalacho rare earth deposit: Flotation response using benzohydroxamic acid. Minerals Engineering, 99, 158-169.
  • Jyothi, R. K., Thenepalli, T., Ahn, J. W., Parhi, P. K., Chung, K. W. ve Lee, J.-Y. (2020). Review of rare earth elements recovery from secondary resources for clean energy technologies: Grand opportunities to create wealth from waste. Journal of Cleaner Production.
  • Kumari, A., Panda, R., Jha, M. K., Kumar, J. R. ve Lee, J. Y. (2015). Process development to recover rare earth metals from monazite mineral: A review. Minerals Engineering, 79, 102-115.
  • Kurşun, İ., Terzi, M. ve Özdemir, O. (2019). Determination of surface chemistry and flotation properties of rare earth mineral: Allanite. Minerals Engineering, 132, 113-120.
  • Li, L. Z. ve Yang, X. (2014). China’s rare earth ore deposits and beneficiation. ERES 2014: 1st European Rare Earth Resources Conference, pp: 26-36, Milos.
  • Liu, M., Li, H., Jiang, T. ve Liu, Q. (2019). Flotation of coarse and fine pyrochlore using octyl hydroxamic acid and sodium oleate. Minerals Engineering, 132, 191-201.
  • Lynas Rare Earth. (t.y.). Retrieved from https://lynasrareearths.com/about-us/locations/mt-weld-western-australia/
  • Mancheri, N. A. (2015). World trade in rare earths, Chinese export restrictions, and implications. Resources Policy, 46, 262-271. doi:10.1016/j.resourpol.2015.10.009
  • Moustafa, M. I. ve Abdelfattah, N. A. (2010). Physical and chemical beneficiation of the Egyptian beach monazit. Resource Geology, 60, 288–299.
  • Schüler, D., Buchert, M., Liu, R., Dittrich, S. ve Merz, C. (2011). Study on rare earths and their recycling. Darmstadt: Öko-Institut e.V.
  • Suli, L. M., Ibrahim, W. H., Aziz, B. A., Deraman, M. R. ve Ismail, N. A. (2017). A review of rare earth mineral processing technology, Chemical Engineering Research Bulletin, 19, 20-35. Erişim adresi: https://doi.org/10.3329/cerb.v19i0.33773
  • Terzi, M. (2017). Isparta Yöresi nadir toprak elementlerinin kazanımı için yeni proseslerin geliştirilmesi (Doktora Tezi). Yöktez Erişim No: 483710, İstanbul: İstanbul Üniversitesi.
  • U.S. Geological Survey, 2021. Mineral Commodity Summaries 2021. U.S. Geological Survey, Reston, Virginia. Vaccarezza, V. ve Anderson, C. (2018). Beneficiation and leaching study of Norra Kärr ödalit mineral. In H. K. al., Rare Metal Technology, The Minerals, Metals & Materials Society.
  • Wall, F. (2014). 13. Rare earth elements. Gunn,G. (Der). Critical metals handbook, pp. 312-340.
  • Yang, X., Satur, J. V., Sanematsu, K., Laukkanen, J. ve Saastamoinen, T. (2015). Beneficiation studies of a complex REE ore. Minerals Engineering, 71, 55-64.
  • Yıldız, N. (2016). Nadir toprak elementleri. Ankara.
  • Zhang, Y. (2016). Froth flotation of xenotime. (YL Tezi). Colorado School of Mines, Arthur Lakes Library. Erişim adresi: http://hdl.handle.net/11124/170057
  • Zhang, W., Noble, A., Yang, X. ve Honaker, R. (2020). A comprehensive review of rare earth elements recovery from coal-related materials. Minerals. doi:10.3390/min10050451
Toplam 34 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Esra Baştürkcü 0000-0003-0894-2185

Ceyda Şavran 0000-0003-3199-8945

Servet Timur 0000-0002-9795-9941

A.ekrem Yüce 0000-0001-9789-0377

Yayımlanma Tarihi 20 Temmuz 2021
Gönderilme Tarihi 22 Mart 2021
Kabul Tarihi 3 Haziran 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 7 Sayı: 2

Kaynak Göster

APA Baştürkcü, E., Şavran, C., Timur, S., Yüce, A. (2021). Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi. International Journal of Pure and Applied Sciences, 7(2), 276-287. https://doi.org/10.29132/ijpas.897898
AMA Baştürkcü E, Şavran C, Timur S, Yüce A. Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi. International Journal of Pure and Applied Sciences. Temmuz 2021;7(2):276-287. doi:10.29132/ijpas.897898
Chicago Baştürkcü, Esra, Ceyda Şavran, Servet Timur, ve A.ekrem Yüce. “Birincil Ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel Ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi”. International Journal of Pure and Applied Sciences 7, sy. 2 (Temmuz 2021): 276-87. https://doi.org/10.29132/ijpas.897898.
EndNote Baştürkcü E, Şavran C, Timur S, Yüce A (01 Temmuz 2021) Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi. International Journal of Pure and Applied Sciences 7 2 276–287.
IEEE E. Baştürkcü, C. Şavran, S. Timur, ve A. Yüce, “Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi”, International Journal of Pure and Applied Sciences, c. 7, sy. 2, ss. 276–287, 2021, doi: 10.29132/ijpas.897898.
ISNAD Baştürkcü, Esra vd. “Birincil Ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel Ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi”. International Journal of Pure and Applied Sciences 7/2 (Temmuz 2021), 276-287. https://doi.org/10.29132/ijpas.897898.
JAMA Baştürkcü E, Şavran C, Timur S, Yüce A. Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi. International Journal of Pure and Applied Sciences. 2021;7:276–287.
MLA Baştürkcü, Esra vd. “Birincil Ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel Ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi”. International Journal of Pure and Applied Sciences, c. 7, sy. 2, 2021, ss. 276-87, doi:10.29132/ijpas.897898.
Vancouver Baştürkcü E, Şavran C, Timur S, Yüce A. Birincil ve İkincil Mineral Kaynaklarından Nadir Toprak Elementlerinin Fiziksel ve Fizikokimyasal Yöntemlerle Üretim Proseslerinin İncelenmesi. International Journal of Pure and Applied Sciences. 2021;7(2):276-87.

154501544915448154471544615445