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Alçak yoğunluklu polietilenin, ceviz ve fındık kabuğu tozu takviyeleri ile eriyik akış değerlerindeki değişimin incelenmesi

Year 2025, Volume: 1 Issue: 1, 35 - 38, 28.05.2025

Abstract

Bu çalışmada, öğütülmüş ceviz ve fındık kabuğu tozu takviyelerinin poliolefinler grubuna ait alçak yoğunluklu polietilenin (LDPE) eriyik akış değerleri üzerine etkileri incelenmiştir. Öncelikle boyutları 75 ile 150 mikron arasında değişen ceviz ve fındık kabuğu tozları LDPE ile mekanik olarak ayrı ayrı ağırlıkça %5, %10 ve %15 oranlarında karıştırılmış ve eriyik akış analizleri gerçekleştirilmiştir. Yapılan deneyler sonucu kütlesel ve hacimsel eriyik akış değerleri belirlenerek elde edilen sonuçlar grafiklerle açıklanmıştır. Sonuçlar, dolgu oranı arttıkça MFI ve MVR değerlerinde genel bir azalma meydana geldiğini göstermiştir. Özellikle %15 fındık kabuğu tozu ilavesi, saf LDPE’ye kıyasla MVR değerinde %35'e varan bir düşüşe neden olmuştur. Ceviz kabuğu tozunda ise bu düşüş daha sınırlı kalmıştır.

References

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Investigation of changes in melt flow index of low density polyethylene with walnut and hazelnut shell powder additives

Year 2025, Volume: 1 Issue: 1, 35 - 38, 28.05.2025

Abstract

In this study, the effects of walnut and hazelnut shell powder reinforcements on the melt flow values of low density polyethylene (LDPE) belonging to the polyolefins group were investigated. First, walnut and hazelnut shell powders with sizes ranging from 75 to 150 microns were mechanically mixed with LDPE separately at 5%, 10% and 15% by weight and melt flow analyses were performed. As a result of the experiments, mass and volumetric melt flow values were determined and the results obtained were explained with graphics. The results showed that there was a general decrease in MFI and MVR values as the filler content increased. In particular, the addition of 15% hazelnut shell powder caused a decrease of up to 35% in the MVR value compared to pure LDPE. This decrease was more limited for walnut shell powder.

References

  • [1] Karagöz İ, Mutlu D, Çavuşoğlu A, Çelebi M, Ceylan Ö. A comprehensive study on the effect of small rates of walnut shell and talc fillers on the thermal,mechanical, and morphological properties of epoxy hybrid composites. Biomass Conv Bioref 2025;15:8439–50. https://doi.org/10.1007/s13399-024-05660-9.
  • [2] Karagöz İ, Tamer İM, Çavuşoğlu A, Sepetcioglu H. Investigation of mechanical, thermal, and morphological properties of walnut shell and nano clay reinforced HDPE composites. Materials Today Communications 2024;41:110905. https://doi.org/10.1016/j.mtcomm.2024.110905.
  • [3] Carvalho MS de, Azevedo JB, Barbosa JDV. Effect of the melt flow index of an HDPE matrix on the properties of composites with wood particles. Polymer Testing 2020;90:106678. https://doi.org/10.1016/j.polymertesting.2020.106678.
  • [4] Kuram E. Advances in development of green composites based on natural fibers: a review. Emergent Mater 2022;5:811–31. https://doi.org/10.1007/s42247-021-00279-2.
  • [5] Pradhan P, Nanda BP, Satapathy A. Polyester composites filled with walnut shell powder: Preparation and thermal characterization. Polymer Composites 2020;41:3294–308. https://doi.org/10.1002/pc.25620.
  • [6] Güler C, Sarikaya A, Sertkaya AA, Canli E. Almond shell particle containing particleboard mechanical and physical properties. Construction and Building Materials 2024;431:136565. https://doi.org/10.1016/j.conbuildmat.2024.136565.
  • [7] Çelik YH, Yalcin R, Topkaya T, Başaran E, Kilickap E. Characterization of Hazelnut, Pistachio, and Apricot Kernel Shell Particles and Analysis of Their Composite Properties. Journal of Natural Fibers 2021;18:1054–68. https://doi.org/10.1080/15440478.2020.1739593.
  • [8] El khayat driaa Y, Maarir H, Mennani M, Grimi N, Moubarik A, Boussetta N. Ultrasound, pulsed electric fields, and high-voltage electrical discharges assisted extraction of cellulose and lignin from walnut shells. International Journal of Biological Macromolecules 2025;292:139319. https://doi.org/10.1016/j.ijbiomac.2024.139319.
  • [9] Martínez-Toledo C, Valdes-Vidal G, Calabi-Floody A, González ME, Ruiz A, Mignolet-Garrido C, et al. Optimising slow pyrolysis parameters to enhance biochar European hazelnut shell as a biobased asphalt modifier. Materials Today Sustainability 2025;30:101087. https://doi.org/10.1016/j.mtsust.2025.101087.
  • [10] Li Z, Abdurashid A, Jamal R, Abdiryim T, You J, Shang J, et al. The microstructure and mechanical properties of eggshell powder and glass fiber reinforced recycled polyethylene/high-density polyethylene as non-structural building composites. Construction and Building Materials 2025;477:141349. https://doi.org/10.1016/j.conbuildmat.2025.141349.
  • [11] Elghnam SM, Abdelalim YH, Hamad MA. Influence of weathering exposure on UV light absorption in low density polyethylene LDPE grad-LA071. Journal of Materials Research and Technology 2022;19:1493–6. https://doi.org/10.1016/j.jmrt.2022.05.096.
  • [12] Faruk O, Bledzki AK, Fink H-P, Sain M. Biocomposites reinforced with natural fibers: 2000–2010. Progress in Polymer Science 2012;37:1552–96. https://doi.org/10.1016/j.progpolymsci.2012.04.003.
  • [13] Li X, Tabil LG, Panigrahi S. Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review. J Polym Environ 2007;15:25–33. https://doi.org/10.1007/s10924-006-0042-3.
  • [14] Balasuriya PW, Ye L, Mai Y-W. Mechanical properties of wood flake–polyethylene composites. Part I: effects of processing methods and matrix melt flow behaviour. Composites Part A: Applied Science and Manufacturing 2001;32:619–29. https://doi.org/10.1016/S1359-835X(00)00160-3.
  • [15] Sarabi MT, Behravesh AH, Shahi P, Daryabari Y. Effect of polymeric matrix melt flow index in reprocessing extruded wood–plastic composites. Journal of Thermoplastic Composite Materials 2014;27:881–94. https://doi.org/10.1177/0892705712458445.
There are 15 citations in total.

Details

Primary Language English
Subjects Solid Mechanics, Material Design and Behaviors
Journal Section Research Article
Authors

Çağdaş Güneş 0000-0002-4040-5614

Akar Doğan 0000-0002-6788-1629

Yılmaz Kısmet 0000-0003-3145-6214

Publication Date May 28, 2025
Submission Date April 29, 2025
Acceptance Date May 23, 2025
Published in Issue Year 2025 Volume: 1 Issue: 1

Cite

IEEE Ç. Güneş, A. Doğan, and Y. Kısmet, “Investigation of changes in melt flow index of low density polyethylene with walnut and hazelnut shell powder additives”, JDEU, vol. 1, no. 1, pp. 35–38, 2025.