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Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism

Year 2024, Volume: 19 Issue: 3, 151 - 159

Abstract

Turkish coffee waste (TCW), an organic by-product, was employed for the adsorption-based removal of Reactive Red 195 (RR195) dye from aqueous solutions. The study explored various parameters including pH (ranging from 3 to 9), initial RR195 concentration (5-500 mg/L), contact time (1-360 minutes), and adsorbent dosage (0.5-20 g/L). In a batch system, these experiments achieved a significant removal efficiency of 89% under optimal conditions. The pseudo-second-order (PSO) kinetic model provided the most accurate representation of the kinetics of RR195 removal by TCW. Additionally, the adsorption equilibrium data aligned well with the Freundlich isotherm model. The maximum adsorption capacity of TCW for RR195 was found to be 63.5 mg/g. These findings confirm that TCW can effectively remove RR195 through adsorption without requiring any pre-treatment.

References

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  • Ahuja S., et al. (2018) Biosorption of Reactive Red 195 using Saccharomyces cerevisiae: Optimization and kinetic studies. Journal of Environmental Chemical Engineering, 6(3), 3561-3568.
  • Aguilar DLG, Rodríguez Miranda JP, Miller MXA, Astudillo RIM, Muñoz JAE, (2020) Removal of Zn(II) in synthetic wastewater using agricultural wastes. Metals, 10, 1465. https://doi.org/10.3390/met10111465
  • Bhatnagar A, Hogland W, Marques M, Sillanpää M, (2013) An overview of the modification methods of activated carbon for its water treatment applications. Chem. Engin. J., 219, 499-511. https://doi.org/10.1016/j.cej.2012.12.038
  • Dolatabadi M, Mehrabpour M, Esfandyari M, Alidadi H, Davoudi M, (2018) Modeling of simultaneous adsorp- tion of dye and metal ion by sawdust from aqueous solution using of ANN and ANFIS. Cemometrics and Intelligent Laboratory Systems, 181, 72–78. https://doi.org/10. 1016/j.chemolab.2018.07.012
  • El-Shafie M, (2023) A comprehensive assessment of ammonia synthesis reaction kinetics and rate equations. Int. J. Hyd. Energy, 48, 35938-35952. https://doi.org/10.1016/j.ijhydene.2023.06.011
  • Freundlich HM, (1906) Over the Adsorption in Solution. J. Physical Chem. A, 57, 385-470.
  • Güneş K, (2023) Isotherm and kinetic modeling of the adsorption of methylene blue, a cationic dye, on pumice. Int. J. Chem. & Tech., 7(1), 67- 74.
  • Ho YS, McKay G, (1999) Pseudo-second order model for sorption processes, Process Biochemistry, 34, 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5
  • Ho JHN, Kallstrom G, Johnson AW, (2000) Nmd3p is a Crm1p-dependent adapter protein for nuclear export of the large ribosomal subunit. J. Cell Bio., 151(5), 1057-1066. https://doi.org/10.1083/jcb.151.5.1057
  • Igwegbe CA, Mohmmadi L, Ahmadi S, Rahdar A, Khadkhodaiy D, Dehghani R, Rahdar S, (2019). Modeling of adsorption of methylene blue dye on Ho-CaWO4 nanoparticles using response surface methodology (RSM) and artificial neural network (ANN) techniques. MethodsX, 6, 1779–1797.
  • Inyinbor AA, Adekola FA, Olatunji GA, (2016) Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp, Water Resources & Industry, 15, 14-27. https://doi.org/10.1016/j.wri.2016.06.001.
  • Katheresan V, Kansedo J, Lau SY, (2018) Efficiency of various recent wastewater dye removal methods: A review. J. Environ. Chem. Engin., 6(4), 4676-4697. https://doi.org/10.1016/j.jece.2018.06.060
  • Kumar, A., et al. (2019) Integration of advanced oxidation processes with biological tr eatments: An emerging strategy for wastewater treatment. Science of the Total Environment, 696, 133989.
  • Lagergren S, (1898) About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1-39.
  • Langmuir I, (1918) The Adsorptıon of Gases on Plane Surfaces of Glass, Mica and Platinum. J. Am. Chem. Soc., 40(9), 1361–1403.
  • Laskar II, Hashisho Z, (2020) Insights into modeling adsorption equilibria of single and multicomponent systems of organic and water vapors. Separ. & Purif. Tech., 241, 116681. https://doi.org/10.1016/j.seppur.2020.116681
  • Litefti K, Freire MS, Stitou M, González-Álvarez J, (2019) Adsorption of an anionic dye (Congo red) from aqueous solutions by pine bark. Sci.Reports, 9, 16530. https://doi.org/10.1038/s41598-019-53046-z
  • Mahanna H, Samy M, (2020) Adsorption of Reactive Red 195 dye from industrial wastewater by dried soybean leaves modified with acetic acid, Desal. & Water Treat. 178, 312–321.
  • Munagapati VS, Yarramuthi V, Kim Y, Lee KM, Kim DS, (2018) Removal of anionic dyes (reactive black 5 and congo red) from aqueous solutions using banana peel powder as an adsorbent. Ecotox. & Environ. Safety, 148, 601–607.
  • Munagapati VS, Wen HY, Wen JC, Gollakota ARK, Shu CM, Lin KYA, Wen JH, (2021). Adsorption of Reactive Red 195 from aqueous medium using Lotus (Nelumbo nucifera) leaf powder chemically modified with dimethylamine: characterization, isotherms, kinetics, thermodynamics, and mechanism assessment. Int. J. Phytorem., 24(2), 131–144. https://doi.org/10.1080/15226514.2021.1929060
  • Rafatullah M, Sulaiman O, Hashim R, Ahmad A, (2010) Adsorption of methylene blue on low-cost adsorbents: A review. J. Hazard. Mat., 177, 1-3, 70-80. https://doi.org/10.1016/j.jhazmat.2009.12.047
  • Saratale RG, Saratale GD, Chang JS, Govindwar SP, (2019a) Bacterial decolorization and degradation of azo dyes: A review. J. Taiwan Inst. Chem. Engin. 42(1), 138-157. https://doi.org/10.1016/j.jtice.2010.06.006
  • Sirés I, Brillas E, (2012) Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: a review. Environ. Int., 40, 212-229.
  • Thi TTL, Ta HS, Van KL, (2021) Activated carbons from coffee husk: Preparation, characterization, and reactive red 195 adsorption. J. Chem. Res., 45(5-6), 380-394. https://doi.org/10.1177/1747519820970469
  • Verma AK, Dash RR, Bhunia P, (2021) A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J. Environ. Manag., 93(1), 154-168. https://doi.org/10.1016/j.jenvman.2011.09.012
  • Wong S, Ghafar NA, Ngadi N (2020) Effective removal of anionic textile dyes using adsorbent synthesized from coffee waste. Scientific Reports, 10, 2928.
  • Yan X, Wang J, Li X, (2018) Influence of pH on adsorption behavior in aqueous solutions. J. Environ. Chem., 45(2), 123-131.
  • Zahir A, Mahmood U, Aslam Z, Naseem S, Obayomi, KS, Kumar P, Saptoro A, Lau SY, Tiong ANT, Abid S, (2024) Growth of novel cinnamon-bentonite loaded chitosan nanospikes for the confiscation of congo red: adsorption studies and ANN modeling. J. Poly. & Environ., 32, 1764–1783. https://doi.org/10.1007/s10924-023-03071-x
  • Zhang EL, Sun XJ, Liu XT, Wang QD, (2015) Morphology controlled synthesis of α-FeOOH crystals and their shape-dependent adsorption for decontamination of congo red dye. Mat. Res. Innov., 19, 385–391. https://doi.org/10.1179/1433075X15Y.0000000019
  • Zhu Y, Liu H, Tang J, (2020) The role of pHpzc in adsorption mechanisms for heterogeneous adsorbents. Chem. Engin. J., 375, 121974.
  • Zuorro A, Lavecchia R, (2020) Coffee grounds as an alternative biosorbent for the removal of heavy metals from aqueous solutions: A review. Sustainability, 12(6), 2406. https://doi.org/10.3390/su12062406
Year 2024, Volume: 19 Issue: 3, 151 - 159

Abstract

References

  • Alhares HS, Shaban MAA, Salman MS, M-Ridha MJ, Mohammed SJ, Abed KM, Inrahim MA, Al-Banaa AK, Hasan HA, (2023) Sunflower Husks Coated with Copper Oxide Nanoparticles for Reactive Blue 49 and Reactive Red 195 Removals: Adsorption Mechanisms, Thermodynamic, Kinetic, and Isotherm Studies. Water Air Soil Poll., 234, 35. https://doi.org/10.1007/s11270-022-06033-6
  • Ahuja S., et al. (2018) Biosorption of Reactive Red 195 using Saccharomyces cerevisiae: Optimization and kinetic studies. Journal of Environmental Chemical Engineering, 6(3), 3561-3568.
  • Aguilar DLG, Rodríguez Miranda JP, Miller MXA, Astudillo RIM, Muñoz JAE, (2020) Removal of Zn(II) in synthetic wastewater using agricultural wastes. Metals, 10, 1465. https://doi.org/10.3390/met10111465
  • Bhatnagar A, Hogland W, Marques M, Sillanpää M, (2013) An overview of the modification methods of activated carbon for its water treatment applications. Chem. Engin. J., 219, 499-511. https://doi.org/10.1016/j.cej.2012.12.038
  • Dolatabadi M, Mehrabpour M, Esfandyari M, Alidadi H, Davoudi M, (2018) Modeling of simultaneous adsorp- tion of dye and metal ion by sawdust from aqueous solution using of ANN and ANFIS. Cemometrics and Intelligent Laboratory Systems, 181, 72–78. https://doi.org/10. 1016/j.chemolab.2018.07.012
  • El-Shafie M, (2023) A comprehensive assessment of ammonia synthesis reaction kinetics and rate equations. Int. J. Hyd. Energy, 48, 35938-35952. https://doi.org/10.1016/j.ijhydene.2023.06.011
  • Freundlich HM, (1906) Over the Adsorption in Solution. J. Physical Chem. A, 57, 385-470.
  • Güneş K, (2023) Isotherm and kinetic modeling of the adsorption of methylene blue, a cationic dye, on pumice. Int. J. Chem. & Tech., 7(1), 67- 74.
  • Ho YS, McKay G, (1999) Pseudo-second order model for sorption processes, Process Biochemistry, 34, 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5
  • Ho JHN, Kallstrom G, Johnson AW, (2000) Nmd3p is a Crm1p-dependent adapter protein for nuclear export of the large ribosomal subunit. J. Cell Bio., 151(5), 1057-1066. https://doi.org/10.1083/jcb.151.5.1057
  • Igwegbe CA, Mohmmadi L, Ahmadi S, Rahdar A, Khadkhodaiy D, Dehghani R, Rahdar S, (2019). Modeling of adsorption of methylene blue dye on Ho-CaWO4 nanoparticles using response surface methodology (RSM) and artificial neural network (ANN) techniques. MethodsX, 6, 1779–1797.
  • Inyinbor AA, Adekola FA, Olatunji GA, (2016) Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp, Water Resources & Industry, 15, 14-27. https://doi.org/10.1016/j.wri.2016.06.001.
  • Katheresan V, Kansedo J, Lau SY, (2018) Efficiency of various recent wastewater dye removal methods: A review. J. Environ. Chem. Engin., 6(4), 4676-4697. https://doi.org/10.1016/j.jece.2018.06.060
  • Kumar, A., et al. (2019) Integration of advanced oxidation processes with biological tr eatments: An emerging strategy for wastewater treatment. Science of the Total Environment, 696, 133989.
  • Lagergren S, (1898) About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1-39.
  • Langmuir I, (1918) The Adsorptıon of Gases on Plane Surfaces of Glass, Mica and Platinum. J. Am. Chem. Soc., 40(9), 1361–1403.
  • Laskar II, Hashisho Z, (2020) Insights into modeling adsorption equilibria of single and multicomponent systems of organic and water vapors. Separ. & Purif. Tech., 241, 116681. https://doi.org/10.1016/j.seppur.2020.116681
  • Litefti K, Freire MS, Stitou M, González-Álvarez J, (2019) Adsorption of an anionic dye (Congo red) from aqueous solutions by pine bark. Sci.Reports, 9, 16530. https://doi.org/10.1038/s41598-019-53046-z
  • Mahanna H, Samy M, (2020) Adsorption of Reactive Red 195 dye from industrial wastewater by dried soybean leaves modified with acetic acid, Desal. & Water Treat. 178, 312–321.
  • Munagapati VS, Yarramuthi V, Kim Y, Lee KM, Kim DS, (2018) Removal of anionic dyes (reactive black 5 and congo red) from aqueous solutions using banana peel powder as an adsorbent. Ecotox. & Environ. Safety, 148, 601–607.
  • Munagapati VS, Wen HY, Wen JC, Gollakota ARK, Shu CM, Lin KYA, Wen JH, (2021). Adsorption of Reactive Red 195 from aqueous medium using Lotus (Nelumbo nucifera) leaf powder chemically modified with dimethylamine: characterization, isotherms, kinetics, thermodynamics, and mechanism assessment. Int. J. Phytorem., 24(2), 131–144. https://doi.org/10.1080/15226514.2021.1929060
  • Rafatullah M, Sulaiman O, Hashim R, Ahmad A, (2010) Adsorption of methylene blue on low-cost adsorbents: A review. J. Hazard. Mat., 177, 1-3, 70-80. https://doi.org/10.1016/j.jhazmat.2009.12.047
  • Saratale RG, Saratale GD, Chang JS, Govindwar SP, (2019a) Bacterial decolorization and degradation of azo dyes: A review. J. Taiwan Inst. Chem. Engin. 42(1), 138-157. https://doi.org/10.1016/j.jtice.2010.06.006
  • Sirés I, Brillas E, (2012) Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: a review. Environ. Int., 40, 212-229.
  • Thi TTL, Ta HS, Van KL, (2021) Activated carbons from coffee husk: Preparation, characterization, and reactive red 195 adsorption. J. Chem. Res., 45(5-6), 380-394. https://doi.org/10.1177/1747519820970469
  • Verma AK, Dash RR, Bhunia P, (2021) A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J. Environ. Manag., 93(1), 154-168. https://doi.org/10.1016/j.jenvman.2011.09.012
  • Wong S, Ghafar NA, Ngadi N (2020) Effective removal of anionic textile dyes using adsorbent synthesized from coffee waste. Scientific Reports, 10, 2928.
  • Yan X, Wang J, Li X, (2018) Influence of pH on adsorption behavior in aqueous solutions. J. Environ. Chem., 45(2), 123-131.
  • Zahir A, Mahmood U, Aslam Z, Naseem S, Obayomi, KS, Kumar P, Saptoro A, Lau SY, Tiong ANT, Abid S, (2024) Growth of novel cinnamon-bentonite loaded chitosan nanospikes for the confiscation of congo red: adsorption studies and ANN modeling. J. Poly. & Environ., 32, 1764–1783. https://doi.org/10.1007/s10924-023-03071-x
  • Zhang EL, Sun XJ, Liu XT, Wang QD, (2015) Morphology controlled synthesis of α-FeOOH crystals and their shape-dependent adsorption for decontamination of congo red dye. Mat. Res. Innov., 19, 385–391. https://doi.org/10.1179/1433075X15Y.0000000019
  • Zhu Y, Liu H, Tang J, (2020) The role of pHpzc in adsorption mechanisms for heterogeneous adsorbents. Chem. Engin. J., 375, 121974.
  • Zuorro A, Lavecchia R, (2020) Coffee grounds as an alternative biosorbent for the removal of heavy metals from aqueous solutions: A review. Sustainability, 12(6), 2406. https://doi.org/10.3390/su12062406
There are 32 citations in total.

Details

Primary Language English
Subjects Environmental Assessment and Monitoring
Journal Section Articles
Authors

Özgül Çimen Mesutoğlu 0000-0002-6704-8645

Publication Date
Submission Date September 14, 2024
Acceptance Date September 30, 2024
Published in Issue Year 2024 Volume: 19 Issue: 3

Cite

APA Çimen Mesutoğlu, Ö. (n.d.). Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism. Journal of International Environmental Application and Science, 19(3), 151-159.
AMA Çimen Mesutoğlu Ö. Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism. J. Int. Environmental Application & Science. 19(3):151-159.
Chicago Çimen Mesutoğlu, Özgül. “Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism”. Journal of International Environmental Application and Science 19, no. 3 n.d.: 151-59.
EndNote Çimen Mesutoğlu Ö Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism. Journal of International Environmental Application and Science 19 3 151–159.
IEEE Ö. Çimen Mesutoğlu, “Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism”, J. Int. Environmental Application & Science, vol. 19, no. 3, pp. 151–159.
ISNAD Çimen Mesutoğlu, Özgül. “Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism”. Journal of International Environmental Application and Science 19/3 (n.d.), 151-159.
JAMA Çimen Mesutoğlu Ö. Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism. J. Int. Environmental Application & Science.;19:151–159.
MLA Çimen Mesutoğlu, Özgül. “Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism”. Journal of International Environmental Application and Science, vol. 19, no. 3, pp. 151-9.
Vancouver Çimen Mesutoğlu Ö. Adsorption of Anionic Dyes Using Turkish Coffee Waste: Efficiency and Mechanism. J. Int. Environmental Application & Science. 19(3):151-9.

“Journal of International Environmental Application and Science”