The effect of surface modification with ozone in waterless (ScCO2) dyeing o polyester

Öz

In this study, ozonation was carried out prior to dyeing 100% polyester fabrics through spray application (without the use of water) at various durations and with different gas flow rates. The ozonated fabrics were dyed with Dianix Dry XF2 Rubine (disperse dye) in conventional and supercritical carbon dioxide (scCO2) medium. The main objective of the study is to investigate the colour efficiency of the ozone modified polyester fabric in waterless dyeing. Hydrophilicity, colour measurement, tensile strength, fastness tests, SEM analyses were performed on the samples. The results of dyeing the samples in a waterless medium after ozonation revealed higher colour strength (K/S) and better fastness test results with breaking strength values than conventionally dyed fabrics.

Anahtar Kelimeler

• Polyester
• Ozone
• Supercritical Carbondioxide
• Surface Modification
• Dyeing

Poliesterin susuz (Scco2) ortamda boyanmasında ozon ile yüzey modifikasyonunun etkisi

Öz

Bu çalışmada %100 poliester kumaşlar boyanmadan önce farklı zamanlarda ve farklı gaz debilerinde püskürtme (susuz) yapılarak ozonlama işlemi yapılmıştır. Ozonlanmış kumaşlar, geleneksel ve süperkritik karbon dioksit (scCO2) ortamında Dianix Dry XF2 Rubine ile boyanmıştır. Çalışmanın temel amacı, ozon gazı yüzeyi modifiye edilmiş polyester kumaşın susuz boyamada renk etkinliğinin araştırılmasıdır. Numuneler üzerinde hidrofilite, renk ölçümü, çekme mukavemeti, haslık testleri, SEM analizi yapılmıştır. Numunelerin ozonlanıp sonrasında susuz ortamda boyanması sonucunda, konvansiyonel boyalı kumaşlara göre daha yüksek renk mukavemeti (K/S) ile daha iyi haslık testi sonuçları ve kopma mukavemeti değerleri elde edilmiştir.

Anahtar Kelimeler

• poliester
• ozon
• süperkritik karbondioksit
• yüzey modifikasyonu
• boyama

Kaynakça

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