Research Article
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Year 2025, Volume: 6 Issue: 1, 24 - 29, 20.07.2025
https://doi.org/10.53635/jit.1587147

Abstract

References

  • Demir, M. (2011). SBS, EVA ve Reaktif Terpolimer Kullanılarak Bitüm Modifikasyonu (Master’s Thesis, Yıldız Technical University).
  • ETİMADEN (2021). Bor Sektör Raporu. Eti maden İşletmeleri Genel Müdürlüğü.
  • TENMAK BOREN. (2024). Rezervler. [Last Accessed:18.03.2024] https://boren.tenmak.gov.tr/tr/calisma-alanlari/rezervler.html
  • Kumandaş, A., & Pancar, E. B. (2023). Bitüm Modifikasyonunda Kullanılan Güncel Katkı Maddeleri: Bir Literatür Araştırması. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi, 3(2), 109-140.
  • Morova, N., & Terzi, S. (2015). Kolemanit atıkların sıcak karışım asfalt betonda agrega olarak değerlendirilmesi. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 19(2), 8-15.
  • Selman, G. Ş. (2015). Bor Atiklarinin Asfalt Kaplamalarda Mineral Filler Olarak Kullanilabilirliği (Master's Thesis, Afyon Kocatepe University).
  • Keskin, M., & Karacasu, M. (2018). Atık bor içeren asfalt betonlarının performanslarının değerlendirilmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi, 30(2), 185-192.
  • Şinoforoğlu, F. (2019). Bor mineralinin bitüm katkı malzemesi olarak kullanılmasının taş mastik asfaltların mühendislik özelliklerine etkisi (Master's Thesis, Recep Tayyip Erdoğan University).
  • Kara, H. (2021). Taş mastik asfalt ve beton yol kaplama inşasında bor atıklarının kullanılabilirliği (Master's Thesis, Bitlis Eren University).
  • Lentz, Alfred P. (1945). Asphaltic Compound, United States Patent Office, Patent No: 2375117.
  • Arslan, D., Gürü, M., Çubuk, M. K., & Çubuk, M. (2011). Improvement of bitumen and bituminous mixtures performances by triethylene glycol based synthetic polyboron. Construction and Building Materials, 25(10), 3863-3868. https://doi.org/10.1016/j.conbuildmat.2011.04.007
  • Arslan, D., Gürü, M., & Çubuk, M. K. (2012). Performance assessment of organic-based synthetic calcium and boric acid modified bitumens. Fuel, 102, 766-772. https://doi.org/10.1016/j.fuel.2012.06.038
  • Arslan, D., Gürü, M., & Çubuk, M. K. (2014). Preventing of rutting and crackings in the bituminous mixtures by monoethylene and diethylene glycol based synthetic polyboron compounds. Construction and Building Materials, 50, 102-107. https://doi.org/10.1016/j.conbuildmat.2013.09.039
  • Oruç, Ş., Yılmaz, B., & Sancak, K. (2016). Effect of boron-containing additives on rheological properties of asphalt binder. Road Materials and Pavement Design, 17(4), 810-824. https://doi.org/10.1080/14680629.2015.1120228
  • Yılmaz, B. (2016). Bor içerikli organik katkıyla modifiye edilen asfaltın performans özelliklerinin araştırılması (Doctoral Thesis, Karadeniz Technical University).
  • Oruç, Ş., & Yılmaz, B. (2016). Improvement in performance properties of asphalt using a novel boron-containing additive. Construction and Building Materials, 123, 207-213. https://doi.org/10.1016/j.conbuildmat.2016.07.003
  • Şahin, D. (2017) Aspir yağı ve borik asit içerikli organik katkının bitümün fiziksel ve reolojik özellikleri üzerine etkisi (Master's Thesis, Karadeniz Technical University).
  • Gürü, M., Çubuk, M. K., Arslan, D., & Aminbakhsh, S. (2017). Effects of sugar beet molasses and molasses-based boron oxide compound on bitumen properties. Journal of Materials in Civil Engineering, 29(4), 04016252. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001790
  • Chai, Z. H. (2015). An Investigation Study on Usage of Boric Powder and Ethylene Glycol Based Synthetic Boric Acid Polymer as Bitumen Modifiers (Doctoral dissertation, Universiti Tunku Abdul Rahman).
  • Yüknü, K., Öztürk, T., & Komut, M. (2021). Bitümlü bağlayıcılar laboratuvar el kitabı. Erişim adresi: https://www.kgm.gov.tr/SiteCollectionDocuments/KGMdocuments/Baskanliklar/BaskanliklarTeknikArastirma/BitumluBaglayicilarLaboratuvarElKitabi.pdf

Investigation of the effect of boric acid additive on bitumen modification by DSR and FT-IR test methods

Year 2025, Volume: 6 Issue: 1, 24 - 29, 20.07.2025
https://doi.org/10.53635/jit.1587147

Abstract

Bitumen, one of the oldest known engineering materials, has been extensively utilized for millennia as both a waterproofing agent and a binder in pavement construction. To improve its engineering properties, a wide range of materials have been explored for bitumen modification. In recent years, a notable increase in the use of boron compounds for this purpose has been reported in the literature. Most existing studies focus on the laboratory synthesis of boron-based additives, which are then incorporated into bitumen matrices. In the present study, the effect of boric acid—a by-product of boron—on the rheological and chemical properties of bitumen was investigated. Modified bitumen samples were produced using varying concentrations of boric acid (0.05%, 0.10%, and 0.15% by weight). Rheological properties were assessed using a Dynamic Shear Rheometer (DSR), while chemical characterization was performed through Fourier Transform Infrared Spectroscopy (FT-IR). DSR results demonstrated that boric acid enhanced the viscoelastic performance of bitumen. Additionally, FT-IR analysis revealed notable changes in the chemical structure of the modified samples, indicating potential interactions between boric acid and the bitumen matrix.

References

  • Demir, M. (2011). SBS, EVA ve Reaktif Terpolimer Kullanılarak Bitüm Modifikasyonu (Master’s Thesis, Yıldız Technical University).
  • ETİMADEN (2021). Bor Sektör Raporu. Eti maden İşletmeleri Genel Müdürlüğü.
  • TENMAK BOREN. (2024). Rezervler. [Last Accessed:18.03.2024] https://boren.tenmak.gov.tr/tr/calisma-alanlari/rezervler.html
  • Kumandaş, A., & Pancar, E. B. (2023). Bitüm Modifikasyonunda Kullanılan Güncel Katkı Maddeleri: Bir Literatür Araştırması. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi, 3(2), 109-140.
  • Morova, N., & Terzi, S. (2015). Kolemanit atıkların sıcak karışım asfalt betonda agrega olarak değerlendirilmesi. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 19(2), 8-15.
  • Selman, G. Ş. (2015). Bor Atiklarinin Asfalt Kaplamalarda Mineral Filler Olarak Kullanilabilirliği (Master's Thesis, Afyon Kocatepe University).
  • Keskin, M., & Karacasu, M. (2018). Atık bor içeren asfalt betonlarının performanslarının değerlendirilmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi, 30(2), 185-192.
  • Şinoforoğlu, F. (2019). Bor mineralinin bitüm katkı malzemesi olarak kullanılmasının taş mastik asfaltların mühendislik özelliklerine etkisi (Master's Thesis, Recep Tayyip Erdoğan University).
  • Kara, H. (2021). Taş mastik asfalt ve beton yol kaplama inşasında bor atıklarının kullanılabilirliği (Master's Thesis, Bitlis Eren University).
  • Lentz, Alfred P. (1945). Asphaltic Compound, United States Patent Office, Patent No: 2375117.
  • Arslan, D., Gürü, M., Çubuk, M. K., & Çubuk, M. (2011). Improvement of bitumen and bituminous mixtures performances by triethylene glycol based synthetic polyboron. Construction and Building Materials, 25(10), 3863-3868. https://doi.org/10.1016/j.conbuildmat.2011.04.007
  • Arslan, D., Gürü, M., & Çubuk, M. K. (2012). Performance assessment of organic-based synthetic calcium and boric acid modified bitumens. Fuel, 102, 766-772. https://doi.org/10.1016/j.fuel.2012.06.038
  • Arslan, D., Gürü, M., & Çubuk, M. K. (2014). Preventing of rutting and crackings in the bituminous mixtures by monoethylene and diethylene glycol based synthetic polyboron compounds. Construction and Building Materials, 50, 102-107. https://doi.org/10.1016/j.conbuildmat.2013.09.039
  • Oruç, Ş., Yılmaz, B., & Sancak, K. (2016). Effect of boron-containing additives on rheological properties of asphalt binder. Road Materials and Pavement Design, 17(4), 810-824. https://doi.org/10.1080/14680629.2015.1120228
  • Yılmaz, B. (2016). Bor içerikli organik katkıyla modifiye edilen asfaltın performans özelliklerinin araştırılması (Doctoral Thesis, Karadeniz Technical University).
  • Oruç, Ş., & Yılmaz, B. (2016). Improvement in performance properties of asphalt using a novel boron-containing additive. Construction and Building Materials, 123, 207-213. https://doi.org/10.1016/j.conbuildmat.2016.07.003
  • Şahin, D. (2017) Aspir yağı ve borik asit içerikli organik katkının bitümün fiziksel ve reolojik özellikleri üzerine etkisi (Master's Thesis, Karadeniz Technical University).
  • Gürü, M., Çubuk, M. K., Arslan, D., & Aminbakhsh, S. (2017). Effects of sugar beet molasses and molasses-based boron oxide compound on bitumen properties. Journal of Materials in Civil Engineering, 29(4), 04016252. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001790
  • Chai, Z. H. (2015). An Investigation Study on Usage of Boric Powder and Ethylene Glycol Based Synthetic Boric Acid Polymer as Bitumen Modifiers (Doctoral dissertation, Universiti Tunku Abdul Rahman).
  • Yüknü, K., Öztürk, T., & Komut, M. (2021). Bitümlü bağlayıcılar laboratuvar el kitabı. Erişim adresi: https://www.kgm.gov.tr/SiteCollectionDocuments/KGMdocuments/Baskanliklar/BaskanliklarTeknikArastirma/BitumluBaglayicilarLaboratuvarElKitabi.pdf
There are 20 citations in total.

Details

Primary Language English
Subjects Transportation Engineering
Journal Section Research Article
Authors

Emre Uyar 0000-0003-4369-0892

Hüseyin Akbulut 0000-0003-4504-4384

Publication Date July 20, 2025
Submission Date November 18, 2024
Acceptance Date May 12, 2025
Published in Issue Year 2025 Volume: 6 Issue: 1

Cite

APA Uyar, E., & Akbulut, H. (2025). Investigation of the effect of boric acid additive on bitumen modification by DSR and FT-IR test methods. Journal of Innovative Transportation, 6(1), 24-29. https://doi.org/10.53635/jit.1587147

Journal of Innovative Transportation (JInnovTrans)
ISSN (Online): 2717-8889 | DOI Prefix: 10.53635/jit | Publisher: Süleyman Demirel University, Isparta, Türkiye
This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0)
© Journal of Innovative Transportation. Published by Süleyman Demirel University – Open Access.
E-mail: jit@sdu.edu.tr    | Website: https://dergipark.org.tr/en/pub/jit