Research Article

All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode

Volume: 10 Number: 2 August 31, 2021
EN

All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode

Abstract

A novel all-solid-state contact poly (vinyl chloride) (PVC) membrane–containing thiocyanate-selective electrode has been prepared. The electrode exhibits the best performance with a membrane composition of PVC:BEHS:ionophore:KTpClPB of 33.0:64.0:2.0:1.0 (%, w/w). The thiocyanate–selective electrode displays a linear response in the concentration range of 1.0 × 10−4 – 1.0 × 10−1 M. The proposed electrode shows good reusability. The thiocyanate–selective electrode shows a better selective response towards thiocyanate compared to different anions. The electrode has a fast response time of the 20s and can be used in a pH range of 5.0–9.0.

Keywords

Thiocyanate, Potentiometry, ion-selective electrode, PVC membrane

References

  1. O. Özbek, Ö. Işıldak, C. Berkel, The use of porphyrins in potentiometric sensors as ionophores, Journal of Inclusion Phenomena and Macrocyclic Chemistry, 98(1-2), (2020) 1–9.
  2. Ö. Işıldak, O. Özbek, M. B. Gürdere, Development of chromium (III)-selective potentiometric sensor by using synthesized pyrazole derivative as an ionophore in PVC matrix and its applications, Journal of Analysis and Testing, 4(4), (2020) 273–280.
  3. Ö. Işıldak, O. Özbek, K. M. Yigit, A bromide-selective PVC membrane potentiometric sensor, Bulgarian Chemical Communications, 52(4), (2020) 448–452.
  4. Ö. Işıldak, N. Deligönül, O. Özbek, A novel silver(I)-selective PVC membrane sensor and its potentiometric applications, Turkish Journal of Chemistry, 43(4), (2019) 1149–1158.
  5. Ö. Işıldak, O. Özbek, K. M. Yigit, Zinc (II)-selective PVC membrane potentiometric sensor for analysis of Zn2+ in drug sample and different environmental samples, International Journal of Environmental Analytical Chemistry, (2019) 1–11.
  6. Ö. Işıldak, O. Özbek, Application of potentiometric sensors in real samples, Critical Reviews in Analytical Chemistry, (2020) 1–14.
  7. O. Özbek, C. Berkel, Ö. Işıldak, Applications of potentiometric sensors for the determination of drug molecules in biological samples, Critical Reviews in Analytical Chemistry, (2020) 1–12.
  8. O. Özbek, Ö. Işıldak, K. M. Yigit, A. Çetin, The use of potentiometric sensors in wastewater analysis, Turkish Journal of Science and Health, 1(2), (2020) 70–78.
  9. O. R. Shehab, A. M. Mansour, New thiocyanate potentiometric sensors based on sulfadimidine metal complexes: Experimental and theoretical studies, Biosensors and Bioelectronics, 57, (2014) 77–84.
  10. M. M. Ardakani, M. Jamshidpour, H. Naeimi, L. Moradi, Thiocyanate ion-selective PVC membrane electrode based on N, N′-ethylene-bis (4-methylsalicylidineiminato) nickel (II), Analytical Sciences, 22(9), (2006) 1221–1226.
APA
Özbek, O., & Işıldak, Ö. (2021). All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode. Journal of New Results in Science, 10(2), 33-39. https://izlik.org/JA43UM53BN
AMA
1.Özbek O, Işıldak Ö. All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode. JNRS. 2021;10(2):33-39. https://izlik.org/JA43UM53BN
Chicago
Özbek, Oğuz, and Ömer Işıldak. 2021. “All-Solid-State Poly (vinyl Chloride) Membrane Thiocyanate–selective Potentiometric Electrode”. Journal of New Results in Science 10 (2): 33-39. https://izlik.org/JA43UM53BN.
EndNote
Özbek O, Işıldak Ö (August 1, 2021) All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode. Journal of New Results in Science 10 2 33–39.
IEEE
[1]O. Özbek and Ö. Işıldak, “All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode”, JNRS, vol. 10, no. 2, pp. 33–39, Aug. 2021, [Online]. Available: https://izlik.org/JA43UM53BN
ISNAD
Özbek, Oğuz - Işıldak, Ömer. “All-Solid-State Poly (vinyl Chloride) Membrane Thiocyanate–selective Potentiometric Electrode”. Journal of New Results in Science 10/2 (August 1, 2021): 33-39. https://izlik.org/JA43UM53BN.
JAMA
1.Özbek O, Işıldak Ö. All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode. JNRS. 2021;10:33–39.
MLA
Özbek, Oğuz, and Ömer Işıldak. “All-Solid-State Poly (vinyl Chloride) Membrane Thiocyanate–selective Potentiometric Electrode”. Journal of New Results in Science, vol. 10, no. 2, Aug. 2021, pp. 33-39, https://izlik.org/JA43UM53BN.
Vancouver
1.Oğuz Özbek, Ömer Işıldak. All-solid-state poly (vinyl chloride) membrane thiocyanate–selective potentiometric electrode. JNRS [Internet]. 2021 Aug. 1;10(2):33-9. Available from: https://izlik.org/JA43UM53BN