Statistical Thermodynamics of Linear Macromolecular Structures: A Systematic Expansion to Simha-Somcynsky Lattice Hole Theory
Öz
Anahtar Kelimeler
Kaynakça
- Jang, J.G. and Bae, Y.C., Phase Behaviors of Hyperbranched Polmer Solutions. Polymer, 1999. 40: p. 6761-6768.
- Lennard-Jones, J.E. and Devonshire, A.F., Proc. R.London, Series A, 1937(163): p. 53. [3] Lennard-Jones, J.E. and Devonshire, A.F., Proc. R.London, Series A, 1938(165): p. 1.
- Prigogine, I., Trappeniers, N., and Mathot, V., Statistical Thermodynamics of R-Mers and R-Mer Solutions. Discussions of the Faraday Society, 1953(15): p. 93-125.
- Prigogine, I., Trappeniers, N., and Mathot, V., in The Molecular Theory Of Solutions. 1957, North Holland Publishing Company: Amsterdam.
- Simha, R. and :, S.T., On Statistical Thermodynamics of Spherical and Chain Molecule Fluids. Macromolecules, 1969. 2(4): p. 342-&.
- Flory, P.J., Thermodynamics of High Polymer Solutions. Journal of Chemical Physics, 1941. 9(8): p. 660.
- Huggins, M.L., Solutions of Long Chain Compounds. J. Chem. Phys., 1941. 9(5): p. 440. [9] Flory, P.J., Thermodynamics of High Polymer Solutions. J. Chem. Phys., 1942. 10: p. 51. [10] Freed, K.F. and Bawendi, M.G., Lattice Theories of Polymeric Fluids. Journal of Physical Chemistry, 1989. 93(6): p. 2194-2203.
- Nemirovsky A.M., Bawendi M.G., and Freed K.F., Lattice Models of Polymer Solutions. Monomers Occupying Several Lattice Sites. J. Chem. Phys., 1987(12): p. 7272.
- Bawendi, M.G. and Freed, K.F., Systematic Corrections to Flory-Huggins Theory - Polymer Solvent Void Systems and Binary Blend Void Systems. Journal of Chemical Physics, 1988. 88(4): p. 2741-2756.
LİNEER MAKROMOLEKÜLER YAPILARIN İSTATİSTİKSEL TERMODİNAMİĞİ: SIMHASOMCYNSKY ÖRGÜ-BOŞLUK TEORİSİNE SİSTEMATİK BİR SERİ AÇILIMI
Öz
Lineer ların istatistiksel termodinamiğinde kullanılan ilk modeller, yapı
bağımlılığı içermeyen ortalama alan teorileridir. (mean field theories) Bir
ortalama alan teorisi olan ve örgüdeki düzensizliğin ölçüsünün
boşluklarla(hole) ifade edildiği Simha-Somcynsky (SS) teorisi, lineer
yapılarda başarıyla kullanılmaktadır. Bu teori dallanmanın başladığı
yapılarda da kullanılması, teorik ve uygulamalı çalışmalar açısından
önemlidir. Bu amaçla teorinin dallanmış yapılara adapte edilmesi için,
zincir yapılardan hareket edilerek Örgü-Küme Teorisinden (Lattice-Cluster
Theory) yararlanılacaktır.
Anahtar Kelimeler
Makromolekül istatistiksel termodinamik SimhaSomcynsky (SS) teorisi Örgü-Küme Teorisi.
Kaynakça
- Jang, J.G. and Bae, Y.C., Phase Behaviors of Hyperbranched Polmer Solutions. Polymer, 1999. 40: p. 6761-6768.
- Lennard-Jones, J.E. and Devonshire, A.F., Proc. R.London, Series A, 1937(163): p. 53. [3] Lennard-Jones, J.E. and Devonshire, A.F., Proc. R.London, Series A, 1938(165): p. 1.
- Prigogine, I., Trappeniers, N., and Mathot, V., Statistical Thermodynamics of R-Mers and R-Mer Solutions. Discussions of the Faraday Society, 1953(15): p. 93-125.
- Prigogine, I., Trappeniers, N., and Mathot, V., in The Molecular Theory Of Solutions. 1957, North Holland Publishing Company: Amsterdam.
- Simha, R. and :, S.T., On Statistical Thermodynamics of Spherical and Chain Molecule Fluids. Macromolecules, 1969. 2(4): p. 342-&.
- Flory, P.J., Thermodynamics of High Polymer Solutions. Journal of Chemical Physics, 1941. 9(8): p. 660.
- Huggins, M.L., Solutions of Long Chain Compounds. J. Chem. Phys., 1941. 9(5): p. 440. [9] Flory, P.J., Thermodynamics of High Polymer Solutions. J. Chem. Phys., 1942. 10: p. 51. [10] Freed, K.F. and Bawendi, M.G., Lattice Theories of Polymeric Fluids. Journal of Physical Chemistry, 1989. 93(6): p. 2194-2203.
- Nemirovsky A.M., Bawendi M.G., and Freed K.F., Lattice Models of Polymer Solutions. Monomers Occupying Several Lattice Sites. J. Chem. Phys., 1987(12): p. 7272.
- Bawendi, M.G. and Freed, K.F., Systematic Corrections to Flory-Huggins Theory - Polymer Solvent Void Systems and Binary Blend Void Systems. Journal of Chemical Physics, 1988. 88(4): p. 2741-2756.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 25 Mart 2016 |
| Yayımlandığı Sayı | Yıl 2010 Cilt: 6 Sayı: 3 |