The synthesis, characterization, electrochemistry, theoretical investigation and antioxidant capability of cobalt cefazolin [Co(Cefaz)Cl] complex are reported here. Electrochemical characterization of the complex was carried out by using cyclic voltammetry (CV) and Linear Sweep Voltammetry (LSV) methods. Two irreversible oxidative responses and one quasi-reversible reduction couple were observed for the complex on the voltammograms. The ground state energies of the molecules have been estimated using B3LYP functional with LanL2DZ basis set based on time dependent density functional theory (TD-DFT). According to the theoretical calculation, [Co(Cefaz)Cl] complex can be expected to exhibit greater reactivity from Cefazolin (Cefaz) ligand, and the higher antioxidant properties were observed for the complex. The experimental results are in good agreement with the theoretical calculations.
cefazolin complex electrochemistry DFT calculation antioxidant capability
The Scientific Research Projects Coordination Unit of Istanbul University-Cerrahpasa
35195
35195
Birincil Dil | İngilizce |
---|---|
Konular | Fiziksel Kimya, Elektrokimya |
Bölüm | Makaleler |
Yazarlar | |
Proje Numarası | 35195 |
Yayımlanma Tarihi | 30 Kasım 2022 |
Gönderilme Tarihi | 7 Eylül 2022 |
Kabul Tarihi | 21 Eylül 2022 |
Yayımlandığı Sayı | Yıl 2022 |