Research Article

A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode

Volume: 10 Number: 1 February 28, 2023
EN

A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode

Abstract

Herein, the copper-based electrodes were successfully synthesized with galvanostatic electrodeposition method. The effect of materials obtained at different concentrations of ASA and anodization times on glucose sensing ability was investigated. During the anodization of copper foil in the presence of ASA molecules, it formed a tree branch-like structure connected to each other while decorating the electrode surface. The Cu(30)/ASA(0.02) electrode exhibited a relatively wide linear range (0.2 – 10.0 mM) and a low detection limit (0.826 µM). These excellent activities were mainly attributed to the surface morphology, which functions as highly active sites and enhanced electronic conductive pathways with the addition of ASA. In addition, the stability obtained together with the excellent sensing ability in beverages makes the electrodes useful for practical applications.

Keywords

Thanks

M.B. Arvas especially thanks Prof. Dr. Yucel Sahin for his valuable contributions to this study.

References

  1. 1. Yoo E-H, Lee S-Y. Glucose Biosensors: An Overview of Use in Clinical Practice. Sensors [Internet]. 2010 May 4;10(5):4558–76. Available from: http://www.mdpi.com/1424-8220/10/5/4558
  2. 2. Khor SM, Choi J, Won P, Ko SH. Challenges and Strategies in Developing an Enzymatic Wearable Sweat Glucose Biosensor as a Practical Point-Of-Care Monitoring Tool for Type II Diabetes. Nanomaterials [Internet]. 2022 Jan 10;12(2):221. Available from: https://www.mdpi.com/2079-4991/12/2/221
  3. 3. Osuna V, Vega-Rios A, Zaragoza-Contreras EA, Estrada-Moreno IA, Dominguez RB. Progress of Polyaniline Glucose Sensors for Diabetes Mellitus Management Utilizing Enzymatic and Non-Enzymatic Detection. Biosensors [Internet]. 2022 Feb 22;12(3):137. Available from: https://www.mdpi.com/2079-6374/12/3/137
  4. 4. Hassan MH, Vyas C, Grieve B, Bartolo P. Recent Advances in Enzymatic and Non-Enzymatic Electrochemical Glucose Sensing. Sensors [Internet]. 2021 Jul 8;21(14):4672. Available from: https://www.mdpi.com/1424-8220/21/14/4672
  5. 5. Malekzad H, Sahandi Zangabad P, Mirshekari H, Karimi M, Hamblin MR. Noble metal nanoparticles in biosensors: recent studies and applications. Nanotechnol Rev [Internet]. 2017 Jun 27;6(3):301–29. Available from: https://www.degruyter.com/document/doi/10.1515/ntrev-2016-0014/html
  6. 6. Barbee B, Muchharla B, Adedeji A, Karoui A, Kumar Sadasivuni K, Sha MS, et al. Cu and Ni Co-sputtered heteroatomic thin film for enhanced nonenzymatic glucose detection. Sci Rep [Internet]. 2022 May 7;12(1):7507. Available from: https://www.nature.com/articles/s41598-022-11563-4
  7. 7. Pourbeyram S, Mehdizadeh K. Nonenzymatic glucose sensor based on disposable pencil graphite electrode modified by copper nanoparticles. J Food Drug Anal [Internet]. 2016 Oct 1;24(4):894–902. Available from: https://linkinghub.elsevier.com/retrieve/pii/S102194981630031X
  8. 8. Yazar S, Kurtulbaş E, Ortaboy S, Atun G, Şahin S. Screening of the antioxidant properties of olive (Olea europaea) leaf extract by titanium based reduced graphene oxide electrode. Korean J Chem Eng [Internet]. 2019 Jul 25;36(7):1184–92. Available from: http://link.springer.com/10.1007/s11814-019-0288-9

Details

Primary Language

English

Subjects

Analytical Chemistry, Electrochemistry, Chemical Engineering

Journal Section

Research Article

Publication Date

February 28, 2023

Submission Date

October 1, 2022

Acceptance Date

December 26, 2022

Published in Issue

Year 2023 Volume: 10 Number: 1

APA
Arvas, M. B. (2023). A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode. Journal of the Turkish Chemical Society Section A: Chemistry, 10(1), 227-240. https://doi.org/10.18596/jotcsa.1182942
AMA
1.Arvas MB. A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode. JOTCSA. 2023;10(1):227-240. doi:10.18596/jotcsa.1182942
Chicago
Arvas, Melih Beşir. 2023. “A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-Sulfonic Acid-Modified Cu Electrode”. Journal of the Turkish Chemical Society Section A: Chemistry 10 (1): 227-40. https://doi.org/10.18596/jotcsa.1182942.
EndNote
Arvas MB (February 1, 2023) A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode. Journal of the Turkish Chemical Society Section A: Chemistry 10 1 227–240.
IEEE
[1]M. B. Arvas, “A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode”, JOTCSA, vol. 10, no. 1, pp. 227–240, Feb. 2023, doi: 10.18596/jotcsa.1182942.
ISNAD
Arvas, Melih Beşir. “A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-Sulfonic Acid-Modified Cu Electrode”. Journal of the Turkish Chemical Society Section A: Chemistry 10/1 (February 1, 2023): 227-240. https://doi.org/10.18596/jotcsa.1182942.
JAMA
1.Arvas MB. A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode. JOTCSA. 2023;10:227–240.
MLA
Arvas, Melih Beşir. “A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-Sulfonic Acid-Modified Cu Electrode”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 10, no. 1, Feb. 2023, pp. 227-40, doi:10.18596/jotcsa.1182942.
Vancouver
1.Melih Beşir Arvas. A Highly Sensitive Non-Enzymatic Sensor for the Determination of Glucose Based on Aniline-2-sulfonic acid-Modified Cu Electrode. JOTCSA. 2023 Feb. 1;10(1):227-40. doi:10.18596/jotcsa.1182942

Cited By