Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)

Abstract

Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.

Keywords

• Molybdenum
• Chromium
• Polyoxometalate
• Anderson-Evans.

References

1. 1. Wang S-S, Yang G-Y. Recent Advances in Polyoxometalate-Catalyzed Reactions. Chem Rev [Internet]. 2015 Jun 10;115(11):4893-962. Available from: https://pubs.acs.org/doi/10.1021/cr500390v
2. 2. Cherevan AS, Nandan SP, Roger I, Liu R, Streb C, Eder D. Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives. Adv Sci [Internet]. 2020 Apr 6;7(8):1903511. Available from: https://onlinelibrary.wiley.com/doi/10.1002/advs.201903511
3. 3. Ramezani-Aliakbari M, Varshosaz J, Sadeghi-aliabadi H, Hassanzadeh F, Rostami M. Biotin-Targeted Nanomicellar Formulation of an Anderson-Type Polyoxomolybdate: Synthesis and In Vitro Cytotoxicity Evaluations. Langmuir [Internet]. 2021 Jun 1;37(21):6475-89. Available from: https://pubs.acs.org/doi/10.1021/acs.langmuir.1c00623
4. 4. Streb C, Kastner K, Tucher J. Polyoxometalates in photocatalysis. Phys Sci Rev [Internet]. 2019 May 27;4(6):20170177. Available from: https://www.degruyter.com/document/doi/10.1515/psr-2017-0177/html
5. 5. Shen Y, Jiang P, Wai P, Gu Q, Zhang W. Recent Progress in Application of Molybdenum-Based Catalysts for Epoxidation of Alkenes. Catalysts [Internet]. 2019 Jan 2;9(1):31. Available from: https://www.mdpi.com/2073-4344/9/1/31
6. 6. Rhule JT, Hill CL, Judd DA, Schinazi RF. Polyoxometalates in Medicine. Chem Rev [Internet]. 1998 Feb 1;98(1):327-58. Available from: https://pubs.acs.org/doi/10.1021/cr960396q
7. 7. Bijelic A, Rompel A. The use of polyoxometalates in protein crystallography – An attempt to widen a well-known bottleneck. Coord Chem Rev [Internet]. 2015 Sep 1;299:22-38. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0010854515001150
8. 8. Bijelic A, Rompel A. Ten Good Reasons for the Use of the Tellurium-Centered Anderson–Evans Polyoxotungstate in Protein Crystallography. Acc Chem Res [Internet]. 2017 Jun 20;50(6):1441-8. Available from: https://pubs.acs.org/doi/10.1021/acs.accounts.7b00109

9. 9. Proust A, Thouvenot R, Gouzerh P. Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science. Chem Commun [Internet]. 2008;(16):1837. Available from: http://xlink.rsc.org/?DOI=b715502f
10. 10. Tucher J, Wu Y, Nye LC, Ivanovic-Burmazovic I, Khusniyarov MM, Streb C. Metal substitution in a Lindqvist polyoxometalate leads to improved photocatalytic performance. Dalt Trans [Internet]. 2012 Jul 31;41(33):9938-43. Available from: http://xlink.rsc.org/?DOI=c2dt30304c
11. 11. Tucher J, Schlicht S, Kollhoff F, Streb C. Photocatalytic reactivity tuning by heterometal and addenda metal variation in Lindqvist polyoxometalates. Dalt Trans [Internet]. 2014 Oct 29;43(45):17029-33. Available from: http://xlink.rsc.org/?DOI=C4DT02682A
12. 12. Jin P, Wei H, Zhou L, Wei D, Wen Y, Zhao B, et al. Anderson-type polyoxometalate as excellent catalyst for green synthesis of adipic acid with hydrogen peroxide. Mol Catal [Internet]. 2021 Jun 1;510:111705. Available from: https://linkinghub.elsevier.com/retrieve/pii/S2468823121003229
13. 13. Wu P, Wang Y, Huang B, Xiao Z. Anderson-type polyoxometalates: from structures to functions. Nanoscale [Internet]. 2021 Apr 23;13(15):7119-33. Available from: http://xlink.rsc.org/?DOI=D1NR00397F
14. 14. Liu W, Lin Z, Bassil BS, Al-Oweini R, Kortz U. Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6–. Chima [Internet]. 2015 Sep 30;69(9):537-40. Available from: https://ojs.chimia.ch/chimia/article/view/5795
15. 15. Ouahab L, Golhen S, Yoshida Y, Saito G. One Dimensional Face-to-Face Stacking of Anderson–Evans [Cr(OH)6Mo6O18]3- Polyoxometalate Anion: Synthesis, Structure, and Physical Properties of (BEDT-TTF) 4 [Cr(OH)6 Mo6O18] 2H2O. J Clust Sci [Internet]. 2003 Sep;14(3):193-204. Available from: http://link.springer.com/10.1023/B:JOCL.0000005057.12788.0a
16. 16. Li Q, Wei Y. A series of unprecedented triol-stabilized [H 3 MW6O24]n− : the missing piece between A- and B-type Anderson–Evans polyoxometalates. Chem Commun [Internet]. 2018 Feb 1;54(11):1375-8. Available from: http://xlink.rsc.org/?DOI=C7CC08976G
17. 17. Gumerova NI, Caldera Fraile T, Roller A, Giester G, Pascual-Borras M, Ohlin CA, et al. Direct Single- and Double-Side Triol-Functionalization of the Mixed Type Anderson Polyoxotungstate [Cr(OH)3W6O21]6–. Inorg Chem [Internet]. 2019 Jan 7;58(1):106-13. Available from: https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01740
18. 18. An H, Guo Y, Li Y, Wang E, Lü J, Xu L, et al. A novel organic-inorganic hybrid with Anderson type polyanions as building blocks: [(Gly)2Cu][Na(H2O)4Cr(OH)6Mo6O 18]∙9.5H2O (Gly=glycine). Inorg Chem Commun [Internet]. 2004 Apr 1;7(4):521-3. Available from: https://linkinghub.elsevier.com/retrieve/pii/S1387700304000371
19. 19. Yin M, Yusov AB, Fedosseev AM, Krupa J-C. Optical evidence of Cr3+ ion pairs in (NH4)3[Cr(OH)6Mo6O18]∙nH2O. J Alloys Compd [Internet]. 2004 Sep 8;377(1-2):43-6. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0925838804001641
20. 20. Shivaiah V, Das SK. Polyoxometalate-Supported Transition Metal Complexes and Their Charge Complementarity: Synthesis and Characterization of [M(OH)6Mo6O18{Cu(Phen)(H2O)2}2][M(OH)6Mo6O18 {Cu(Phen)(H2O)Cl}2]·5H2O (M=Al3+, Cr3+). Inorg Chem [Internet]. 2005 Nov 1;44(24):8846-54. Available from: https://pubs.acs.org/doi/10.1021/ic050830j
21. 21. Shi D-M, Ma F-X, Zhang C-J, Lu S, Chen Y-G. Self-Assembly of Polyoxometalate-Supported Ln-H nydroxo/Oxo Clusters with 1D Extended Structure: [LnIII(H2O)7Cr(OH)6Mo6O18]n∙4nH2O (Ln= Ce, Sm, Eu). Z. Anorg. Allg. Chem. [Internet]. 2008 Apr 1;634(4):758-63. Available from: https://onlinelibrary.wiley.com/doi/10.1002/zaac.200700498
22. 22. Shi D, Hu M, Zhang C, Li J, Chen Y. Synthesis and Structure of a Novel Polyoxomolybdate Lanthanide Complex: [Er2(H2O)14Cr(OH)6Mo6O18][Cr(OH)6Mo6O18]∙14H2O. J Chem Crystallogr [Internet]. 2008 Sep 9;38(9):695-700. Available from: http://link.springer.com/10.1007/s10870-008-9378-y
23. 23. Ma H, Wu L, Pang H, Meng X, Peng J. Hydrothermal synthesis of two Anderson POM-supported transition metal organic-inorganic compounds. J Mol Struct [Internet]. 2010 Apr 1;967(1-3):15-9. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0022286009007716
24. 24. Peng Z-S, Zhang C-L, Shen X-M, Deng Q, Cai T-J. A novel Anderson-type polyoxometalate: hydrothermal synthesis, crystal structure, and catalytic performance of (H3O)[(3-C5H7N2)2 (Cr(OH)6Mo6O18 )]∙3H2O. J Coord Chem [Internet]. 2011 Aug 20;64(16):2848-58. Available from: https://www.tandfonline.com/doi/full/10.1080/00958972.2011.607897
25. 25. Gumerova NI, Melnik NA, Rozantsev GM, Baumer VN, Radio S V. Sodium heteropolyhexamolybdenumnickelate (II) Na4[Ni(OH)6Mo6O18]∙16H2O with an anderson anion: Synthesis and crystal structure. J Struct Chem [Internet]. 2015 Sep 16;56(5):926-33. Available from: http://link.springer.com/10.1134/S0022476615050157
26. 26. Tewari S, Adnan M, Balendra, Kumar V, Jangra G, Prakash GV, et al. Photoluminescence Properties of Two Closely Related Isostructural Series Based on Anderson-Evans Cluster Coordinated With Lanthanides [Ln(H2O)7{X(OH)6Mo6O18}]∙yH2O, X = Al, Cr. Front Chem [Internet]. 2019 Jan 7;6:631. Available from: https://www.frontiersin.org/article/10.3389/fchem.2018.00631/full
27. 27. Wang Y, Wu Z, Yu H, Han S, Wei Y. Highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2. Green Chem [Internet]. 2020 May 26;22(10):3150-4. Available from: http://xlink.rsc.org/?DOI=D0GC00388C