Synthesis and Characterization of Poly(N-Hydroxymethyl Acrylamide)/Na-Montmorillonite Composites

Year 2017, Volume: 4 Issue: 1, 39 - 50, 13.07.2017

Sibel Erol Dağ Pınar Acar Bozkurt , Meltem Çelik

https://doi.org/10.18596/jotcsa.324877

Abstract

In this study, N-hydroxymethyl
acrylamide (HMAm) monomer was mixed with Na-Montmorillonite (Na-MT) in
different ratio. The mixture was polymerized in the presence of benzoyl
peroxide (Bz₂O₂) with in-situ radical polymerization to
prepare poly(N-hydroxymethyl acrylamide) (PHMAm)/Na-Montmorillonite (Na-MT) composites.
Purified Na-MT, and also produced composites with different ratio were characterized
with Fourier transform infrared (FTIR)
spectroscopy, X-ray diffraction (XRD), scanning electron microscopy
(SEM), thermal analysis (TGA/DTA) techniques. The moisture retention,
water uptake, adsorptive properties of composites was also researched. The XRD pattern demonstrated that Na-MT layers intercalated into the PHMAm matrix. The composites displayed
much better thermal stability than
the pure polymer.

Keywords

Composite , clay , poly(N-hydroxymethyl acrylamide) , benzoyl peroxide

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