Novel
metallophthalocyanines (M = Zn, Co)
carrying on the four of the
peripheral positions (E)-1-(furan-2-yl)-3-(4-hydroxyphenyl)prop-2-en-1-one as
chalcone were sythesized. These complexes
have been characterized by a combination of FT-IR, 1H-NMR, HRMS and
UV–Vis spectroscopy techniques. Also cyclic voltammograms of these
phthalocyanines were taken and obtained knowledge as zinc phthalocyanine have
one reduction reaction and cobalt phthalocyanine have two reduction reaction.
Spectroelectrochemical investigation shows the ring based reduction of MPc’s. Pc-7 cobalt(II)phthalocyanine was investigated as catalyst in the catalytic
oxidation of 2-mercaptoethanol. Turnover number,
initial reaction rate and the oxygen consumption was found in the catalytic
oxidation of 2-mercaptoethanol as 16.6,
0.29, 2.52 recpectively.
Birincil Dil | İngilizce |
---|---|
Konular | Mühendislik |
Bölüm | Makaleler |
Yazarlar | |
Yayımlanma Tarihi | 1 Ocak 2018 |
Gönderilme Tarihi | 13 Kasım 2017 |
Kabul Tarihi | 16 Nisan 2018 |
Yayımlandığı Sayı | Yıl 2018 |