Research Article

Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium

Volume: 5 Number: 2 January 1, 2018
EN

Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium

Abstract

In this study, three aromatic-structured di-cationic surfactants with different length carbon chains were synthesized and inhibition efficiencies against metal corrosion in 1.0 M HCl solution were investigated. Corrosion inhibition efficiencies of di-cationic surfactants that structurally illuminated by spectroscopic methods (FT-IR and NMR) were determined in acidic media by gravimetric method based on weight loss in metal coupons. Corrosion tests resulted in good inhibition efficiencies (90.40% - 96.85%) against metallic corrosion at different concentrations of inhibitors. By using the weight loss values, corrosion rates were also calculated in the inhibited and uninhibited medium. Finally, images of metal surfaces were obtained using scanning electron microscopy to support the obtained corrosion inhibition effect results.

Keywords

References

  1. 1. Görenler A. Al-Si Matrisli Kompozit Malzemelerin Korozyon Davranışlarının İncelenmesi. Yıldız Technical University, Institute of Science, Master of Science Thesis, 2007 İstanbul.
  2. 2. Üneri S. Corrosion and Prevention. Corrosion Society, 1998, Ankara, 413 s.
  3. 3. Öztürk S. Design and Synthesis of Some Amide Compounds as Potential Corrosion Inhibitors. Uludag University, Institute of Science and Technology, PhD Thesis, 2013, Bursa.
  4. 4. Papavinasam, S. Corrosion Inhibitors. In: Uhlig’s Corrosion Handbook, W.R. Revie (Editor), Wiley Interscience, 2000, p.1089-1105.
  5. 5. Hegazy MA. Novel cationic surfactant based on triazole as a corrosion inhibitor for carbon steel in phosphoric acid produced by dihydrate wet process. J. Mol. Liq. 2015 Aug; 208:227-36.
  6. 6. Asefi D, Arami M, Sarabi AA, Mahmoodi NM. The chain length influence of cationic surfactant and role of nonionic co-surfactants on controlling the corrosion rate of steel in acidic media. Corros. Sci. 2009 Aug; 51:1817-21.
  7. 7. El Achouri M, Infante MR, Izquierdo F, Kertit S, Gouttaya HM, Nciri B. Synthesis of some cationic gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium. Corros. Sci. 2001 Jan; 43:19-35.
  8. 8. Hegazy MA, Abdallah M, Ahmed H. Novel cationic gemini surfactants as corrosion inhibitors for carbon steel pipelines. Corros. Sci. 2010 Sep; 52:2897-2904.

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Publication Date

January 1, 2018

Submission Date

February 27, 2018

Acceptance Date

June 4, 2018

Published in Issue

Year 2018 Volume: 5 Number: 2

APA
Öztürk, S., & Yıldırım, A. (2018). Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium. Journal of the Turkish Chemical Society Section A: Chemistry, 5(2), 819-834. https://doi.org/10.18596/jotcsa.399297
AMA
1.Öztürk S, Yıldırım A. Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium. JOTCSA. 2018;5(2):819-834. doi:10.18596/jotcsa.399297
Chicago
Öztürk, Serkan, and Ayhan Yıldırım. 2018. “Synthesis of Aromatic Structured Di-Cationic Surfactants Used As Inhibitors Against Corrosion of Carbon Steel in Acidic Medium”. Journal of the Turkish Chemical Society Section A: Chemistry 5 (2): 819-34. https://doi.org/10.18596/jotcsa.399297.
EndNote
Öztürk S, Yıldırım A (January 1, 2018) Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium. Journal of the Turkish Chemical Society Section A: Chemistry 5 2 819–834.
IEEE
[1]S. Öztürk and A. Yıldırım, “Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium”, JOTCSA, vol. 5, no. 2, pp. 819–834, Jan. 2018, doi: 10.18596/jotcsa.399297.
ISNAD
Öztürk, Serkan - Yıldırım, Ayhan. “Synthesis of Aromatic Structured Di-Cationic Surfactants Used As Inhibitors Against Corrosion of Carbon Steel in Acidic Medium”. Journal of the Turkish Chemical Society Section A: Chemistry 5/2 (January 1, 2018): 819-834. https://doi.org/10.18596/jotcsa.399297.
JAMA
1.Öztürk S, Yıldırım A. Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium. JOTCSA. 2018;5:819–834.
MLA
Öztürk, Serkan, and Ayhan Yıldırım. “Synthesis of Aromatic Structured Di-Cationic Surfactants Used As Inhibitors Against Corrosion of Carbon Steel in Acidic Medium”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 5, no. 2, Jan. 2018, pp. 819-34, doi:10.18596/jotcsa.399297.
Vancouver
1.Serkan Öztürk, Ayhan Yıldırım. Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium. JOTCSA. 2018 Jan. 1;5(2):819-34. doi:10.18596/jotcsa.399297

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