The Effect of Polymer Capping Group to the Electrocatalytic Water Oxidation Activities of Prussian Blue Analogues

Year 2020, , 225 - 232, 15.02.2020

Emine Ülker

https://doi.org/10.18596/jotcsa.554229

Abstract

The Prussian Blue (PB) nanoparticles can be
obtained by reacting the hexacyanometal center with metal ions in the existence
of polymers such as polyethyleneglycol (PEG). In this study, a pentacyanometal
complex, [Fe(CN)₅NO]^2-, was used in addition to hexacyanometal
ion, [Fe(CN)₆]^3-, to obtain nanoparticles coated with
PEG. PB nanoparticles have been prepared, characterized, and comprehensive
electrochemical studies were performed to investigate their performance for
water oxidation electrocatalysis. The effect the ratio of PEG to the morphology
and the water oxidation electrocatalytic performance have also been
interrogated. Overall, the study clearly indicates that Co-FeNO@PEG with 1:10
and 1:25 Co:PEG rate show the best electrocatalytic activity with an overpotential
of 472 and 489 mV for current density of 1 mA cm^-1, respectively.

Keywords

Prussian blue, polyethyleneglycol, cyanide, water oxidation, electrocatalysis

Supporting Institution

TUBITAK

Project Number

1929B011500059

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